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1.
Sung Hwan Koo Dong Jun Li Taeyeong Yun Dong Sung Choi Kyung Eun Lee Gil Yong Lee Youngtak Oh Joonwon Lim Suchithra Padmajan Sasikala Ho Jin Lee In Ho Kim Hong Ju Jung Rishabh Jain Sang Ouk Kim 《Particle & Particle Systems Characterization》2019,36(7)
Efficient water electrolysis catalyst is highly demanded for the production of hydrogen as a sustainable energy fuel. It is reported that cobalt derived nanoparticle (CoS2, CoP, CoS|P) decorated reduced graphene oxide (rGO) composite aerogel catalysts for highly active and reliable hydrogen evolution reaction electrocatalysts. 7 nm level cobalt derived nanoparticles are synthesized over graphene aerogel surfaces with excellent surface coverage and maximal expose of active sites. CoS|P/rGO hybrid aerogel composites show an excellent catalytic activity with overpotential of ≈169 mV at a current density of ≈10 mA cm?2. Accordingly, efficient charge transfer is attained with Tafel slope of ≈52 mV dec?1 and a charge transfer resistance (Rct) of ≈12 Ω. This work suggests a viable route toward ultrasmall, uniform nanoparticles decorated graphene surfaces with well‐controlled chemical compositions, which can be generally useful for various applications commonly requiring large exposure of active surface area as well as robust interparticle charger transfer. 相似文献
2.
Lakshminarayana B. N. Sreenatha N. R. Jeevan Chakravarthy A. S. Suchithra B. Hariprasad S. 《Crystallography Reports》2022,67(2):201-208
Crystallography Reports - The molecular structure of 2-chloro-3-(1'-napthyl)-5,5-dimethyl-2- cyclohexenone was determined by single crystal X-ray diffraction. The compound crystallized in a... 相似文献
3.
Abstract
The surfactant complex ion cis-[Co(tmd)2(C12H25NH2)2]3+ (tmd = 1,3-propanediamine, C12H25NH2 = dodecylamine) has been synthesized and characterized by elemental analysis and spectral data. In addition we have determined the critical micelle concentration of the surfactant–cobalt(III) complex and studied the kinetics and mechanism of the complex with ferrocyanide anion. The reaction is found to be second order, and the second-order rate constant increases with increasing initial concentration of the surfactant–cobalt(III) complex due to the presence of self-micelles formed by the complex itself. The thermodynamic parameters were determined. The results have been analyzed. 相似文献4.
The kinetics and mechanism of reduction of the surfactant-cobalt(III) complex ions, cis-[Co(bpy)2(C12H25NH2)2]3+ and cis-[Co(phen)2(C12H25NH2)2]3+ (bpy = bipyridyl, phen = 1,10-phenan-throline, C12H25NH2 = dodecylamine) by Fe(CN6)4− in self-micelles were studied at different temperatures. Experimentally the reaction was found to be second order and the
electron transfer postulated as outersphere. The rate constant for the electron transfer reaction for both the complexes was
found to increase with increase in the initial concentration of the surfactant-cobalt(III) complex. This peculiar behaviour
of dependence of second-order rate constant on the initial concentration of one of the reactants has been attributed to the
presence of various concentration of micelles under different initial concentration of the surfactantcobalt(III) complexes
in the reaction medium. The effect of inclusion of the long aliphatic chain of the surfactant complex ions into β-cyclodextrin
on these reactions has also been studied. 相似文献
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6.
P.P. Hankare R.P. Patil U.B. Sankpal R. Sasikala I.S. Mulla 《Journal of magnetism and magnetic materials》2010,322(18):2629-9662
Nanocrystalline Li0.5Fe2.5−xCrxO4 (2.5≤x≥0) ferrites were prepared by a sol-gel autocombustion route. X-ray diffraction was employed to confirm the cubic spinel phase formation of the ferrites. The lattice parameter decreases with increase in Cr content. The saturation magnetization, coercivity and remanance were studied as a function of Cr content. The dielectric constant and dielectric loss were measured as a function of frequency in the frequency range 20 Hz-1 MHz. Frequency dependence of dielectric constant shows dielectric dispersion due to the Maxwell-Wagner type of interfacial polarization. In order to understand the conduction mechanism, complex impedance measurements were carried out. The substitution of chromium plays an important role in changing the dielectric and magnetic properties of lithium ferrites. 相似文献
7.
Annie Mathews Karunalayam A. Sasikala Sholly C. George Kooramattom U. Krishnaraj Naduthottiyil K. Sreedevi Marathu Prasanth Engoor R. Anabha Karakkattu S. Devaky Chittoorthekkathil V. Asokan 《Journal of heterocyclic chemistry》2008,45(6):1583-1587
2‐Aroyl‐3,3‐bis(alkylsulfanyl)acrylaldehyde was utilized for the synthesis of three different isoxazoles by reacting with hydroxylaminehydrochloride. We synthesized differently substituted isoxazoles like (aryl)[5‐(methylsulfanyl)‐4‐isoxazolyl]methanones, 3‐(methylsulfanyl)‐5‐phenyl‐4‐isoxazolecarbonitriles and 5‐aryl‐3‐(methylsulfanyl)‐4‐isoxazolecarbaldehyde oximes in good yields by varying the substratereagent stoichiometry and temperature of the reaction medium. 相似文献
8.
Ponnusamy Shanmugam Baby Viswambharan Kodirajan Selvakumar Suchithra Madhavan 《Tetrahedron letters》2008,49(16):2611-2615
The [3+2] cycloaddition reaction of azomethine ylides with isomerised Morita-Baylis-Hillman adducts, both dipoles and dipolarophiles are derived from isatin, afforded highly functionalised 3,3′-dispiro pyrrolidine- and 3,3′-dispiropyrrolizidine bisoxindoles in high yields. 相似文献
9.
D. Umamaheswari B.C. Jamalaiah T. Sasikala Il-Gon Kim L. Rama Moorthy 《Journal of Non》2012,358(4):782-787
The photoluminescence properties of different concentrations of Sm3+ ions doped sodium fluoroborate (SFB) glasses of composition Na2O–LaF3–CaF2–AlF3–B2O3–SmF3 have been investigated. The energy level analysis is carried out using free-ion Hamiltonian model. The Judd–Ofelt intensity parameters are used to evaluate the laser characteristic parameters such as spontaneous transition probability, radiative lifetime and fluorescence branching ratio for 4G5/2 → 6HJ (J = 5/2, 7/2, 9/2 and 11/2) emission transitions of Sm3+ ion. The principal photoluminescence transitions of interest are identified by recording the emission spectra for different Sm3+ ion concentrations and measuring their emission cross-sections, integrated absorption cross-sections and optical gain parameters. The decay profiles from the 4G7/2 excited manifold state to its lower lying energy levels have been recorded by monitoring the excitation and emission wavelengths at 402 and 600 nm, respectively. The dependence of effective fluorescence lifetime on the Sm3+ concentration is also discussed. 相似文献