Y2O2S∶Er3+，Yb3+的制备及Er3+离子在晶场中的能级分裂

采用沉淀法制备前驱体,通过不同温度合成了上转换发光材料Y2O2S∶Er3+,Yb3+,运用XRD,SEM和上转换发射光谱对其进行表征。结果表明,所合成的Y2O2S∶Er3+Yb3+属于六方晶系晶体,随着合成温度的升高,产物的粒径不断增大,上转换发射光强度逐渐增加。研究Y2O2S∶Er3+Yb3+的上转换发光过程,红光发射和绿光发射分别源于Er3+离子的4F9/2→4I15/2以及2H11/2→4I15/2,4S3/2→4I15/2能级跃迁。利用群论计算了晶场中Er3+离子的能级分裂数目。     

Tri‐Chain Hydrocarbon Surfactants as Designed Micellar Modifiers for Supercritical CO2

Getting their feet wet : Low‐cost hydrocarbon surfactants act as fluid modifiers for supercritical carbon dioxide (scCO₂). Increased terminal branching of the surfactant chains aids micelle formation (see middle picture: CO₂ green), and more chains allows water to be incorporated (right, blue).

     

Order-constrained uniform approximations to the exponential based on restricted rationals

LetR _n/m(z∶γ)=P _n(z∶γ)/(1?γz) ^m be a rational approximation to exp (z),z ∈C, of ordern for all real positiveγ. In this paper we show there exists exactly one value ofγ in each of min(n+1,m) interpolation intervals such that the uniform error overR ^? is at a local minimum.     

一类含测度的非强制拟线性椭圆方程解的存在性和不存在性

本文主要研究如下含非线性梯度项的非强制拟线性椭圆方程\begin{equation*}\left \{\begin{array}{rl}-\text{div}(\frac{|\nabla u|^{p-2}\nabla u}{(1+|u|)^{\theta(p-1)}})+\frac{|u|^{p-2}u|\nabla u|^{p}}{(1+|u|)^{\theta p}}=\mu,~&x\in\Omega,\\ u=0,~&x\in\partial\Omega,\end{array}\right.\end{equation*} 弱解的存在性和不存在性, 其中$\Omega\subseteq\mathbb{R}^N(N\geq3)$ 是有界光滑区域, $1相似文献   

Triblock copolymer Pluronic®F127 sustains insulin release and reduces initial burst of microspheres—in vitro and in vivo study

In many cases, initial release of drugs from microparticles is undesirable. In the present study, Pluronic^®F127, which shows thermosensitive characteristic, was used for controlling both the initial release and the sustained release of insulin from microspheres. Calcium-alginate insulin microspheres were prepared by emulsion technology and dispersed in a thermosensitive semisolid gel, the PF127. In vitro study demonstrated that PF127 could protect the activity of insulin in some extent and control the initial release and sustained release of insulin well. The results of in vivo hypoglycemic experiment carried out on diabetic rats also displayed a well correlation with in vitro release patterns. The results suggested that PF127 could sustain insulin release through a subcutaneous injection, and this material was available to deliver insulin aiming for prolonged and smooth hypoglycemic function.     

High-affinity small molecule inhibitors of T cell costimulation: compounds for immunotherapy

Costimulatory molecules are important regulators of T cell activation and thus favored targets for therapeutic manipulation of immune responses. One of the key costimulatory receptors is CD80, which binds the T cell ligands, CD28, and CTLA-4. We describe a set of small compounds that bind with high specificity and low nanomolar affinity to CD80. The compounds have relatively slow off-rates and block both CD28 and CTLA-4 binding, implying that they occlude the shared ligand binding site. The compounds inhibit proinflammatory cytokine release in T cell assays with submicromolar potency, and as such, they represent promising leads for the development of novel therapeutics for immune-mediated inflammatory disease. Our results also suggest that other predominantly beta proteins, such as those that dominate the cell surface, may also be accessible as potentially therapeutic targets.     

Neutron diffraction and computer simulation study of liquid CS2 and CSe2

The structure factor of liquid CS₂ has been measured at ambient temperature by the 7C2 diffractometer at the Laboratoire Leon Brillouin?, Saclay, France. The result has been modelled by the reverse Monte Carlo (RMC) method. The only reported neutron diffraction measurement on liquid CSe₂ has also been investigated in detail. In both cases initial configurations for the RMC runs have been obtained by molecular dynamics simulation using a simple soft sphere potential. It has been found that the main features of experimental results have been reproduced even by this choice suggesting that the structure of these systems is almost entirely described by the excluded volume. Examination of model size dependence of results has also been carried out revealing the importance of using large simulation boxes.     

带多个形状参数的Bézier曲线

基于Bézier曲线升阶的思想,构造了带多个形状参数的Bézier曲线,它具有与Bézier曲线相同的性质.在控制顶点不变的情况下,可通过改变多个形状参数的取值调整曲线的形状.n次Bézier曲线是n次带多个形状参数的Bézier曲线的一个特例,多个形状参数可使曲线变化更灵活.     

4.7-W, 255-nm source based on second-harmonic generation of a copper-vapor laser in cesium lithium borate

We have generated 4.7 W of UV (255-nm) radiation with wall plug efficiency of 0.12% by frequency doubling the green (511-nm) output of a kinetically enhanced medium-scale copper-vapor laser (CVL) in cesium lithium borate (CLBO). Frequency doubling in beta -barium borate produced 3.9 W of UV radiation with wall plug efficiency of 0.1%. We found that conversion was better with CLBO because of the reduced constraints on CVL beam quality, less UV absorption, and smaller UV walk-off.