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排序方式: 共有351条查询结果,搜索用时 15 毫秒
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Kraus RM Lagoudakis PG Müller J Rogach AL Lupton JM Feldmann J Talapin DV Weller H 《The journal of physical chemistry. B》2005,109(39):18214-18217
We study the interplay between Auger effects and ionization processes in the limit of strong electronic confinement in core/shell CdSe/ZnS semiconductor nanocrystal quantum dots. Spectrally resolved fluorescence decay measurements reveal a monotonic increase of the photoluminescence decay rate on excitation density. Our results suggest that Auger recombination accelerates ionization processes that lead to the occupation of dark, nonemissive nanocrystal states. A model is proposed in the quantized Auger regime describing these experimental observations and providing an estimate of the Auger assisted ionization rates. 相似文献
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It has been shown, that in vitro incubation of Laminaria digitata extract (containing mainly As-sugar 1 (glycerol-arsenoribose) and As-sugar 3 (sulfonate-arsenoribose)) with liver cytosol, produced the same two arsenicals, as when L. digitata extract was treated with H(2)S. By parallel use of HPLC-ICP-MS and HPLC-ES-MS the compounds displayed mainly m/z 345 and m/z 409. A pure As-sugar 1 standard was obtained, and a standard of arsinothioyl-sugar 1 (m/z 345) was produced, by purging a solution of As-sugar 1 with gaseous H(2)S. The identity of arsinothioyl-sugar 1 was characterised by ES-MS, 1D and 2D NMR. Arsinothioyl-sugar 1 showed the same chromatographic behaviour and MS characteristics as one of the two arsenic-containing compounds (m/z 345) produced by incubation of L. digitata extracts with liver cytosol, and as the product of the incubation of As-sugar 1 with liver cytosol (HPLC-ICP-MS, HPLC-ES-MS). Assuming that As-sugar 3 reacts in a similar way to As-sugar 1 with H(2)S, it is most likely that the second unknown (m/z 409) is arsinothioyl-sugar 3. The degradation of As-sugar 1 in acidic solution (100 mM HCl) was followed by (1)H-NMR, and the relative slow degradation (t(1/2)= 17 h) suggests that arsenosugars are taken up from the stomach in their original chemical form, hence the study of arsenosugar incubation in tissue is highly relevant. The arsinothioyls are a new group of organoarsenicals, which have only recently been identified in nature. Here, arsinothioyl sugars are detected for the first time. The in vitro formation of arsinothioyl-sugars in liver cytosol suggests that arsinothioyls may be of large biochemical and toxicological importance. 相似文献
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M. Guillot F. Tchéou A. Marchand P. Feldmann 《Zeitschrift für Physik B Condensed Matter》1984,56(1):29-39
Using neutron diffraction data, the thermal evolution of the magnetic structure of Ho3Fe5O12 has been studied. Below the compensation temperature (T
comp=137 K), the umbrella structure parameters which fit the spontaneous ferrite magnetizations have been determined. AboveT
comp, the compound behaves as a Néel type ferrimagnet. Particular attentions have been given to the magnetic form factors of both iron sublattice on one hand and on the other hand to a rhombohedral distorsion fromI a3d toR
below 30 K and in first approximation toR
c forT>30 K. 相似文献
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H. Blume R. Färber N. Feldmann K. Heinloth D. Kramarczyk F. Kuckelkorn H. J. Michels J. Päsler J. P. Dowd 《Zeitschrift fur Physik C Particles and Fields》1983,16(4):283-289
The electroproduction of π0-mesons on protons has been measured with electrons of 1.7 and 2.1 GeV energy in the region of the nucleon resonances at \(W = \sqrt {(q + p)^2 } = 1,400 - 2,000MeV\) at rather low values of |q 2|=|(e?e′)2|=0.01–0.1 GeV2 but at high values of the nucleon recoil |t|=|(p?p′)2|≈0.6–2.2 GeV2 corresponding to \(\Theta _\pi ^{cm} \approx 145^ \circ - 180^ \circ\) . Up toW≈1,650 MeV the cross section for π0-production with virtual photons of |q 2|≈0.03 GeV2 is only slightly smaller than that with real photons. ForW?1,700 MeV the cross section at |q 2|≈0.03 GeV2 is on average a factor of 2 smaller than that atq 2=0 but only slightly higher than that at |q 2|≈0.3–1 GeV2. 相似文献
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Fabian Gyger André Sackmann Michael Hübner Pascal Bockstaller Dagmar Gerthsen Henning Lichtenberg Jan‐Dierk Grunwaldt Nicolae Barsan Udo Weimar Claus Feldmann 《Particle & Particle Systems Characterization》2014,31(5):591-596
Pd@SnO2 and SnO2@Pd core@shell nanocomposites are prepared via a microemulsion approach. Both nanocomposites exhibit high‐surface, porous matrices of SnO2 shells (>150 m2 g?1) with very small SnO2 crystallites (<10 nm) and palladium (Pd) nanoparticles (<10 nm) that are uniformly distributed in the porous SnO2 matrix. Although similar by first sight, Pd@SnO2 and SnO2@Pd are significantly different in view of their structure with Pd inside or outside the SnO2 shell and in view of their sensor performance. As SMOX‐based sensors (SMOX: semiconducting metal oxide), both nanocomposites show a very good sensor performance for the detection of CO and H2. Especially, the Pd@SnO2 core@shell nanocomposite is unique and shows a fast response time (τ90 < 30 s) and a very good response at low temperature (<250 °C), especially under humid‐air conditions. Extraordinarily high sensor signals are observed when exposing the Pd@SnO2 nanocomposite to CO in humid air. Under these conditions, even commercial sensors (Figaro TGS 2442, Applied Sensor MLC, E2V MICS 5521) are outperformed. 相似文献
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