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排序方式: 共有82条查询结果,搜索用时 15 毫秒
1.
Numerical Algorithms - Interpolatory splines are usually useful to reconstruct data that present certain regularity. This paper is devoted to the construction and analysis of a new technique that... 相似文献
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Multiple Stable Conformations Account for Reversible Concentration‐Dependent Oligomerization and Autoinhibition of a Metamorphic Metallopeptidase
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Mar López‐Pelegrín Dr. Núria Cerdà‐Costa Dr. Anna Cintas‐Pedrola Fátima Herranz‐Trillo Dr. Pau Bernadó Dr. Juan R. Peinado Dr. Joan L. Arolas Prof. Dr. F. Xavier Gomis‐Rüth 《Angewandte Chemie (International ed. in English)》2014,53(40):10624-10630
Molecular plasticity controls enzymatic activity: the native fold of a protein in a given environment is normally unique and at a global free‐energy minimum. Some proteins, however, spontaneously undergo substantial fold switching to reversibly transit between defined conformers, the “metamorphic” proteins. Here, we present a minimal metamorphic, selective, and specific caseinolytic metallopeptidase, selecase, which reversibly transits between several different states of defined three‐dimensional structure, which are associated with loss of enzymatic activity due to autoinhibition. The latter is triggered by sequestering the competent conformation in incompetent but structured dimers, tetramers, and octamers. This system, which is compatible with a discrete multifunnel energy landscape, affords a switch that provides a reversible mechanism of control of catalytic activity unique in nature. 相似文献
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We investigate wave-breaking and dispersive shock wave formation driven by a pulse undergoing second-harmonic generation in a quadratic medium. We show that the process is accessible in the regime of high phase-mismatch (cascading limit) and weak dispersion. Insight into the phenomenon is obtained by means of a suitable hydrodynamic reduction of the equations that govern the mixing. 相似文献
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In an amplifier, nonlinear feedback from mismatched backward second-harmonic generation leads to strong enhancement of parametric conversion. With reference to LiNbO(3) quasi-phase-matched waveguides, we propose a parametric bistable device that operates simultaneously in two colors and in the cw or the self-pulsed regime. 相似文献
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Alfredo De Rossi Gaetano Assanto Stefano Trillo William E. Torruellas 《Optics Communications》1998,150(1-6):390-398
We have identified a family of (2+1)D spatial solitary waves which can stably propagate in bulk media in the presence of coexisting diffraction, self-focusing Kerr and quadratic nonlinearities. In a conspicuous range of excitation conditions close to the stationary solutions, the emerging wavepackets are immune to the detrimental occurrence of filamentation and collapse, typical of pure Kerr media. The presence of a second-order contribution to the cubic nonlinear response is, therefore, able to prevent optical damage in applications relying on self-guidance. We show that the cross-phase modulation plays an important effect on stability. Our estimate shows that the effects of the cubic susceptibility cannot be neglected below a certain beam size in realistic crystals (e.g. KTP or similar). 相似文献
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Di Trapani P Valiulis G Piskarskas A Jedrkiewicz O Trull J Conti C Trillo S 《Physical review letters》2003,91(9):093904
We observe the formation of an intense optical wave packet fully localized in all dimensions, i.e., both longitudinally (in time) and in the transverse plane, with an extension of a few tens of fsec and microns, respectively. Our measurements show that the self-trapped wave is an X-shaped light bullet spontaneously generated from a standard laser wave packet via the nonlinear material response (i.e., second-harmonic generation), which extend the soliton concept to a new realm, where the main hump coexists with conical tails which reflect the symmetry of linear dispersion relationship. 相似文献
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Luca Stabellini Wei Lu Alfredo De Rossi Thomas Antoni Mathieu Carras Stefano Trillo Gaetano Bellanca 《Optical and Quantum Electronics》2008,40(14-15):1085-1090
A Finite Difference Time Domain approach is used to design and to optimize quantum-well based infrared photodetectors. Results showing the influence of some parameters on the performance of these devices are presented and discussed. 相似文献
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Archilla JF Cuevas J Alba MD Naranjo M Trillo JM 《The journal of physical chemistry. B》2006,110(47):24112-24120
Reconstructive transformations in layered silicates need a high temperature in order to be observed. However, very recently, some systems have been found where transformation can be studied at temperatures 600 degrees C below the lowest experimental results previously reported, including sol-gel methods. We explore the possible relation with the existence of intrinsic localized modes, known as discrete breathers. We construct a model for nonlinear vibrations within the cation layer, obtain their parameters, and calculate them numerically, obtaining their energies. Their statistics show that, although there are far less breathers than phonons, there are much more above the activation energy, making them good candidates to explain the reconstructive transformations at low temperatures. 相似文献