Accessing Tunable Afterglows from Highly Twisted Nonaromatic Organic AIEgens via Effective Through-Space Conjugation

Nonaromatic, cross-conjugated, and highly twisted luminogens consisting of acylated succinimides demonstrate aggregation-induced emission characteristics along with tunable multicolor photoluminescence and afterglows in their single crystals. Effective through-space conjugation among different moieties bearing n/π electrons promote the spin–orbit coupling and intersystem crossing and lead to diverse emissive clusters with concurrently rigidified conformations, thus allowing readily tunable emissions. Derived from it, the proof-of-concept application for advanced anti-counterfeiting is illustrated. These results should spur the rational design of novel nonaromatic AIEgens, and moreover advance understandings of the non-traditional intrinsic luminescence and the origin of tunable multicolor afterglows.     

具有全色发光的非芳香聚马来酰亚胺

<正>有机发光材料由于分子结构多样、发光颜色可调、加工简便等优点受到广泛关注。经典有机发光分子往往含有大的π共轭结构,并由此产生充分的电子离域。然而,此类有机发光分子往往含有稠环或芳杂环结构,具有潜在的细胞毒性^[1];且在调节发光颜色时往往需要增加分子共轭、改变取代基或引入不同的推拉电子结构,合成步骤较为繁琐。与之相比,不含大型共轭单元而仅含N、O、S、P等杂原子及C=O、C=N、C≡N、C=C等富电子单元的非典型发光化合物结构简单,可通过商购或简单反应获得。且许多非典型发光分子与生物体系密切相关,生物相容性良好,有利于后续应用^[2]。     

固相萃取-高效液相色谱法测定鱼组织中的吡喹酮和克螨特残留

吡喹酮和克螨特是新型抗寄生虫药,在水产养殖中被作为渔药复配剂。二者均为受热易分解物质,其残留分析可采用色谱法、光谱法以及生物检测法,但对二者的同时分离检测未见报道。本研究采用固相萃取-高效液相色谱SPE-HPLC同时测定了鱼组织中二者的残留。     

Study on the photodegradation and microbiological degradation of pirimicarb insecticide by using liquid chromatography coupled with ion-trap mass spectrometry

The intermediates of photodegradation and microbial degradation of pirimicarb insecticide were investigated by liquid chromatography coupled with ion-trap mass spectrometry (LC–IT-MS). Different intermediates were detected in the photodegradation and microbial degradation of pirimicarb. In the photodegradation of pirimicarb in aqueous solution 2-dimethylamino-5,6-dimethyl-4-hydroxypyrimidine (MW = 167), 2-methylamino-5,6-dimethylpyrimidin-4-yl-dimethylcarbamate (MW = 224) and 2-formylamino-5,6-dimethylpyrimidin-4-yl-dimethylcarbamate (MW = 252) were the main products. It was found that 2-dimethylamino-5,6-dimethyl-4-hydroxypyrimidine (MW = 167) was the major product in the microbial degradation of pirimicarb in soil.     

Blumlein双极脉冲形成线

 为了提高超宽带系统的辐射因子,对超宽带脉冲整形技术进行了深入研究,介绍了采用Blumlein线产生双极脉冲的高功率双极脉冲产生技术。对采用Blumlein线产生双极脉冲的原理进行了讨论,通过数值模拟分析了影响双极脉冲形成的主要因素。设计了一套Blumlein高功率双极脉冲形成线,在800 kV脉冲源上开展了高压实验研究,分析了开关及形成线长度对形双极脉冲的影响。在输入单极脉冲电压为652.0 kV、脉宽为2.1 ns的情况下,Blumlein双极脉冲形成线可以产生负峰电压为571.9 kV、正峰电压为550.4 kV、半周期为740 ps的双极脉冲,峰-峰值电压是入射脉冲峰值电压的1.72倍,辐射因子为4.54 MV。     

Study on the photocatalytic degradation of methyl orange in water using Ag/ZnO as catalyst by liquid chromatography electrospray ionization ion-trap mass spectrometry

A nanocrystal catalyst Ag/ZnO was successfully synthesized using a simple solvothermal method in this study. This catalyst was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results showed that this catalyst was composed of metallic Ag and ZnO. The photodegradation of methyl orange (MO) was investigated in aqueous suspension containing Ag/ZnO catalyst under UV irradiation. Liquid chromatography coupled with electrospray ionization ion-trap mass spectrometry was applied to the analysis of the samples coming from the photocatalytic degradation of MO. The experimental results showed that there were four intermediates existing in the photocatalytic reaction. MO could be mineralized in the Ag/ZnO suspension after 60 min illumination.     

Identification and quantitation of auxins in plants by liquid chromatography/electrospray ionization ion trap mass spectrometry

Auxin is an important phylohormone, which regulates specific physiological responses such as division, elongation and differentiation of cells. A new method using liquid chromatography/electrospray ionization ion trap mass spectrometry (LC/ESI-ITMS) has been developed for identification and quantitation of four auxins. Under the optimum conditions, four auxins (indole-3-acetic acid, indole-3-propionic acid, indole-3-butyric acid and 1-naphthylacetic acid) were completely separated and quantitated within 7 min with a minimum detection limit of 8.0 ng mL(-1) with relative standard deviations lower than 5.0%. This method also has been applied to analysis of auxins in Chinese cabbage where, even with a complicated serious background perturbation due to the natural biological matrix, the mean recoveries ranged from 77.5% to 99.8%. Finally, we discuss the MS-relevant properties of the identified auxins in detail.     

Synthesis of deuterium-enriched and fluorine-substituted plinabulin derivatives and evaluation of their antitumor activities

Deuterium-enriched and fluorine-substituted compounds have been widely applied in drug discovery due to their advantages in the studies of clinical pharmacokinetics and metabolic profiles. Herein we synthesized a library of deuterated and fluorine-substituted plinabulin derivatives, and all 15 D- or F-compounds were characterized by MS, \(^{1}\hbox {H}\) NMR and \(^{ 13}\hbox {C}\,\hbox {NMR}\). Their antitumor activities were evaluated against human Jurkat T lymphocyte cells.     

基于图像融合的动态轮廓线跟踪新方法

红外与可见光传感器是目标跟踪识别系统中常用的两种传感器,对这两种传感器图像进行融合能有效提高系统跟踪检测的准确性。将动态轮廓线模型与图像融合结合,在特征搜索过程中利用特征点准确地完成了图像配准,同时使用了一种新的特征级融合方法,将两种图像中目标轮廓的B样条曲线控制点进行实时微分耦合。这种耦合将Curwen提出的微分耦合机制作了改进,利用图像配准把刚性硬模板改变为实时的变换模板并推导了融合后动态轮廓线的新的动力学方程。这种融合利用了红外图像目标轮廓信息约束可见光图像中动态轮廓线的收敛形状,有效地提高了可见光图像目标跟踪的准确性。对运动人手序列图像的对比跟踪实验表明,这种融合使得可见光图像中动态轮廓线平均跟踪误差减小了60．25％。