Photochromism of diarylethene derivatives having an indene unit

Photochromic indene derivatives, 1-(2-methyl-1-inden-3-yl)-2-(2-methyl-1-benzothien-3-yl)perfluorocyclopentene and 1-(2-methyl-1-inden-3-yl)-2-(2-methyl-1-benzofuran-3-yl)perfluorocyclopentene, were synthesized and their photochromic performance was examined.     

Electrical properties and memory effect in the field effect transistor based on organic ferroelectric insulator and pentacene

We have fabricated a field effect transistor (FET) based on an organic ferroelectric insulator and molecular conductor, and investigated the electrical properties and memory effects on the PEN-FET. We have observed a drastic change in the drain current at around the coercive electric fieldE _c of the organic ferroelectric insulator in not only a FET (PEN-FET) based on a pentacene (PEN) film but also a FET (IPEN-FET) based on an iodine doped PEN film. The magnitude of the change of the drain current for the IPEN-FET is 200 times larger than that for the PEN-FET. It is expected from these results that the PEN-FET (especially the IPEN-FET) is an improvement in such devices, since it operates at a low gate electric field accompanied by the appearance of the spontaneous polarization in the organic ferroelectric insulator. In addition, we have found that the drain current for the PEN-FET does not return to the initial drain current ofE _G =0 V/cm for more than one week, even if the gate electric field is changed to 0 V/cm from 500 V/cm(>E _c ). From these results, it is suggested that the PEN-FET becomes a memory device.     

Impact of cell-voltage on energy and power performance of supercapacitors with single-walled carbon nanotube electrodes

We report the energy and power voltage-dependencies of supercapacitors using single-walled carbon nanotube electrodes. The energy density was dependent on the cell-voltage cubed (up to 4 V: E = 1.43 × V³). The cubic relationship was attributed to the linear increase of the capacitance as a function of voltage, enabled by electrochemical doping. Furthermore, while up to 3.5 V, the maximum power rating of the nanotube electrodes increased as a function of the cell-voltage squared, beyond 3.5 V, a decline in power was observed as a result of depletion of the electrolyte's ions.     

Turbulent diffusion for the radial twist map

An analytical tool is given to study the statistical properties of the radial twist map, X_n+1 = X_n + α(Y_n+1) and Y_n+1 = Y_n + Af (X_n), with arbitrary rotation number α(Y) and arbitrary periodic force f(X). The case for which f(X) = sin 2 πX and with arbitrary α is treated in the region of large A. The turbulent diffusion coefficient D for the chaotic orbit relaxes as $\text{t}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>2</mtext>}}$ to $\text{A}{}^2\text{4}$, except for the case of the standard map, where the eventual value of D is different from $\text{A}{}^2\text{4}$.     

Characterizations of isometric isomorphisms between uniform algebras via nonlinear range-preserving properties

Let be a surjective mapping from a uniform algebra on a compact Hausdorff space onto a uniform algebra on a compact Hausdorff space . Suppose that holds for every . Then we have that is an almost isometric isomorphism, which is a generalization of results of Molnár (2002) and Rao and Roy (2005).

     

Generalizations of spectrally multiplicative surjections between uniform algebras

Let $ A $ A and ℬ be unital semisimple commutative Banach algebras. It is shown that if surjections S,T: $ A $ A → ℬ with S(1)=T(1)= 1 and α ∈ ℂ \ {0} satisfy r(S(a)T(b) − α)= r(ab− α) for all a,b ∈ $ A $ A , then S=T and S is a real algebra isomorphism, where r(a) is the spectral radius of a. Let I be a nonempty set, A and B be uniform algebras. Let ρ, τ: I → A and S,T: I → B be maps satisfying σ _π (S(p)T(q)) ⊂ σ _π (ρ(p) τ(q)) for all p,q ∈ I, where σ _π (f) is the peripheral spectrum of f. Suppose that the ranges ρ(I), τ(I) ⊂ A and S(I),T(I) ⊂ B are closed under multiplication in a sense, and contain peaking functions “enough”. There exists a homeomorphism ϕ: Ch(B)→Ch(A) such that S(p)(y)= ρ(p)(ϕ(y)) and T(p)(y)= τ(p)(ϕ(y)) for every p ∈ I and y ∈ Ch(B), where Ch(A) is the Choquet boundary of A.     

New procedure to mask the 2,3-pi bond of the indole nucleus and its application to the preparation of potent opioid receptor agonists with a Corynanthe skeleton

Treatment of indole alkaloids with hypervalent iodine in the presence of ethylene glycol provides 2,3-ethylene glycol bridged adducts that could be converted into the original indoles under mild reductive conditions. This procedure, which involves masking of the reactivity of the indole nucleus at the beta-position, was utilized for the modification of the benzene ring of the indoline derivative and was applied to the preparation of potent opioid receptor agonists with the Corynanthe skeleton. [reaction: see text]     

Comparative examination of titania nanocrystals synthesized by peroxo titanic acid approach from different precursors

Titanium dioxide nanocrystalline particles were synthesized by peroxo titanium acid (PTA) approach from titanium alkoxide and inorganic salt precursors, and their structural and surface properties, porosities, and photocatalytic activities were comparatively examined by XRD, TG/DTA, DRIFT, UV-vis, low temperature N(2) adsorption, and methyl orange (MO) degradation. It was found that nanoparticles with single anatase phase can be obtained from alkoxide precursor even near room temperature if synthesis conditions are appropriately controlled. PTA-derived anatase nanoparticles from titanium alkoxide precursor have smaller crystalline sizes and better porosities, and contain less amount of peroxo group and no organic impurities as compared to those from TiCl(4) precursor. The advantages in structural property, porosity, and surface properties (few deficiencies) lead to a much better photocatalytic activity for TiO(2) nanoparticles from titanium alkoxide precursor in comparison with those from TiCl(4) precursor.     

Thallium selenate (Tl2SeO4) in a paraelastic phase by X‐ray powder diffraction

The structure of thallium selenate, Tl₂SeO₄, in a paraelastic phase (above 661 K) has been analysed by Rietveld analysis of the X‐ray powder diffraction pattern. Atomic parameters based on the isomorphic K₂SO₄ crystal in the paraelastic phase were used as the starting model. The structure was determined in the hexagonal space group P6₃/mmc, with a = 6.2916 (2) Å and c = 8.1964 (2) Å. From the Rietveld refinement it was found that two orientations are possible for the SeO₄ tetrahedra, in which one of their apices points randomly up and down with respect to [001]. One Tl atom lies at the origin with symmetry, the other Tl and one of the O atoms occupy sites with 3m symmetry, the Se atom is at a site with symmetry and the remaining O atom is at a site with m symmetry. Furthermore, it was also found that the Tl atoms display anomalously large positional disorder along [001] in the paraelastic phase.