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We derive the incompressible and compressible k–ε model for locally homogeneous turbulence. The model is rigorously derived on formal mathematical grounds using the MPP modelling technique. This lets us calculate by either analytical or numerical means the closure constants of the model. To cite this article: T. Chacón Rebollo, D. Franco Coronil, C. R. Acad. Sci. Paris, Ser. I 337 (2003). 相似文献
3.
Franco Flandoli 《Annali di Matematica Pura ed Applicata》1993,163(1):93-131
Two classes of Riccati equations arising in the boundary control of parabolic systems are studied by direct methods. The new feature with respect to previous works on this subject is the low regularity of the final data. The classes considered here generalize those of [7]and [5]on one side, and of [14]on the other one. Completely new methods are used to obtain the solution of the Riccati equations, in both cases. The central theme is the dependence of the solutions on a «symmetric» norm of the final data, yielding these new results as well as a new proof of existence for the related algebraic Riccati equation under more general assumptions. The synthesis of the associated linear-quadratic-regulator problems is easily solved using these results. 相似文献
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Exploring new directions for research in problem structuring methods: on the role of cognitive style
Prior research has argued that cognitive style can have a significant impact on group decision making. In addition, several scholars have proposed that cognitive style can play a key role in the design and use of group decision support systems. However, cognitive style has not received a great deal of attention in the problem structuring methods (PSMs) community. This is surprising, given that PSMs are specifically developed to support a group in their decision making. The purpose of this paper is thus to examine the significance of cognitive style within PSMs. The paper identifies and explores the role of four different cognitive style functions in problem structuring interventions. This analysis is carried out by focusing on the different tasks embedded within a group process supported by PSMs. Implications for the research and practice of PSMs are then discussed. 相似文献
6.
Shock waves and the relevant Rankine-Hugoniot conditions may be inadequate even in simple cases. As an example, the electromagnetic field generated by a point charge, whose velocity jumps from0 to a constant value, not only jumps across a spherical surface expanding at light speed, but also includes a-distribution term. This suggests that the concept of higher order shock waves be introduced, the associated compatibility conditions being also deduced.
Sommario Il concetto di onda d'urto può rivelarsi inadeguato per descrivere situazioni anche semplici. A titolo di esempio, si determina esplicitamente l'espressione del campo elettromagnetico generato da una carica puntiforme la cui velocità passa istantaneamente da0 a un valore costante. Il campo elettromagnetico non solo è discontinuo attraverso una superficie sferica che si espande alla velocità della luce, ma include anche un termine che coinvolge la distribuzione. Ciò suggerisce di definire le onde d'urto di ordine superiore, per le quali si determinano le corrispondenti condizioni di compatibilità.相似文献
7.
Franco Piacenti Mario Bianchi Piero Frediani Ugo Matteoli 《Journal of organometallic chemistry》1975,87(3):C54-C55
Both normal and secondary alkylcobalt carbonyls are shown not to undergo isomerization under catalytic “oxo” conditions, and the relevance of this obervation for the mechanism of the “oxo” reaction is discussed. 相似文献
8.
Substrate relaxation is shown to play an important role in the 1 : 2 regular chemisorption of hydrogen atoms above alternate carbon atoms in a graphite monolayer. Binding energy, population analysis and electron density maps show that the direct HC bond is strengthened on relaxation. 相似文献
9.
Franco Cecconi Andrew Duthie Pedro Gili Stefano Midollini 《Journal of solid state chemistry》2004,177(3):786-792
By reaction of Zn(CH3COO)2 with p,p′-diphenylmethylenediphosphinic acid in water a new inorganic-organic polymeric hybrid of formula [Zn(CH2(P(Ph)O2)2)] has been synthesized and completely characterized. The X-ray analysis established that the structure consists of 2D-layered polymeric array, the 2D-sheets being built up through strong covalent linkages between the zinc metal and the oxygen donors of the phenylphosphinate ligand. The 2D-layers, which are featuring a mesh-net fashion, present voids of various dimensionality, up to 24-membered rings. The organic parts of the hybrid ligand, namely the phenyl rings, are shielding the inorganic skeleton of the layers, preventing the propagation of the polymer in the third dimension. No water molecules are present in the lattice, both of coordination and crystallization. Crystal data are: monoclinic, P21/c, a=11.840(2), b=9.646(9), c=12.516(5) Å, β=95.03(2), V=1423.9(15) Å3, Z=4. The solid material has been characterized by 31P MAS NMR spectroscopy and thermogravimetric analysis. 相似文献
10.
Peroxidase based biosensors for the selective determination of D,L-lactic acid and L-malic acid in wines 总被引:1,自引:0,他引:1
A novel bioelectrochemical method for the direct determination of D(−) L(+) lactic acid and of L(−) malic acid in wines is presented. Multienzymatic biosensors were realized for the selective determination of the three analytes: D(−) and L(+) lactic acid were measured by a trienzymatic biosensor based on the catalytic activities of the enzymes L(+) lactate oxidase (LOD), D(−) lactate dehydrogenase (D-LDH) and horseradish peroxidase (HRP); L(−) malic acid was measured by a bienzymatic electrode, realized by coupling the enzymes L(−) malic dehydrogenase (L-MDH) and horseradish peroxidase (HRP). In both cases the enzymes were immobilized on an oxygen selective Clark electrode.The simultaneous determination of the two organic acids can be accomplished either in batch or in a flow injection analysis apparatus using the same biosensors as detectors. The analytical performance of the method, tested in standard aqueous solutions and on real samples of wines, showing high repeatability, short response times and reduced cost of analysis, suggest that the experimental approach here described could be followed to monitor the progress of malolactic fermentation. 相似文献