全文获取类型
收费全文 | 32319篇 |
免费 | 270篇 |
国内免费 | 82篇 |
专业分类
化学 | 15632篇 |
晶体学 | 475篇 |
力学 | 1197篇 |
综合类 | 22篇 |
数学 | 4686篇 |
物理学 | 10659篇 |
出版年
2023年 | 77篇 |
2022年 | 396篇 |
2021年 | 634篇 |
2020年 | 545篇 |
2019年 | 732篇 |
2018年 | 1176篇 |
2017年 | 1270篇 |
2016年 | 1677篇 |
2015年 | 799篇 |
2014年 | 1378篇 |
2013年 | 2180篇 |
2012年 | 2065篇 |
2011年 | 2145篇 |
2010年 | 2210篇 |
2009年 | 2129篇 |
2008年 | 2212篇 |
2007年 | 2107篇 |
2006年 | 1814篇 |
2005年 | 1223篇 |
2004年 | 910篇 |
2003年 | 588篇 |
2002年 | 523篇 |
2001年 | 461篇 |
2000年 | 740篇 |
1999年 | 440篇 |
1998年 | 534篇 |
1997年 | 497篇 |
1996年 | 198篇 |
1995年 | 97篇 |
1994年 | 83篇 |
1993年 | 58篇 |
1992年 | 66篇 |
1991年 | 58篇 |
1990年 | 56篇 |
1989年 | 36篇 |
1988年 | 41篇 |
1987年 | 34篇 |
1986年 | 36篇 |
1985年 | 50篇 |
1984年 | 40篇 |
1983年 | 37篇 |
1982年 | 28篇 |
1981年 | 29篇 |
1980年 | 36篇 |
1979年 | 19篇 |
1978年 | 29篇 |
1977年 | 15篇 |
1976年 | 25篇 |
1975年 | 20篇 |
1974年 | 17篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Ana Luísa Daniel‐da‐Silva João Carlos Moura Bordado José Miguel Martín‐Martínez 《Journal of Polymer Science.Polymer Physics》2007,45(22):3034-3045
The degree of phase separation in several moisture‐cured poly(urethane urea)s (PUUs) was studied by FTIR spectroscopy, wide angle X‐ray diffraction (WAXD), and temperature‐modulated differential scanning calorimetry (TMDSC). This latter technique was shown to be particularly useful in analysing the degree of phase separation in PUU polymers. Both phase mixing and phase segregation coexisted in the PUUs and the degree of phase separation increased as the urea hard segment (HS) content in the PUU increased. The maximum solubility of urea HSs into the polyol soft segments (SSs) was achieved for 50 wt % urea HS content in diol‐based PUUs, whereas for triol‐based PUUs the highest solubility between HS and SS was reached for lower urea HS amount. Finally, the higher the urea HS content the higher the extent of phase separation in the PUU. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3034–3045, 2007 相似文献
2.
V. P. Ershov D. A. Kas’yanov V. I. Rodchenkov D. A. Sergeev 《Crystallography Reports》2008,53(2):339-343
The growth of the isolated (100) face of a KDP crystal at exposure of the phase boundary to the initial ultrasound field and a standing acoustic wave has been investigated. A significant growth response of this face, exposed to sound normally along the acoustic axis in the near zone of a piston-like half-wave vibrator with f = 20 kHz and tangentially in the pulsed two-frequency (f = 600 and 900 kHz) standing-wave mode, has been revealed. It is shown that the mechanisms of mass exchange enhancement in these acoustic modes are different. The results obtained show a fundamental possibility of controlling crystal growth and dissolution by varying the parameters of inhomogeneous acoustic field. 相似文献
3.
A. P. Voronov G. N. Babenko V. M. Puzikov A. D. Roshal’ V. I. Salo 《Crystallography Reports》2008,53(4):708-712
The features of doping of KDP crystals with cerium ions and organocerium complexes with alizarin complexon and arsenazo III have been investigated. It is established that “direct” doping by introducing cerium salts into the initial solution cannot be implemented. The effect of organometallic complexes of cerium on the crystal growth has been studied. Organocerium complexes predominantly enter the prismatic or pyramidal growth sectors. It is shown that the complex arsenazo III + Ce blocks the growth of the prismatic sector. Cerium-doped KDP crystals exhibit a photoluminescence band peaking at the wavelength λmax= 350 nm. 相似文献
4.
I. D. Lomako M. I. Danil’kevich D. V. Karpinskiĭ I. I. Makoed 《Crystallography Reports》2008,53(2):278-284
The experimental and calculated values of the optical permittivity ε∞ have been analyzed and generalized with allowance for the oxygen concentration and possible valences of Fe and O ions in YIG single crystals. It is shown that the deficit of oxygen ions in the samples is accompanied by a decrease in ε∞. A decrease in the gradient of distribution of Ba ions over the sample thickness decreases the difference between the calculated and experimental values. It is revealed that the ratio of the number of valence electrons to the number of core electrons, with regard to their polarizabilities, is proportional to the ratio of the incoherent and coherent X-ray scattering intensities, nk/k. 相似文献
5.
M. K. Bratenko Yu. V. Kadel’nik V. A. Chornous M. V. Vovk 《Russian Journal of Organic Chemistry》2008,44(2):247-250
Oximes of 4-(4-pyrazolyl)-3-buten-2-onees obtained by successive reaction of 3-aryl-4-formylpyrazoles with acetone and hydroxylamine at the treatment with iodine suffered an oxidative cyclization yielding 3-aryl-4-(5-isoxazolyl)pyrazoles. 相似文献
6.
7.
8.
A preconditioning approach based on the artificial compressibility formulation is extended to solve the governing equations for unsteady turbulent reactive flows with heat release, at low Mach numbers, on an unstructured hybrid grid context. Premixed reactants are considered and a flamelet approach for combustion modelling is adopted using a continuous quenched mean reaction rate. An overlapped cell‐vertex finite volume method is adopted as a discretisation scheme. Artificial dissipation terms for hybrid grids are explicitly added to ensure a stable, discretised set of equations. A second‐order, explicit, hybrid Runge–Kutta scheme is applied for the time marching in pseudo‐time. A time derivative of the dependent variable is added to recover the time accuracy of the preconditioned set of equations. This derivative is discretised by an implicit, second‐order scheme. The resulting scheme is applied to the calculation of an infinite planar (one‐dimensional) turbulent premixed flame propagating freely in reactants whose turbulence is supposed to be frozen, homogeneous and isotropic. The accuracy of the results obtained with the proposed method proves to be excellent when compared to the data available in the literature. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
9.
H. William Bosch Sre
o D. kapin Egon Matijevi 《Colloids and surfaces. A, Physicochemical and engineering aspects》2004,250(1-3):43-50
Controlled precipitation of the diagnostic imaging agent ethyl 3,5-di(acetylamino)-2,4,6-triiodobenzoate has been used to produce fine particles of various sizes, morphologies, and degrees of crystallinity, which depended on experimental conditions. In addition, two distinct polymorphic forms of the drug have been fully characterized by single crystal X-ray diffraction studies, and evidence for a third polymorph was also observed. Some of the so prepared dry particles were coated with a thin layer of silica. 相似文献
10.
A semiclassical theory of electromagnetically induced transparency in a Bose-Einstein condensate is considered. A nonlinear Schrödinger equation that describes the interaction of the Bose-Einstein condensate with an electromagnetic field is derived. An analysis of the obtained solutions to this equation demonstrates a decrease in the group velocity of the light pulse. 相似文献