全文获取类型
收费全文 | 229篇 |
免费 | 14篇 |
专业分类
化学 | 179篇 |
晶体学 | 2篇 |
力学 | 7篇 |
数学 | 7篇 |
物理学 | 48篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 6篇 |
2019年 | 13篇 |
2018年 | 4篇 |
2017年 | 6篇 |
2016年 | 12篇 |
2015年 | 12篇 |
2014年 | 8篇 |
2013年 | 10篇 |
2012年 | 16篇 |
2011年 | 20篇 |
2010年 | 8篇 |
2009年 | 8篇 |
2008年 | 16篇 |
2007年 | 18篇 |
2006年 | 8篇 |
2005年 | 11篇 |
2004年 | 15篇 |
2003年 | 7篇 |
2002年 | 8篇 |
2001年 | 6篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1995年 | 5篇 |
1994年 | 1篇 |
1992年 | 2篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有243条查询结果,搜索用时 15 毫秒
1.
Hiroaki Miyagawa Michael J. Rich Lawrence T. Drzal 《Journal of Polymer Science.Polymer Physics》2004,42(23):4391-4400
The thermophysical and mechanical properties of a nanocomposite material composed of amine‐cured diglycidyl ether of bisphenol A (DGEBA) reinforced with organomontmorillonite clay are reported. The storage modulus at 100 °C, which was above the glass‐transition temperature (Tg), increased approximately 350% with the addition of 10 wt % (6.0 vol %) of clay. Below the Tg, the storage modulus at 30 °C increased 50% relative to the value of unfilled epoxy. It was determined that the Tg linearly increased as a function of clay volume percent. The tensile modulus of epoxy at room temperature increased approximately 50% with the addition of 10 wt % of clay. The reinforcing effect of the organoclay nanoplatelets is discussed with respect to the Tandon–Weng and Halpin–Tsai models. A pseudoinclusion model is proposed to describe the behavior of randomly oriented, uniformly dispersed platelets in nanocomposite materials. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4391–4400, 2004 相似文献
2.
Momoko Ishida Rika Ohara Fuka Miyagawa Hiroe Kikuzaki Kosuke Nishi Hiroyuki Onda Nanami Yoshino Takuya Sugahara 《Molecules (Basel, Switzerland)》2022,27(13)
Cuminum cyminum L. (cumin) is an annual plant of the Umbelliferae family native to Egypt. We previously showed that the aqueous extract of cumin seeds suppresses degranulation by downregulating the activation of antigen-induced intracellular signaling molecules in rat basophilic leukemia RBL-2H3 cells. However, the active substances in the extract have not yet been identified. Accordingly, herein, we aimed to ascertain the water-soluble substances present in cumin seeds that inhibit degranulation, which led to the identification of umbelliferose, a characteristic trisaccharide present in plants of the Umbelliferae family. Our study is the first to reveal the degranulation-suppressing activity of umbelliferose, and quantification studies suggest that cumin seed powder contains 1.6% umbelliferose. Raffinose, an isomer of umbelliferose, was also found to significantly suppress antigen-induced degranulation, but less so than umbelliferose. Both umbelliferose and raffinose contain sucrose subunits in their structures, with galactose moieties bound at different sites. These differences in structure suggest that the binding of galactose to the sucrose subunit at the α1-2 bond contributes to its strong degranulation-inhibiting properties. 相似文献
3.
The pressure-temperature phase diagram of the organic Mott insulator kappa-(ET)2Cu2(CN)3, a model system of the spin liquid on triangular lattice, has been investigated by 1H NMR and resistivity measurements. The spin-liquid phase is persistent before the Mott transition to the metal or superconducting phase under pressure. At the Mott transition, the spin fluctuations are rapidly suppressed and the Fermi-liquid features are observed in the temperature dependence of the spin-lattice relaxation rate and resistivity. The characteristic curvature of the Mott boundary in the phase diagram highlights a crucial effect of the spin frustration on the Mott transition. 相似文献
4.
Takayama K Arakida Y Dixit T Iwashita T Kono T Nakamura E Otsuka K Shimosaki Y Torikai K Wake M 《Physical review letters》2007,98(5):054801
We report an experimental demonstration of the induction synchrotron, the concept of which has been proposed as a future accelerator for the second generation of neutrino factory or hadron collider. The induction synchrotron supports a superbunch and a superbunch permits more charge to be accelerated while observing the constraints of the transverse space-charge limit. By using a newly developed induction acceleration system instead of radio-wave acceleration devices, a single proton bunch injected from the 500 MeV booster ring and captured by the barrier bucket created by the induction step voltages was accelerated to 6 GeV in the KEK proton synchrotron. 相似文献
5.
Naoto Sato Taiki Hayashi Kazuma Tochigi Prof. Hiroaki Wada Prof. Atsushi Shimojima Prof. Kazuyuki Kuroda 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(33):7860-7865
Eight corners of a double-four ring cage-type germanoxane, containing a fluoride ion, were successfully silylated by the combination of chlorosilanes and silazanes. Three different silyl groups, trimethylsilyl, dimethylsilyl, and dimethylvinylsilyl, were attached on the corners of germanoxane cage. The solubility and reactivity of the cage modified with dimethylvinylsilyl groups were significantly increased, allowing for further reaction. Hydrosilylation reaction between dimethylvinylsilylated cage geramanoxanes and dimethylsilylated cage siloxanes afforded porous solids. Functionalization of the corners of germanoxanes with silyl groups should provide valuable building blocks in various functional materials. 相似文献
6.
7.
8.
Michael Andreas Tandiary Masashi Asano Taiki Hattori Satoshi Takehira Yoichi Masui Makoto Onaka 《Tetrahedron letters》2017,58(20):1925-1928
The solid acid, tin hydroxide-embedded montmorillonite, catalyzes the unprecedented alkylation of various silicon enolates with primary, secondary and tertiary benzylic alcohols as well as secondary allylic alcohols. The acid catalysis of Sn-Mont was not only higher than that of the other ion-exchanged montmorillonites (M-Mont; M = H, Ti, Fe and Al), but also higher than that of the typical homogeneous acid catalysts such as BF3·OEt2, TMSOTf and TfOH. 相似文献
9.
We consider a problem of allocating indivisible objects when agents may desire to consume more than one object and no monetary
transfers are allowed. We are interested in allocation rules that satisfy desirable properties from an economic and social
point of view. In addition to strategy-proofness and Pareto efficiency, we consider consistency and two solidarity properties
(replacement-domination and population-monotonicity). In most of the cases, these properties are satisfied only by serially
dictatorial rules.
Received: November 1999/Final version: December 2001 相似文献
10.
Nanocomposite materials consisting of an epoxy matrix and silicate clay particles have been processed and characterized mechanically.
The clay material used was a modified natural montmorillonite. The clay particles consisted of 1 nm thick layers with aspect
ratios in the range of 100–1000. The clay particles were mixed with acetone and sonicated, then mixed with the polymer, deaerated
and cured. The ultimate objective of processing was to produce a polymer/clay nanocomposite with separated (exfoliated) platelets,
dispersed as uniformly as possible. Samples were prepared with clay concentrations of up to 10 wt%. The process used resulted
in limited exfoliation but mostly intercalation, i.e., infusion of polymer between the silicate layers and increase of interlayer
spacing. The characteristics of the nanocomposite were assessed by transmission electron microscopy and x-ray diffraction.
Results from these observations show that the basal spacing of clay platelets increased from an initial pre-processing value
of 1.85 nm to 4.5 nm. Enhancement of mechanical properties was measured by tensile testing of coupons. Stiffness increases
of up to 50% over that of the unfilled epoxy were measured for clay concentrations of 5 wt%. Strength increases were also
measured for low clay concentrations and low strain rate loading. Micromechanics modeling of mechanical behavior is discussed
as a function of clay platelet dispersion. 相似文献