全文获取类型
收费全文 | 16081篇 |
免费 | 3162篇 |
国内免费 | 2373篇 |
专业分类
化学 | 11562篇 |
晶体学 | 246篇 |
力学 | 1022篇 |
综合类 | 204篇 |
数学 | 1818篇 |
物理学 | 6764篇 |
出版年
2024年 | 41篇 |
2023年 | 312篇 |
2022年 | 600篇 |
2021年 | 615篇 |
2020年 | 768篇 |
2019年 | 722篇 |
2018年 | 658篇 |
2017年 | 586篇 |
2016年 | 857篇 |
2015年 | 851篇 |
2014年 | 1013篇 |
2013年 | 1294篇 |
2012年 | 1594篇 |
2011年 | 1560篇 |
2010年 | 1172篇 |
2009年 | 1077篇 |
2008年 | 1219篇 |
2007年 | 1051篇 |
2006年 | 878篇 |
2005年 | 738篇 |
2004年 | 553篇 |
2003年 | 460篇 |
2002年 | 449篇 |
2001年 | 385篇 |
2000年 | 325篇 |
1999年 | 325篇 |
1998年 | 214篇 |
1997年 | 205篇 |
1996年 | 181篇 |
1995年 | 152篇 |
1994年 | 142篇 |
1993年 | 109篇 |
1992年 | 95篇 |
1991年 | 85篇 |
1990年 | 74篇 |
1989年 | 49篇 |
1988年 | 33篇 |
1987年 | 22篇 |
1986年 | 34篇 |
1985年 | 30篇 |
1984年 | 21篇 |
1983年 | 16篇 |
1982年 | 13篇 |
1981年 | 12篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1974年 | 4篇 |
1972年 | 2篇 |
1966年 | 2篇 |
1957年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
Let p ∈ [1, ∞), q ∈ [1, ∞), α∈ R, and s be a non-negative integer. Inspired by the space JNp introduced by John and Nirenberg(1961) and the space B introduced by Bourgain et al.(2015), we introduce a special John-Nirenberg-Campanato space JNcon(p,q,s) over Rn or a given cube of R;with finite side length via congruent subcubes, which are of some amalgam features. The limit space of such spaces as p →∞ is just the Campanato space which coincides with the space BMO(the space of functions with bounded mean oscillations)when α = 0. Moreover, a vanishing subspace of this new space is introduced, and its equivalent characterization is established as well, which is a counterpart of the known characterization for the classical space VMO(the space of functions with vanishing mean oscillations) over Rn or a given cube of Rn with finite side length.Furthermore, some VMO-H1-BMO-type results for this new space are also obtained, which are based on the aforementioned vanishing subspaces and the Hardy-type space defined via congruent cubes in this article. The geometrical properties of both the Euclidean space via its dyadic system and congruent cubes play a key role in the proofs of all these results. 相似文献
3.
Yujie Xiong 《中国科学:化学(英文版)》2022,65(1):5-6
Photoelectrochemical(PEC)technique represents a promising approach to chemical transformation by harvesting sustainable solar energy.Despite the wide applications of PEC systems such as environmental remediation and solar energy conversion,the reported PEC reactions are dominated by the radical-based processes that are initiated by the single electron transfer between photo-induced carriers and adsorbed species on photoelectrode surface[1,2].For instance,hydroxyl radicals are often involved in the PEC oxidation reactions.As well known,it is a grand challenge to control the formation and evolution rates of radicals,which inevitably leads to the unsatisfactory product selectivity of PEC reactions.Naturally,such a circumstance brings about a question to the research community whether a different mechanism can be established to sustain efficient and selective oxygenation.Recently,based on their previous findings on PEC water oxidation[3,4],Zhao and coworkers[5]reported that many substrates can be oxidized in an oxygen atom transfer(OAT)pathway,a non-radical two electron process,to oxygenated products byα-Fe2O3 photoanodes. 相似文献
4.
Meihua Shen Dr. Xinpeng Zhao Dr. Lu Han Nanxi Jin Prof. Song Liu Prof. Tao Jia Prof. Zhijun Chen Prof. Xiuhua Zhao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(20):e202104137
Solar-driven interfacial vaporization by localizing solar-thermal energy conversion to the air−water interface has attracted tremendous attention. In the process of converting solar energy into heat energy, photothermal materials play an essential role. Herein, a flexible solar-thermal material di-cyan substituted 5,12-dibutylquinacridone (DCN−4CQA)@Paper was developed by coating photothermal quinacridone derivatives on the cellulose paper. The DCN−4CQA@Paper combines desired chemical and physical properties, broadband light-absorbing, and shape-conforming abilities that render efficient photothermic vaporization. Notably, synergetic coupling of solar-steam and solar-electricity technologies by integrating DCN−4CQA@Paper and the thermoelectric devices is realized without trade-offs, highlighting the practical consideration toward more impactful solar heat exploitation. Such solar distillation and low-grade heat-to-electricity generation functions can provide potential opportunities for fresh water and electricity supply in off-grid or remote areas. 相似文献
5.
Mathematical Programming - We seek tight bounds on the viable parallelism in asynchronous implementations of coordinate descent that achieves linear speedup. We focus on asynchronous coordinate... 相似文献
6.
Interactions of the vector breathers for the coupled Hirota system with $$4\times 4$$ 4 × 4 Lax pair
Nonlinear Dynamics - In this paper, we investigate the interactions of the vector breathers for the coupled Hirota system with $$4\times 4$$ Lax pair. Firstly, we give the first-order breather... 相似文献
7.
Dr. Qing Xu Dr. Shanshan Tao Dr. Qiuhong Jiang Prof. Donglin Jiang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(11):4587-4593
A strategy based on covalent organic frameworks for ultrafast ion transport involves designing an ionic interface to mediate ion motion. Electrolyte chains were integrated onto the walls of one-dimensional channels to construct ionic frameworks via pore surface engineering, so that the ionic interface can be systematically tuned at the desired composition and density. This strategy enables a quantitative correlation between interface and ion transport and unveils a full picture of managing ionic interface to achieve high-rate ion transport. Moreover, the effect of interfaces was scaled on ion transport; ion mobility is increased in an exponential mode with the ionic interface. This strategy not only sets a benchmark system but also offers a general guidance for designing ionic interface that is key to systems for energy conversion and storage. 相似文献
8.
Yin Pengpeng Liu Chang Wang Ying Guan Lei Chen Xian Xiong Xuejia Jin Hongzhe 《Russian Journal of General Chemistry》2021,91(5):897-903
Russian Journal of General Chemistry - A dinuclear Tb complex, Tb2(H2L)3(phen)2 (1), and two similar N-donor coordination complexes, Fe(phen)3·HL (2), Fe(bipy)3·HL·5H2O (3) (Na2H2L =... 相似文献
9.
随着经济的飞速发展,社会对能源的需求日益扩大,对工业废水的无害化处理也提出了更高的要求。光催化燃料电池 (photocatalytic fuel cell, PFC) 在燃料电池中引入半导体光催化材料作为电极,实现了有机污染物高效降解和同步对外产电的双重功能,在废水无害化与资源化利用方面具有潜在的应用价值。半导体光催化电极是PFC系统高效运行的核心组件,增强其可见光响应和光生载流子分离是提高PFC性能的关键策略。反应器结构设计和运行参数优化也有利于改善PFC性能。本文从PFC基本原理和应用入手,综述了PFC在环境污染物资源化处理中的研究进展,并详细阐述了提高PFC的污染控制性能和产电效率的优化手段,为进一步设计高效稳定的PFC系统并实现其在水污染控制和清洁能源生产中的应用提供理论指导。 相似文献
10.