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1.
2.
Formation of porous polymer morphology by microsyneresis during divinylbenzene polymerization 下载免费PDF全文
Libuše Hanková Ladislav Holub Karel Jeřábek 《Journal of Polymer Science.Polymer Physics》2015,53(11):774-781
This article describes the investigation of the importance of various reaction conditions on microsyneretic pore formation during polymerization of divinylbenzene (DVB) under so‐called “solvothermal” conditions. To induce microsyneretic pore formation, the most important parameter is an unusually high dilution of monomers with a “good” porogen solvating the polymer chains. High dilution and solvation of the growing poly(DVB) chains promote the prolongation of the polymer chains rather than their interconnection by crosslinking. Consequently, when the polymer gel density reaches the point where syneresis starts, the polymer network is geometrically too extensive to be broken up into precipitating entities and, instead, porogen droplets are formed within the continuous polymer gel. The pore geometry created by microsyneresis offers high surface area in wide mesopores and hence, high capacity for supporting functional groups or reactions with much better accessibility than narrow pores between polymer microspheres produced by macrosyneresis in conventional styrenic polymer supports. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 774–781 相似文献
3.
N. Raju T. Špaček J. Ježek I. M. Caminiti F. Leinisch K. Hideg P. Ježek W. E. Trommer 《Applied magnetic resonance》2006,30(3-4):373-383
Electron paramagnetic resonance (EPR) spectroscopy of spin-labeled fatty acids was used to investigate their interaction withEscherichia coli-expressed human mitochondrial uncoupling protein UCP2 refolded from inclusion bodies in nonaethylene glycol monododecyl ether (C12E9) micelles. 5-DOXYL-stearic acid and 4-PROXYL-palmitic acid bound to UCP2 exhibited additional clearly separated h+1I, h?1I “immobile” peaks in the low- and high-field region, respectively, separated by 42 and 44 Gauss, and extensively reduced h+1M, h?1M “mobile” peaks, separated by about 30 G, whereas with 7-DOXYL-stearic acid the I and M peaks were smoothed together into one wide peak. Competition of 4-PROXYL-palmitic acid with added palmitic acid, arachidonic acid, and all-cis-8,11,14-eicosatrienoic acid and of 7-DOXYL-stearic acid with arachidonic acid was indicated by the disappearance of the h+1I, h?1I “immobile” peaks, whereas redistribution in micelles without protein was indicated by the rising of the h+1M, h?1M “mobile” peaks. In conclusion, a competition of palmitic, arachidonic, and eicosatrienoic acid within a putative fatty acid binding site was observed for mitochondrial uncoupling protein UCP2. This finding together with the observation of EPR spectra of highly immobilized probes exclusively in the presence of the recombinant UCP2 suggest the existence of a fatty acid binding site on UCP2 which is a prerequisite of the fatty acid cycling mechanism as previously postulated for UCP1. 相似文献
4.
J. Ježek 《Czechoslovak Mathematical Journal》2004,54(1):233-246
We investigate congruences in one-element extensions of algebras in the variety generated by tournaments. 相似文献
5.
We prove that a finite unary algebra with at least two operation symbols is a homomorphic image of a (finite) subdirectly
irreducible algebra if and only if the intersection of all its subalgebras which have at least two elements is nonempty.
While working on this paper the first and the third authors were partially supported by the Grant Agency of the Czech Republic,
grant #201/02/0594, and by the institutional grant MSM0021620839; the second author was supported by the Ministry of Science,
Technologies and Development of Republic of Serbia, grant no. 1227. 相似文献
6.
A. Paulenová P. Rajec M. Ježíková 《Journal of Radioanalytical and Nuclear Chemistry》1998,228(1-2):119-122
The ultrafiltration preconcentration of Cd2+ using micellar extraction with 8-hydroxyquinoline (8-HQ), solubilized in anionic micelles of sodium dodecylsulphate (SDS)) were studied. The n-butanol was used as a co-surfactant. Ultrafiltration yields (R, %) on cellulose acetate membranes (wet, 20000 MW-CO) under 400 kPa pressure were determined. Distribution ratios (D) of cadmium between bulk liquid phase and micellar pseudophase were estimated. The constants (app.) for the cadmium-sodium exchange on SDS micelles surface at pH values of 4.8 and 5.3 (3.36 and 3.86, respectively) were determined. It was found, that the values of ultrafiltration yields of the cadmium (at constant concentration of 8-HQ) are influenced not only by the pH and by the concentration values, but also by the ratio of the concentrations of the metal and the anionic surfactant. 相似文献
7.
A. Paulenová P. Rajec M. Ježíková J. Kučera 《Journal of Radioanalytical and Nuclear Chemistry》1996,211(1):145-152
The preconcentration of cadmium from aqueous colloid solution containing 8-hydroxyquinoline as extractant, laurylsulphate natrium as surfactant,n-butanol as co-surfactant was performed using micellar ultrafiltration technique. Filters with different pore size and materials were used to achieve a separation from liquid solutions. The cadmium recoveries depending on different conditions (pH, concentration of surfactant) were determined and the results are explained in the terms of colloidal parameters in the compare with the classical solvent extraction. 相似文献
8.
M. Ježabek J. Karczmarczuk M. Rożańska 《Zeitschrift fur Physik C Particles and Fields》1985,29(1):55-60
In the framework of the dual parton model we calculate the spectra of secondary antibaryons in \(\bar p\) -nucleus non-annihilation inelastic interactions. We find that the number of antibaryons in the backward hemisphere in the \(\bar p\) -nucleon centre-of-mass frame can grow with the atomic number of the nucleus. 相似文献
9.
Lee JH Je J Schlautmana MA Carraway ER 《Chemical communications (Cambridge, England)》2003,(2):270-271
The maximum intensity, Imax, and time required to reach the maximum emission, taumax, for 1-aminopyrene monitored in 1,1'-oxalyldi-4-methylimidazole (OD4MI) chemiluminescence (CL) reactions are approximately 61 times higher and 16 times faster than their respective values for bis(2,4,6-trichlorophenyl)oxalate (TCPO) CL reactions in the presence of imidazole (ImH). 相似文献
10.
Exchange interactions in copper(II) complexes with tridentate Schiff bases: EPR and magnetic studies
Bogusława Jeżowska-Trzebiatowska Julia Jezierska Jerzy Baranowski 《Chemical physics letters》1977,52(3):590-594
The influence of the nature of ligands upon the magnetic and EPR properties was investigated for the series of polynuclear Cu(II) complexes with tridentate Schiff bases. A similar tendency of changes in the |J| and D parameters was found for binuclear Cu(II) complexes with ligands derived from condensation of 3-amino-1-propanol with 2-hydroxyaldehydes and acetylacetone as well as for Cu(II) complexes with condensation products of o-aminophenol and β-diketones. The Cu(II) complex with Schiff base of 1-amino-2-propanol and acetylacetone exhibits ferromagnetic behaviour suggesting tetrameric structure. 相似文献