Noiselike magnetic resonance fine structure for ferromagnetic powders: Dipole-dipole interaction effects

A noiselike fine structure of ferromagnetic resonance spectra in magnetic powders was investigated after ultrasonic treatment. Magnetic interactions between particles are proved to have an influence upon the fine structure formation. After decreasing dipole-dipole magnetic interactions in dilute suspension a special order appears in fine-structure spectra, which is generally the same for different systems.     

Electron spin echo of CH2OH radicals adsorbed in A-type zeolites

Data on the trapping site of radicals in zeolite α-cages have been obtained by the analysis of modulation effects in the electron spin echo of CH₂OH radicals produced by irradiation in A-type zeolite with adsorbed methyl alcohol.     

A new approach to fluorinated 4(3H)-quinazolinones

A new approach for the synthesis of fluorinated 1H-quinazolin-4-ones and 4-substituted quinazolines has been developed. 6-Fluoro-1H-quinazolin-4-ones were obtained by intramolecular cyclization of fluorine-containing S-ethyl N-benzoylisothioureas. Nucleophilic substitution reactions at positions 2 and 7, as well as alkylation at 1-position of quinazolinones were investigated. In addition, the synthesis of fluorine-containing 4-aminoquinazolines was carried out.     

Synthesis of Ozone in a Surface Barrier Discharge with a Plasma Electrode

The synthesis of ozone from oxygen in a cylindrical ozonizer operating under surface discharge conditions with a plasma electrode was studied. The conditions of ozone synthesis were optimized. The dependence of ozone concentration and specific energy consumption on gas pressure in the plasma electrode and on distance between the coils of a corona electrode was determined. The results were compared with data obtained with the use of classical surface barrier discharge.__________Translated from Khimiya Vysokikh Energii, Vol. 39, No. 4, 2005, pp. 307–311.Original Russian Text Copyright © 2005 by Alemskaya, Lelevkin, Tokarev, Yudanov.     

Phase transition,structure, and molecular dynamics in fluorographite C2F intercalated with acetonitrile

Compounds of fluorographite C₂F intercalated with acetonitrile have been investigated by nuclear magnetic resonance. The appearance of anisotropic molecular diffusion accompanied by a phase transition of the melting type has been discovered in the quasi-two-dimensional system of guest molecules.Institute of Inorganic Chemistry, Academy of Sciences of the USSR, Siberian Branch. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 2, pp. 79–83, March–April, 1991.     

Application of nitroxyl radicals to study mass transfer processes in porous materials

A method to determine rates for gaseous and liquid transfer of moisture in the process of mass transfer in porous materials is suggested. The data obtained agree well with the theoretical concepts about liquid transfer of moisture under contact of two porous bodies.

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Wide bandgap OPV polymers based on pyridinonedithiophene unit with efficiency >5%

We report the properties of a new series of wide band gap photovoltaic polymers based on the N-alkyl 2-pyridone dithiophene (PDT) unit. These polymers are effective bulk heterojunction solar cell materials when blended with phenyl-C₇₁-butyric acid methyl ester (PC₇₁BM). They achieve power conversion efficiencies (up to 5.33%) high for polymers having such large bandgaps, ca. 2.0 eV (optical) and 2.5 eV (electrochemical). Grazing incidence wide-angle X-ray scattering (GIWAXS) reveals strong correlations between π–π stacking distance and regularity, polymer backbone planarity, optical absorption maximum energy, and photovoltaic efficiency.     

Biodegradable and Biocompatible Silatrane Polymers

In this study, new biodegradable and biocompatible amphiphilic polymers were obtained by modifying the peripheral hydroxyl groups of branched polyethers and polyesters with organosilicon substituents. The structures of the synthesized polymers were confirmed by NMR and GPC. Organosilicon moieties of the polymers were formed by silatranes and trimethylsilyl blocks and displayed hydrophilic and hydrophobic properties, respectively. The effect of the ratio of hydrophilic to hydrophobic organosilicon structures on the surface activity and biological activity of macromolecules was studied, together with the effect on these activities of the macromolecules’ molecular weight and chemical structure. In particular, the critical micelle concentrations were determined, the effect of the structure of the polymers on their wetting with aqueous solutions on glass and parafilm was described, and the aggregation stability of emulsions was studied. Finally, the effect of the polymer structures on their antifungal activity and seed germination stimulation was examined.