全文获取类型
收费全文 | 59篇 |
免费 | 0篇 |
专业分类
化学 | 10篇 |
数学 | 23篇 |
物理学 | 26篇 |
出版年
2020年 | 1篇 |
2013年 | 1篇 |
2012年 | 1篇 |
2011年 | 1篇 |
2009年 | 2篇 |
2008年 | 1篇 |
2003年 | 1篇 |
2000年 | 11篇 |
1999年 | 1篇 |
1996年 | 1篇 |
1995年 | 5篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 8篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1980年 | 2篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1966年 | 1篇 |
1964年 | 1篇 |
1962年 | 1篇 |
1960年 | 1篇 |
1958年 | 2篇 |
排序方式: 共有59条查询结果,搜索用时 15 毫秒
1.
Kochocki JA Allison WW Alner GJ Ambats I Ayres DS Balka LJ Barr GD Barrett WL Benjamin D Border P Brooks CB Cobb JH Cockerill DJ Coover K Courant H Dahlin B DasGupta U Dawson JW Edwards VW Fields TH Kirby-Gallagher LM Garcia-Garcia C Giles RH Goodman MC Heller K Heppelman S Hill N Hoftiezer JH Jankowski DJ Johns K Joyce T Kafka T Litchfield PJ Lopez FV Lowe M Mann WA Marshak ML May EN McMaster L Milburn RH Miller W Napier A Oliver WP Pearce GF Perkins DH Peterson EA Price LE Roback D Rosen DB 《Physical review D: Particles and fields》1990,42(9):2967-2973
2.
Garcia Ruano JL Alcudia A del Prado M Barros D Maestro MC Fernandez I 《The Journal of organic chemistry》2000,65(10):2856-2862
The addition of the lithium anions derived from (R)- and (S)-methyl and -ethyl p-tolyl sulfoxides to (S)-N-benzylidene-p-toluenesulfinamide provides an easy access route to enantiomerically pure beta-(N-sulfinyl)amino sulfoxides. Stereoselectivity can be achieved when the configurations at the sulfur atoms of the two reagents are opposite (matched pair), thus resulting in only one diastereoisomer, even for the case in which two new chiral centers are created. The N-sulfinyl group primarily controls the configuration of the carbon bonded to the nitrogen, whereas the configuration of the alpha-sulfinyl carbanion seems to be responsible for the level of asymmetric induction, as well as for the configuration of the new stereogenic C-SO carbon in the reactions with ethyl p-tolyl sulfoxides. An efficient method for transforming the obtained beta-(N-sulfinyl)amino sulfoxides into optically pure beta-amino alcohols, based on the stereoselective non-oxidative Pummerer reaction, is also reported. 相似文献
3.
4.
Garcia Ruano JL Alemparte C Martin Castro AM Adams H Rodriguez Ramos JH 《The Journal of organic chemistry》2000,65(23):7938-7943
The behavior of (Z)-3-p-tolylsulfinylacrylonitrile (1) as a chiral dienophile has been evaluated from its reactions with furan and acyclic dienes. Electrostatic interactions of the cyano group with the sulfinyl one restrict the conformational mobility around the C-S bond, thus controlling the pi-facial selectivity, which is almost complete in all cases, the approach of the diene from the less-hindered face of the dienophile (that bearing the lone electron pair) in the predominant rotamer being the favored one. The regioselectivity is also completely controlled by the cyano group. Additionally, the reactivity of compound 1 as well as its endo-selectivity are both higher than those observed for the corresponding (Z)-3-sulfinylacrylates, thus proving the potential of sulfinylnitriles as chiral dienophiles. 相似文献
5.
6.
The space group of alpha(')-NaV2O5 turns below T(c) = 34 K from Pmmn with all V sites equivalent, into Fmm2 with three independent vanadium sites per layer. This is incompatible with models of charge ordering into V4+ and V5+. Our structure determination indicates that the phase transition consists of a charge ordering with three distinct valence states, formally V4+, V4.5+, and V5+. The singlet formation is not associated with dimerization on the spin ladder, but with the formation of spin clusters. Finally, we ascribe the quadrupling of the c axis to the large polarizability of the V2O5 skeleton. 相似文献
7.
Acoustic performance in ultrasonic transmitters can be improved by means of a suitable electrical driving response and matching/tuning networks. It is important to predict this electrical response, but doing so is not easy because it departs notably from the nominal pattern with the loading probes. In practice, the analysis of HV pulser spikes in NDE applications requires fairly complex models in the transient regime and, in addition, non-linear problems could arise, especially in the case of tuned transmitters. In this paper, the most relevant influences of loading characteristics of NDT ultrasonic probes on the pulser electrical driving responses are evaluated in time and frequency domains. Conventional pulse generators and typical NDE pulsers are considered. Driving responses are analysed across commercial ultrasonic probes and, alternatively, across similar purely electrical loads. Distinct influences on pulser responses from electrical and motional sections of the probes are identified. All these aspects are studied on the basis of experimental and computer results. 相似文献
8.
M. Derrick D. Krakauer S. Magill B. Musgrave J. Repond J. Schlereth R. Stanek R. L. Talaga J. Thron F. Arzarello et al. 《Zeitschrift fur Physik C Particles and Fields》1995,65(3):379-398
The ZEUS detector has been used to measure the proton structure functionF
2. During 1993 HERA collided 26.7 GeV electrons on 820 GeV protons. The data sample corresponds to an integrated luminosity of 0.54 pb–1, representing a twenty fold increase in statistics compared to that of 1992. Results are presented for 7Q
2<>4 GeV2 andx values as low as 3×10–4. The rapid rise inF
2 asx decreases observed previously is now studied in greater detail and persists forQ
2 values up to 500 GeV2.supported by Worldlab, Lausanne, Switzerland 相似文献
9.
W. J. Thron 《Mathematische Zeitschrift》1958,70(1):310-344
Ohne ZusammenfassungThis research was supported by the United States Air Force under Contract No. AF 49 (638)-100 monitored by the AF Office of Scientific Research of the Air Research and Development Command. 相似文献
10.