WITCH: A Penning Trap Retardation Spectrometer Combination for Precision Studies of the Weak Interaction

We present data from three seasons of experimental field work designed to recreate ancient Andean coastal ceramic firing techniques. Based on the recent discovery of two different archaeological ceramic production sites in the La Leche river valley of northern coastal Peru, the opportunity arose to apply Mössbauer spectroscopy and other analytical methods to reconstruct ancient firing procedures. Two sets of firings took place in 1993 and 1997 in Batán Grande using a partially restored Formative kiln from about 800 BC, local hardwood and cow dung as fuel. A third experiment followed in 2000 after the discovery of a Middle Sicán ceramics workshop in use between ca. AD 950 and 1050 at Huaca Sialupe, where an exact replica of an ancient kiln was built from local clay, and fired with local wood and cow dung. Additionally, inverted urns found at Huaca Sialupe were tested for their potential use as furnaces for metal working. Mössbauer spectroscopy was used to compare the physical and chemical state of specimens produced in the field experiments with ancient ceramics and with specimens produced in controlled laboratory experiments.     

Noncollinear magnetic hyperfine fields in the Ag spacers of Fe/Ag multilayers

Nearly perpendicular magnetic hyperfine fields have been observed for the first time in the Ag "spacers" of Fe/Ag multilayers using low temperature nuclear orientation of (110)Ag(m) at 6 mK. At the same time, vibrating sample magnetometry measurements at temperatures down to 4 K have shown the magnetic anisotropy of the Fe to be in plane. The direction of the Ag hyperfine field is thus noncollinear (nearly orthogonal) to the Fe anisotropy. These results are compared with full potential linearized augmented plane wave calculations using the wien97 code.     

Fundamental weak interaction studies using polarised nuclei and ion traps

Two experiments to search for new physics beyond the standard model for electroweak interactions by measuring correlations between different spin and momentum vectors in nuclear β-decay are discussed. In the first experiment the correlation between the emission asymmetry and the longitudinal polarisation of positrons emitted by polarised nuclei is determined. This type of measurement is sensitive to the presence of right-handed currents but also to possible scalar and tensor-type currents in the weak interaction. The aim of the second experiment is to determine the βν-correlation in β-decay by measuring the energy spectrum of the recoil ions, using a Penning trap and a retardation spectrometer. In this case the focus is on the search for scalar currents in the weak interaction. The results of the experiments presented here are complementary to results from experiments in muon decay and at high-energy colliders. This revised version was published online in July 2006 with corrections to the Cover Date.     

The geometry of the site and its relevance for chain migration and stereospecificity

The structurally well characterized members of the family of the bridged metallocene procatalysts with cyclopentadienyl-fluorenyl ligand framework constitute excellent examples for the investigation of the interrelation between the catalyst geometry and stereospecificity from a dynamic chain perspective. We have thus carefully selected a set of metallocenes, based on the increasing size of their β-substituents and the choice of Zr and Hf as transition metals. By their application as polymerization catalysts we have been able to investigate the impact of the substituent size on the migratory behavior of the chain and stereospecific control of the corresponding catalysts. Through these investigations it has been demonstrated that the degree of freedom for the chain's lateral displacements, and the frequency of its back and forth migrations, varies largely with and is dependent on the steric bulk of the β-positioned substituent and to the degree of the geometrical (stereo-electronic) flexibility of the catalytic site with a given symmetry. It has been inferred from the experimental results that substituents, depending on their voluminosity and spatial expansion, interfer differently with the migratory function of the chain and can bring its migration, temporarily or permanently, to a halt (chain stationary insertion). The ratio of chain migratory insertion to chain stationary insertion and their prevalence in each individual case has the final saying about the degree and the type of the microtacticity of the resulting polymer chains (e.g. syndiotactic, syndiotactic containing isoblock, syndio-isoblock, isotactic, and isotactic with syndioblock.     

A study of the induced magnetic hyperfine fields in Fe/Ag multilayers

Near perpendicular magnetic hyperfine fields in ^110mAg have been observed in Fe/Ag multilayers. These fields are studied by low temperature nuclear orientation (LTNO) in multilayers [Ag(x ML)/Fe(y ML)]₂₀, with (x,y) monolayer (ML) values of (2,10), (3,9), (5,10) and (3,18). The ^110mAg γ-ray anisotropy was measured as a function of applied magnetic field parallel to the multilayer. The average induced hyperfine field of Ag is significantly influenced by the quality of the multilayer as measured by X-ray diffraction. This revised version was published online in August 2006 with corrections to the Cover Date.     

Reservation and allocation policies for influenza vaccines

This research investigates the impact of alternative allocation mechanisms that can be employed in the context of vaccine inventory rationing. Available vaccine inventory can be allocated to arrivals from high priority (target groups such as healthcare professionals) and low priority (non-target groups) demand classes using Partitioned Allocation (PA), Standard Nesting (SN), and Theft Nesting (TN). In any one of the mechanisms, a part of the available inventory is reserved for the exclusive use of the high priority demand class. They differ, however, in how the unreserved portion of the inventory is utilized: Under PA, demand from the high (low) priority class consumes only the reserved (unreserved) quantity. Under SN, demand from the high priority class first consumes the reserved quantity; once and if this quantity is exhausted, high priority demand competes with low priority demand for the remaining inventory. Under TN the sequence of allocation is reversed: both demand classes first compete for the unreserved inventory. Once this portion of inventory is exhausted, high priority demand is fulfilled from the reserved inventory and low priority demand is rejected. We develop service level (probability of fulfilling the entire demand) and fill rate (fraction of demand fulfilled) expressions for all three allocation mechanisms. Based on these expressions, numerical analyses are conducted to illustrate which allocation mechanism a health planner should choose depending on the availability of vaccines, and how the health planner should set the reserved quantity for the high priority class. We observe that (1) there exist certain conditions under which one of the allocation mechanisms outperforms the others and (2) this effect is determined by the decision maker’s choice of the performance measure.