排序方式: 共有53条查询结果,搜索用时 15 毫秒
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MM. J. Duflos D. Letouz G. Queguiner P. Pastour 《Journal of heterocyclic chemistry》1973,10(6):1083-1084
This communication describes the synthesis of l-methyl-2,3-diformylpyrrole. This new compound is used to prepare a new heterocycle, l-methylcyclohepta[b]pyrrol-6-one and thus allows a new synthesis of l-methylpyrrolo[2,3-d]pyridazine. 相似文献
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Buchachenko AA Tscherbul TV Kłos J Szcześniak MM Chałasiński G Webb R Viehland LA 《The Journal of chemical physics》2005,122(19):194311
Interaction potentials of the iodine atom, atomic cation, and anion with light rare-gas atoms from He to Ar are calculated within the unified ab initio approach using the unrestricted coupled-cluster with singles and doubles and perturbative treatment of triples correlation treatment, relativistic small-core pseudopotential, and an extended basis set. Ab initio points are fit to a flexible analytical function. The calculated potentials are compared with available literature data, assessed in the I(-)-and I+-ion mobility calculations and the Ar-I(-)-anion zero electron kinetic-energy spectra simulations, and analyzed using the correlation rules. The results indicate a high precision of the reported potentials. 相似文献
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A simple method for the synthesis of sugar-derived imines by a Schwartz's reagent reduction of easily available sugar lactams has been described. A direct addition of nucleophiles to the generated in situ cyclic imines and subsequent deprotection of hydroxyl function allows to convert sugar lactams in polyhydroxylated pyrrolidines and piperidines. 相似文献
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E. R. Andrew S. G
owinkowski J. Radomski E. Szcze
niak 《Solid state nuclear magnetic resonance》2000,15(4):195-230
Spin–lattice relaxation times T1 in solid pregnenolone have been studied over a wide range of temperatures, from 77 up to 417 K. The dynamic processes arising from C3 motion of the three methyl substituents are separated, and their activation parameters are determined. 相似文献
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Phenol adsorption on closed carbon nanotubes 总被引:1,自引:0,他引:1
Pacholczyk A Terzyk AP Wiśniewski M Gauden PA Wesołowski RP Furmaniak S Szcześ A Chibowski E Kruszka B 《Journal of colloid and interface science》2011,361(1):288-292
We present the results of systematic studies of phenol adsorption on closed commercially available, unmodified carbon nanotubes. Phenol adsorption is determined by the value of tube-specific surface area, the presence of small amount of surface groups influence adsorption only in very small amount. Phenol can be applied as a probe molecule for comparative analysis of tube surface areas. Tube curvature influences adsorption from solution, i.e., we observe increasing adsorption energy (and slower desorption process) with the decrease in tube curvature. This is in full accordance with molecular simulation results. 相似文献
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Szcześ A Chibowski E Hołysz L Rafalski P 《The journal of physical chemistry. A》2011,115(21):5449-5452
Electrolyte solutions were exposed for different time to weak static magnetic field (MF) generated from a stack of magnets (B = 15 mT) at the flow rate of 1.4 mL/s. The conductivity was measured as a function of time following the application of MF. It was found that the changes in conductivity depend on the kind of electrolyte and the magnetic exposure time and are related to the thermodynamic function of hydration. 相似文献
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P. Kędzia T. Czechowski M. Baranowski J. Jurga E. Szcześniak 《Applied magnetic resonance》2013,44(5):605-618
In this paper we use a simple analysis based on properties of the axial field generated by symmetrical multipoles to reveal all possible distributions of two coaxial pairs of circular windings, which result in systems featuring zero octupole and 32 pole magnetic moments (six-order systems). Homogeneity of magnetic field of selected systems is analyzed. It has been found that one of the derived systems generates homogenous magnetic field whose volume is comparable to that yielded by the eight-order system. The influence of the current distribution and the windings placement on the field homogeneity is considered. The table, graphs and equations given in the paper facilitate the choice of the most appropriate design for a given problem. The systems presented may find applications in low field electron paramagnetic resonance imaging, some functional f-MRI (nuclear magnetic resonance imaging) and bioelectromagnetic experiments requiring the access to the working space from all directions. 相似文献