全文获取类型
收费全文 | 703篇 |
免费 | 27篇 |
国内免费 | 1篇 |
专业分类
化学 | 505篇 |
晶体学 | 4篇 |
力学 | 21篇 |
数学 | 62篇 |
物理学 | 139篇 |
出版年
2023年 | 6篇 |
2022年 | 11篇 |
2021年 | 27篇 |
2020年 | 14篇 |
2019年 | 22篇 |
2018年 | 13篇 |
2017年 | 15篇 |
2016年 | 37篇 |
2015年 | 25篇 |
2014年 | 25篇 |
2013年 | 52篇 |
2012年 | 31篇 |
2011年 | 41篇 |
2010年 | 30篇 |
2009年 | 34篇 |
2008年 | 54篇 |
2007年 | 35篇 |
2006年 | 39篇 |
2005年 | 23篇 |
2004年 | 23篇 |
2003年 | 16篇 |
2002年 | 16篇 |
2001年 | 8篇 |
2000年 | 5篇 |
1999年 | 9篇 |
1998年 | 4篇 |
1997年 | 12篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1984年 | 2篇 |
1982年 | 2篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 7篇 |
1975年 | 6篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1972年 | 3篇 |
1971年 | 4篇 |
1970年 | 2篇 |
1969年 | 3篇 |
1967年 | 2篇 |
排序方式: 共有731条查询结果,搜索用时 15 毫秒
1.
K.V. Stepurska О.О. Soldatkin I.S. Kucherenko V.M. Arkhypova S.V. Dzyadevych A.P. Soldatkin 《Analytica chimica acta》2015
This study was aimed at the development of a conductometric biosensor based on acetylcholinesterase considering the feasibility of its application for the inhibitory analysis of various toxicants. In this paper, the optimum conditions for enzyme immobilization on the transducer surface are selected as well as the optimum concentration of substrate for inhibitory analysis. Sensitivity of the developed biosensor to different classes of toxic compounds (organophosphorus pesticides, heavy metal ions, surfactants, aflatoxin, glycoalkaloids) was tested. It is shown that the developed biosensor can be successfully used for the analysis of pesticides and mycotoxins, as well as for determination of total toxicity of the samples. A new method of biosensor analysis of toxic substances of different classes in complex multicomponent aqueous samples is proposed. 相似文献
2.
Tanja Vidaković-Koch Tamara Miličić Luka A. Živković Hoon Seng Chan Ulrike Krewer Menka Petkovska 《Current Opinion in Electrochemistry》2021
The nonlinear frequency response analysis (NFRA) can be seen as an extension of electrochemical impedance spectroscopy. NFRA gives a full and detailed representation of the system response and can establish a connection between model parameters and the experimentally observed phenomena. In this article, different theoretical NFRA approaches and the most recent application examples are discussed. A simple electrochemical example is used to showcase the benefits and disadvantages of analyzing the system response by using different approaches. In addition, it was shown how to extract experimental harmonic values and analyze them. 相似文献
3.
The kinetics of formation and relaxation of transient holographic gratings recorded in a system of saturable three-level centers is studied. Distortions in the shape of the profile of recorded and decaying structures of population and of the refractive index are taken into account. The analysis of the time dependences of diffraction efficiencies of different orders is performed for phase (thermal) and amplitude (concentration) gratings. 相似文献
4.
W Y Hung S Kucherenko N J Samsatli N Shah 《The Journal of the Operational Research Society》2004,55(8):801-813
In this paper, we present a new modelling approach for realistic supply chain simulation. The model provides an experimental environment for informed comparison between different supply chain policies. A basic simulation model for a generic node, from which a supply chain network can be built, has been developed using an object-oriented approach. This generic model allows the incorporation of the information and physical systems and decision-making policies used by each node. The object-oriented approach gives the flexibility in specifying the supply chain configuration and operation decisions, and policies. Stochastic simulations are achieved by applying Latin Supercube Sampling to the uncertain variables in descending order of importance, which reduces the number of simulations required. We also present a case study to show that the model is applicable to a real-life situation for dynamic stochastic studies. 相似文献
5.
A complete study of the spectrum of a finite-dimensional Bose operator is carried out in the paper. The cases in which the
spectrum is discrete or continuous are studied.
Translated fromMatematicheskie Zametki, Vol. 61, No. 6, pp. 835–854, June, 1997.
Translated by A. M. Chebotarev 相似文献
6.
7.
E. S. Filatov S. V. Sysoev Ludmila N. Zelenina Tamara P. Chusova V. A. Logvinenko P. P. Semyannikov I. K. Igumenov 《Journal of Thermal Analysis and Calorimetry》2006,86(2):537-539
Thermal behaviour
of a series of lithium β-diketonates: Li(dpm) (dpm=dipivaloylmethanate
(2,2,6,6-tetramethylheptane-3,5- dionate)), Li(pta) (pta=pivaloyltrifluoracetonate
(2,2-dimethyl-6,6,6-trifluoro-3,5-hexanedionate)), Li(tfa) (tfa=trifluoracetylacetonate
(1,1,1-trifluoro-2,4-pentandionate)), Li(hfa) (hfa=hexafluoracetylacetonate
(1,1,1,5,5,5-hexafluoro-2,4-pentandionate)) has been investigated. Gas phase
composition of these complexes has been established. Temperature dependences
of vapor pressure of lithium compounds were obtained by static and dynamic
methods, and thermodynamic parameters were calculated. Dependence of compound
volatility on ligand structure is shown. For Li(dpm) detailed investigation
has been done by differential scanning calorimetry (DSC). 相似文献
8.
9.
Tamara Elzein Virginie Kreim Achraf Ghorbal Sophie Bistac 《Journal of Polymer Science.Polymer Physics》2006,44(22):3272-3281
Friction‐deposited layers of atactic polystyrene (PS) on inert and OH‐grafted gold substrates were the subject of this study to establish a relationship between the friction process and the resulting anisotropy of the transferred polymer chains. We show, by using polarization‐modulation infrared reflection‐absorption spectroscopy that the deposited PS chains involve an anisotropy in which PS main backbone is rather perpendicular to the friction support, fact that is surprising when compared with the majority of polymers where the anisotropy is along the sliding direction. Moreover, our calculation of the orientation angles revealed that PS chains are more perpendicular in the transferred layers than in spin‐coated films. This particular anisotropy is probably due to a parallel reorientation of the phenyl ring on the friction support whatever the surface chemistry is. On the other hand, this study was useful to rectify the assignment of infrared bands unclearly reported in the literature. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3272–3281, 2006 相似文献
10.
John R. Peterson Tamara J. Winter Hoang D. Do Robin D. Rogers 《Journal of chemical crystallography》1989,19(1):135-145
Structural and conformational information obtained from the crystal structure and solution1H nmr investigations of the title compound are compared. The 4-aryltetralone, C24H24O10, crystallizes as a chloroform solvate in the monoclinic space group, P21/n, witha=12.519(4),b=17.938(6),c=12.534(9)Å,=111.90(5)°, and Dcalc=1.51 g cm–3 forZ=4. The data for this compound were collected at –150°C. Least-squares refinement of 2796 observed [F
o5(F
o)] reflections led to the final agreement index ofR=0.062. A threefold static disorder was observed for one of the carboxyl groups. The second carboxyl group participates in an intramolecular hydrogen bond and is thus ordered. The1H nmr spectrum revealed the title compound to exist as a keto-enol tautomeric mixture in solution. Vicinal hydrogen coupling constant analysis proved reliable in ascertaining B-ring stereochemistry of 2,3-disubstituted-4-aryltetralones. 相似文献