Radio-frequency muon spin resonance studies of endohedral and exohedral muonium adducts of fullerenes

The radio-frequency muon spin resonance technique (RF-μSR) is described, with examples drawn from muon studies of fullerences. Two distinct species can be detected by RF-μSR when solid C₆₀ is irradiated with positive muons. Endohedral muonium (Mu@C₆₀) is characterized by a muon hyperfine constant (A _μ) close to the vacuum value. A remarkable feature of the RF-μSR spectrum is the double quantum transition, which appears when the allowed transitions are saturated. The exohedral muonium adduct (C₆₀Mu) is also detected, and has a much smaller value ofA _μ typical of a carbon-centred organic radical. It has been studied by RF-μSR in dilute solution, which is not possible for transverse field muon spin rotation (TF-μSR). There is a significant difference inA _μ of C₆₀Mu in the solid and in solution, a result of great import to the analysis of avoided-level crossing experiments on¹³C₆₀Mu.     

Final states in Si and GaAs via RF μSR spectroscopy

The ionization of muonium centers in Si and GaAs have been studied using radio frequency (RF) resonant techniques. In Si all three muonic centers are detectable by RF. No evidence was found for delayed Mu and Mu^* states at any temperature. However, our results on the diamagnetic final state (μ _f ⁺ ) show that it is composed of prompt fractions (as seen by conventional μSR) and delayed fractions arising from the ionization of Mu^* and Mu. We observe a full μ _f ⁺ fraction at 317 K when the Mu relaxation rate is above 10 μs⁻¹. GaAs differs from the situation in Si in that we observed only a partial conversion of Mu^* and Mu to a μ⁺ final state up to 310 K in spite of the fact that the transverse field relaxation rates become very high at 150 and 250 K respectively.