全文获取类型
收费全文 | 811篇 |
免费 | 34篇 |
国内免费 | 1篇 |
专业分类
化学 | 537篇 |
晶体学 | 23篇 |
力学 | 4篇 |
数学 | 82篇 |
物理学 | 200篇 |
出版年
2021年 | 12篇 |
2020年 | 10篇 |
2019年 | 11篇 |
2017年 | 5篇 |
2016年 | 28篇 |
2015年 | 28篇 |
2014年 | 32篇 |
2013年 | 28篇 |
2012年 | 45篇 |
2011年 | 37篇 |
2010年 | 26篇 |
2009年 | 39篇 |
2008年 | 31篇 |
2007年 | 38篇 |
2006年 | 39篇 |
2005年 | 34篇 |
2004年 | 25篇 |
2003年 | 18篇 |
2002年 | 17篇 |
2001年 | 15篇 |
2000年 | 17篇 |
1999年 | 13篇 |
1998年 | 10篇 |
1997年 | 10篇 |
1996年 | 15篇 |
1995年 | 17篇 |
1994年 | 12篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1991年 | 13篇 |
1990年 | 6篇 |
1989年 | 8篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1986年 | 14篇 |
1983年 | 11篇 |
1982年 | 9篇 |
1980年 | 11篇 |
1978年 | 10篇 |
1977年 | 5篇 |
1976年 | 6篇 |
1974年 | 5篇 |
1965年 | 5篇 |
1964年 | 6篇 |
1960年 | 4篇 |
1959年 | 6篇 |
1957年 | 6篇 |
1956年 | 4篇 |
1955年 | 6篇 |
1932年 | 4篇 |
排序方式: 共有846条查询结果,搜索用时 15 毫秒
1.
Martin Kellert Jan-Simon Jeshua Friedrichs Nadine Anke Ullrich Alexander Feinhals Jonas Tepper Peter Lnnecke Evamarie Hey-Hawkins 《Molecules (Basel, Switzerland)》2021,26(7)
The development of novel, tumor-selective and boron-rich compounds as potential agents for use in boron neutron capture therapy (BNCT) represents a very important field in cancer treatment by radiation therapy. Here, we report the design and synthesis of two promising compounds that combine meta-carborane, a water-soluble monosaccharide and a linking unit, namely glycine or ethylenediamine, for facile coupling with various tumor-selective biomolecules bearing a free amino or carboxylic acid group. In this work, coupling experiments with two selected biomolecules, a coumarin derivative and folic acid, were included. The task of every component in this approach was carefully chosen: the carborane moiety supplies ten boron atoms, which is a tenfold increase in boron content compared to the l-boronophenylalanine (l-BPA) presently used in BNCT; the sugar moiety compensates for the hydrophobic character of the carborane; the linking unit, depending on the chosen biomolecule, acts as the connection between the tumor-selective component and the boron-rich moiety; and the respective tumor-selective biomolecule provides the necessary selectivity. This approach makes it possible to develop a modular and feasible strategy for the synthesis of readily obtainable boron-rich agents with optimized properties for potential applications in BNCT. 相似文献
2.
G. Ullrich D. Herzog R. Liska P. Burtscher N. Moszner 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4948-4963
Camphorquinone (CQ), a widely used photoinitiator (PI) in dental applications, was covalently bonded to aromatic amines to enhance the rate of electron and proton transfer effect due to the close vicinity of the diketone and the amine group. 10‐bromocamphorquinone and 10‐bromomethylcamphorquinone were selected as suitable precursors for esterification with the carboxyl group containing aromatic amines based on 4‐dimethylaminobenzoic acid. Properties of the new photoinitiating systems were investigated by UV spectroscopy and differential scanning photocalorimetry in lauryl acrylate. Compared to physical mixtures, in all cases similar or even better performance was obtained. Surprisingly, 10‐acetyl derivatives 7 – 9 and 18 especially, were found to be highly reactive. Compared to CQ/ethyl 4‐dimethylaminobenzoate, the rate of photopolymerization was increased by a factor of up to 2. Intramolecular reaction was confirmed by photo‐differential scanning calorimetry experiments with varying PI concentrations. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4948–4963, 2004 相似文献
3.
M. Froese C. Champagne J. R. Crespo López-Urrutia S. Epp G. Gwinner A. Lapierre J. Pfister G. Sikler J. Ullrich J. Dilling 《Hyperfine Interactions》2006,173(1-3):85-92
The precision of atomic mass measurements in a Penning trap is directly proportional to the charge state q of the ion and,
hence, can be increased by using highly charged ions (HCI). For this reason, charge breeding with an electron beam ion trap
(EBIT) is employed at TRIUMF’s Ion Trap for Atomic and Nuclear science (TITAN) on-line facility in Vancouver, Canada. By bombarding
the injected and trapped singly charged ions with an intense beam of electrons, the charge state of the ions is rapidly increased
inside the EBIT. To be compatible with the on-line requirements of short-lived isotopes, very high electron beam current densities
are needed. The TITAN EBIT includes a 6 Tesla superconducting magnet and is designed to have electron beam currents and energies
of up to 5 A and 60 keV, respectively. Once operational at full capacity, most species can be bred into a He-like configuration
within tens of ms. Subsequently, the HCI are extracted, pass a Wien filter to reduce isobaric contamination, are cooled, and
injected into a precision Penning trap for mass measurement. We will present the first results and current status of the TITAN
EBIT, which has recently been moved to TRIUMF after assembly and commissioning at the Max-Planck-Institute (MPI) for Nuclear
Physics in Heidelberg, Germany. 相似文献
4.
R. Pietsch 《Fresenius' Journal of Analytical Chemistry》1957,155(3):189-194
Zusammenfassung Es wird über die Möglichkeit einer Bestimmung des Vanadat-Ions mit Phenarsazinsäure berichtet. Vanadat fällt mit dem Reagens in saurem Medium bei pH 2 als hellbrauner flockiger Niederschlag quantitativ aus, wenn ein mehr als dreifacher molarer Überschuß an Phenarsazinsäure angewendet wird. Die Bestimmung des Vanadiums im gebildeten Niederschlag erfolgt maßanalytisch. Über einige Trennungsmöglichkeiten wird berichtet. 相似文献
5.
Analytical and Bioanalytical Chemistry - Es wird eine neue extraktive Trennungsmethode für Uran beschrieben. Mit Hilfe einer Lösung von Triphenylarsinoxid in Chloroform lassen sich... 相似文献
6.
We report on the efficiency behavior of light-emitting electrochemical cells (LECs) fabricated from a methyl-substituted ladder-type poly(p-phenylene) (mLPPP) that was blended with a crown ether based solid state electrolyte. Unlike organic light-emitting diodes (oLEDs) utilizing mLPPP as an active layer, the LECs suffer from a loss of efficiency at elevated current densities. From scan rate dependent studies we deduce that this efficiency drop is not only due to device decomposition upon high voltage operation and we also reveal the intrinsic mode of LEC operation. The decreasing width of the intrinsic region between the p- and n-type doped zones upon ongoing pin-junction formation causes distinct (either field or electrode induced) luminance quenching effects. 相似文献
7.
R. Pietsch 《Mikrochimica acta》1955,43(5-6):1019-1025
Zusammenfassung Die qualitative Fällung von Metallionen mit den drei isomeren o-, m- und p-Nitrophenylarsinsäuren wird beschrieben und auf Unterschiede der ph-Werte des Fällungsbeginnes hingewiesen. Die Beeinflussung des Fällungsbeginnes durch die Stellung der Nitrogruppe wird hervorgehoben.
Summary The precipitation of metal ions by means ofo-, m-, andp-nitrophenyl arsonic acids is described. The differences of the pH values of the start of the precipitation are pointed out. The effect of the position of the nitro group on the beginning of the precipitation is stressed.
Résumé On décrit la précipitation qualitative d'ions métalliques par les trois isomèreso., m. etp. de l'acide nitrophénylarsonique et l'on donne des indications concernant les différences de valeur du ph lors du commencement de précipitation. On met en évidence l'influence de la position du groupe nitro sur le commencement de précipitation.相似文献
8.
9.
10.
S. A. Stepanov U. Pietsch G. T. Baumbach 《Zeitschrift für Physik B Condensed Matter》1995,96(3):341-347
A method for computation of X-ray grazing-incidence diffraction (GID) in multilayers and superlattices is presented. The method is based on X-ray dynamical diffraction theory and a matrix from a boundary equations and provides a simple numerical solution of the problem. The application of the method to simulating GID measurements taken from A1As/GaAs superlattice (20 periods of 14.6 nm A1As and 6.8 nm GaAs) demonstrates the principal validity of the theory. A perfect matching between the theory and the experiment requires the real-structure effects of sample to be taken into account. 相似文献