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1.
The turbulent flow in a compound meandering channel with a rectangular cross section is one of the most complicated turbulent flows, because the flow behaviour is influenced by several kinds of forces, including centrifugal forces, pressure‐driven forces and shear stresses generated by momentum transfer between the main channel and the flood plain. Numerical analysis has been performed for the fully developed turbulent flow in a compound meandering open‐channel flow using an algebraic Reynolds stress model. The boundary‐fitted coordinate system is introduced as a method for coordinate transformation in order to set the boundary conditions along the complicated shape of the meandering open channel. The turbulence model consists of transport equations for turbulent energy and dissipation, in conjunction with an algebraic stress model based on the Reynolds stress transport equations. With reference to the pressure–strain term, we have made use of a modified pressure–strain term. The boundary condition of the fluctuating vertical velocity is set to zero not only for the free surface, but also for computational grid points next to the free surface, because experimental results have shown that the fluctuating vertical velocity approaches zero near the free surface. In order to examine the validity of the present numerical method and the turbulent model, the calculated results are compared with experimental data measured by laser Doppler anemometer. In addition, the compound meandering open channel is clarified somewhat based on the calculated results. As a result of the analysis, the present algebraic Reynolds stress model is shown to be able to reasonably predict the turbulent flow in a compound meandering open channel. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
2.
Yoshiyuki Watabe Takuya Kondo Hiroe Imai Masatoshi Morita Nobuo Tanaka Jun Haginaka Ken Hosoya 《Analytical sciences》2004,20(1):133-137
A new high-performance liquid chromatography (HPLC) method has been developed to detect ultra-low concentrations of bisphenol-A (BPA) (below 1 ng/L (ppt)) using column switching electrochemical detection (ECD). The results were superior to those obtained from manual pretreatment procedure with membrane stationary phase. BPA is inherently ubiquitous in the environment, including tools and solvents used for its analysis; to obtain meaningful results, therefore, the concentration of the overall BPA contamination must be below the detection limit for BPA using the analytical system. Therefore, purified water for preparing the standard BPA solution must be filtered with a hydrophobic membrane to suppress BPA background levels of contamination. In addition, we investigated methods for effectively preserving environmental water containing BPA. The addition of a small amount of ethylenediaminetetraacetic acid (EDTA) provided good recovery even after overnight storage. By employing these precautionary measures and procedures to reduce BPA contamination from the analytical procedure, we could accurately determine l(-10) ppt of BPA in environmental water samples using a column switching HPLC system. 相似文献
3.
A new monitoring system for bacterial communities involving dimethylarsinic acid (DMAA) decomposition was provided by combining the MPN (Most Probable Number) method and RFLP (restriction-fragment-length polymorphism analysis). The abundance of DMAA decomposing bacteria was estimated by the MPN method using a bacterial culture medium, which included DMAA as the sole carbon source, indicating bacterial cell densities of 1700 cells/ml in Lake Kahokugata and 330 cells/ml in Lake Kibagata. After isolating the dominant bacteria using agar plates, the isolates were classified into some genotype groups by RFLP analysis using 16S rDNA sequences. Classification of the RFLP analysis indicated that 14 isolates of Lake Kahokugata were classified into 6 types, which included 2 dominant types related to genus Pseudomonas, while 8 isolates of Lake Kibagata displayed 6 types including one or two isolates. Moreover, the RFLP types were unique for each lake, suggesting that DMAA decomposing bacteria were specific for the aquatic environment related to the arsenic cycle. The activities of DMAA decomposition mostly matched with the RFLP type category of the isolates. Accordingly, combining the MPN method with the RFLP analysis will play an important role in elucidating the distributions and dynamics of the DMAA-decomposing bacterial community. 相似文献
4.
Arthur G. Maki John C. Grecu Brenda Winnewisser Manfred Winnewisser 《Journal of Molecular Spectroscopy》2003,222(2):198-212
High-resolution spectra of 15N12C12C15N and 14N13C13C14N have been measured and analyzed from 200 to 3600 cm−1. All the vibrational levels below 900 cm−1 have been observed and characterized. The Fermi resonance between ν2 and 2ν4 has been studied and the resonance constant has been determined for several cases. Several Σ− states have been directly observed for the first time for each isotopomer, the (0001111)0f, (0011111)0f, and (0002222)0f states. The pattern of the energy levels for clusters of l-type resonance coupled levels, such as 0001131,3, has been determined for cyanogen for the first time. Among other things this involved the determination of the vibrational l-type resonance constant, r45. Many of the power series constants, αi and xij, and higher order constants have been determined. 相似文献
5.
Takuya Hashimoto Koichi Kitazawa Masaaki Nakabayashi Tadashi Shiraishi Youichi Suemune Takakazu Yamamoto Hideomi Koinuma 《应用有机金属化学》1991,5(4):325-330
For low-temperature deposition of oxide films relating to Bi-Sr-Ca-Cu-O superconductors, photo-absorption and -decomposition properties were examined with respect to copper and alkaline-earth ß-diketonates. It was confirmed that all ß-diketonates examined were promising as source materials for photochemical vapour deposition (photo-CVD) using a low-pressure mercury lamp, in view of their large light absorption coefficients at wavelength 254 nm. The light irradiation was effective for the formation of highly crystalline oxide films at temperatures below 600 °C. By combining two sources, Ca2CuO3 and SrCuO2 films were prepared. Photo-CVD of c-axis oriented Bi2Sr2CuOx film was achieved by the irradiation of ternary sources of Bi(C6H5)3 and strontium and copper ß-diketonates at 500 °C. 相似文献
6.
The DNA complexes of triostin A, echinomycin, and the monoquinoline (1QN) and bisquinoline (2QN) biosynthesized derivatives of echinomycin were investigated by optical detection of triplet-state magnetic resonance (ODMR) spectroscopy, with the quinoxaline and quinoline moieties of the DNA-binding peptides used as intrinsic probes. Plots of zero-field splitting (zfs)D parameter versus monitored wavelength revealed heterogeneity in the phosphorescence emission of echinomycin, triostin A, and 2QN ascribed to the occurrence of major and minor forms of the peptides in aqueous solution. ODMR results, in conjunction with findings from phosphorescence studies, indicate that the quinoxaline and quinoline chromophores of the major forms of the peptides are involved in aromatic stacking interactions in complexes with the natural DNAs fromMicrococcus lysodeikticus, Escherichia coli, and calf thymus as evidenced by red shifts in the phosphorescence 0,0 bands of the drugs, reductions in the phosphorescence lifetimes and zfsD andE parameters, and polarity reversal of the ODMR slow passage signals upon drug complexation. The reversal in ODMR signal polarity of echinomycin and 2QN is a consequence of changes in the triplet-state sublevel decay constants upon peptide binding to the natural DNAs. The extent of reduction of theD parameter for the major form of echinomycin, 2QN, and the quinoline moiety of 1QN upon complexation with polymeric DNAs was found to correlate with the binding affinities measured for these targets [1], but no correlation was found for the quinoxaline moiety of 1QN. Preliminary studies of triostin A-DNA complexes also revealed no correlation between the reduction in zfsD-value upon complexation and binding affinity, although the largest reductions inD-value among the peptides investigated in this report were exhibited by the poly(dG-dC)·poly(dG-dC) and natural DNA complexes of triostin A. 相似文献
7.
8.
The average heat transfer rates were measured for natural convection of air in a shallow cylindrical enclosure heated from below and cooled from above in a bore space of an inclined super-conducting magnet. Depending on the location of the enclosure in the bore space, the angle of inclination and the strength of magnetic field, the net acceleration force could be arbitrarily varied and in this report, two locations where mostly axial magnetizing force prevails were selected. The average heat transfer rates varied with the angle of inclination due to the change in the total net acceleration of gravitational and magnetizing forces. Numerical computations were also carried out for the similar system under the combined magnetizing and gravitational forces and the computed average Nusselt numbers agreed mostly with the measured results. Detailed flow modes were graphically presented for the computed cases. 相似文献
9.
Takuya Hasegawa Hirotaka Matsuura Kazumi Inagaki Hiroki Haraguchi 《Analytical sciences》2003,19(1):147-150
The major-to-ultratrace elements in human bone-marrow fluid were determined by ICP-AES (inductively coupled plasma atomic emission spectrometry), and ICP-MS (inductively coupled plasma mass spectrometry). The bone-marrow fluid sample was centrifuged prior to acid digestion to exclude the bone piece from bone marrow, and then digested with nitric acid. As a result, 20 elements could be determined over the concentration range from 1610 microg g(-1) for Na to 0.00043 microg g(-1) for W. It was found that Fe, Zn and Sb were enriched by ca. 264-, 7- and 15-fold, respectively, in bone-marrow fluid, compared to those in human blood serum. Alkali metals (K, Rb, Cs), except for Na, were also significantly enriched in bone-marrow fluid. Furthermore, the concentrations of various elements, such as Fe, P, Al, Zn, Cu, Se, Zr, Sn, Ag and W, were significantly higher than those in open seawater. 相似文献
10.
Arthur Maki Robert L. Sams Jeffrey Barber Engelene t.H. Chrysostom Alfons Weber 《Journal of Molecular Spectroscopy》2004,225(2):109-122
Several new infrared absorption bands for 32S16O3 have been measured and analyzed. The principal bands observed were ν1+ν2 (at 1561 cm−1), ν1+ν4 (at 1594 cm−1), ν3+ν4 (at 1918 cm−1), and 3ν3 (at 4136 cm−1). Except for 3ν3, these bands are very complicated because of (a) the Coriolis coupling between ν2 and ν4, (b) the Fermi resonance between ν1 and 2ν4, (c) the Fermi resonance between ν1 and 2ν2, (d) ordinary l-type resonance that couples levels that differ by 2 in both the k and l quantum numbers, and (e) the vibrational l-type resonance between the A1′ and A2′ levels of ν3+ν4. The unraveling of the complex pattern of these bands was facilitated by a systematic approach to the understanding of the various interactions. Fortunately, previous work on the fundamentals permitted good estimates of many constants necessary to begin the assignments and the fit of the measurements. In addition, the use of hot band transitions accompanying the ν3 band was an essential aid in fitting the ν3+ν4 transitions since these could be directly observed for only one of four interacting states. From the hot band analysis we find that the A1′ vibrational level is 3.50 cm−1 above the A2′ level, i.e., r34=1.75236(7) cm−1. In the case of the 3ν3 band, the spectral analysis is straightforward and a weak Δk=±2, Δl3=±2 interaction between the l3=1 and l3=3 substates locates the latter A1′ and A2′ “ghost” states 22.55(4) cm−1 higher than the infrared accessible l3=1 E′ state. 相似文献