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1.
K. S. Trofimova V. G. Dronov N. S. Shaglaeva R. G. Sultangareev 《Russian Journal of Applied Chemistry》2008,81(4):730-731
Possibilities of utilization of by-products formed in manufacture of epichlorohydrin are considered. A promising way to utilize wastes from production of epichlorohydrin by synthesis of 2,3-dichloropropene from 1,2,3-trichloropropane is suggested. 相似文献
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M. G. Voronkov E. A. Grebneva O. M. Trofimova A. I. Albanov N. F. Chernov N. N. Chipanina 《Russian Journal of General Chemistry》2006,76(12):1851-1853
Reaction of tetrafluorosilane with tris(2-hydroxyethyl)-and tris(2-trimethylsiloxyethyl)amine results in formation of 1-fluorosilatrane and fluorosilatrane in 75 and 53% yield, respectively. Reaction of tetrafluorosilane with bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative leads to the hitherto unknown 1,1-difluoroquasisilatranes (N → Si) F2Si(OCH2CH2)2NR (R = H, Me) containing donor-acceptor bond N → Si and pentacoordinate silicon atom. The structure of the synthesized compounds was proved by 1H, 13C, 15N, 19F, 29Si NMR and IR spectroscopy. 相似文献
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We have used electronic spectroscopy in the 160–1100 nm range to study the polyvinyl alcohol-nickel(II) chloride system. Based
on the results obtained, we hypothesize formation of mixed-ligand complexes of the type [Ni(H2O)6-nCln]2-n (n = 0, 1,..., 5) in the polyvinyl alcohol matrix. Transformation of the coordination sphere as the NiCl2 concentration changes is apparent both in the region of the d-d transition bands (350–1100 nm) and in the region of the charge
transfer bands (160–250 nm). We propose assigning the absorption bands separated by mathematical treatment to complexes of
specific compositions.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 1, pp. 136–138, January–February, 2006. 相似文献
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M. G. Voronkov L. I. Larina Yu. I. Bolgova O. M. Trofimova N. F. Chernov V. A. Pestunovich 《Chemistry of Heterocyclic Compounds》2006,42(12):1585-1591
The 1H, 13C, 15N, and 29Si NMR, IR, and UV spectra of N-(1-silatranylmethyl) and N-(trimethoxysilylmethyl) derivatives of nitrogen heterocycles have
been studied. The dependence and interrelation of the chemical shifts of 29Si and 15N nuclei of the silatranyl group in the spectra of N-(1-silatranylmethyl)-substituted nitrogen heterocycles are determined
by the nature of the heterocyclic system.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1857–1865, December, 2006. 相似文献
10.
B. S. Fedorov M. A. Fadeev V. V. Arakcheeva G. V. Strukov N. I. Golovina R. F. Trofimova G. V. Shilov L. O. Atovmyan 《Russian Chemical Bulletin》1994,43(12):2087-2090
A novel heterocyclic compound, 4-acetoxy-5,6-dihydro-5,5-dinitro-2H-1,3-oxazineN-oxide, has been synthesized by the reaction of the dipotassium salt of 1,1,5,5-tetranitro-3-oxapentane with aqueous acetic acid. The synthesized compound has been studied by X-ray diffraction analysis.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2207–2210, December, 1994.We would like to thank G. V. Lagodzinskaya (Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences) for recording and interpreting1H NMR spectra, A. M. Korolev (Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences) for helpful discussion, and V. I. Fetisov (Institute of Physiologically Active Compounds, Russian Academy of Sciences) for performing quantum-chemical calculations by the AM1 SCF MO LCAO method. 相似文献