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排序方式: 共有1425条查询结果,搜索用时 31 毫秒
1.
Anna Arkhireeva John N. Hay Jackie M. Lane Miguel Manzano Helen Masters Wilberforce Oware Steve J. Shaw 《Journal of Sol-Gel Science and Technology》2004,31(1-3):31-36
The synthesis of ORganically MOdified SILica (ORMOSIL) particles has been carried out using both the hydrolytic and non-hydrolytic sol-gel routes. The hybrid (nano)composites are organically modified with an alkyl or aryl group covalently bonded to silicon. Hybrids have been synthesised in an aqueous sol-gel process by a modified Stöber route, producing spherical nanoparticles with diameters in the range 50–300 nm. The size of the particles can be controlled by control of certain reaction parameters. Smaller ormosil nanoparticles can be synthesised by a base-catalysed emulsion polymerisation route, by varying the type and concentration of surfactant and precursor feed rate. In this case, particles in the size range 3.5–10 nm can be obtained. Hybrids have been synthesised from hyperbranched polyesters by encapsulation in a silica matrix using the hydrolytic sol-gel route. Optimisation of the reaction conditions allows the hybrids to be produced as isolated sub-micron spherical particles. Ormosil particles have also been synthesised using the non-hydrolytic sol-gel route, which may lead to products of different morphologies because of the different polarity of the reaction medium. Different reaction conditions were studied in order to optimise the size and shape of the particles, including choice of solvent, use of surfactants and addition of polystyrene. Dimethylsulfoxide acts as a novel oxygen donor for the catalyst-free formation of colourless silsesquioxanes. 相似文献
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This report focuses on a theoretical study of the cobalt-cabon bond activation mechanism in Vitamin B12, its co enzyme complexes, and model compounds such as cobalamins (Cbl), cobaloximes and cobalt porphyrins. In particular, emphasis is placed on the nucleotide loop and its role in the base on and base off mechanism. 相似文献
4.
The regression problem in learning theory is investigated with least square Tikhonov regularization schemes in reproducing
kernel Hilbert spaces (RKHS). We follow our previous work and apply the sampling operator to the error analysis in both the
RKHS norm and the L2 norm. The tool for estimating the sample error is a Bennet inequality for random variables with values in Hilbert spaces.
By taking the Hilbert space to be the one consisting of Hilbert-Schmidt operators in the RKHS, we improve the error bounds
in the L2 metric, motivated by an idea of Caponnetto and de Vito. The error bounds we derive in the RKHS norm, together with a Tsybakov
function we discuss here, yield interesting applications to the error analysis of the (binary) classification problem, since
the RKHS metric controls the one for the uniform convergence. 相似文献
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Steve Tisserand Célia Billaud J.R. Falck Charles Mioskowski 《Tetrahedron letters》2006,47(29):5177-5180
CrCl2-mediated condensation of γ-chloro-gem-trichloroalkanes with aldehyde generates homoallylic alcohols through a hydride rearrangement followed by a Nozaki-Hiyama allylation. 相似文献
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Felipe Cucker Steve Smale Ding-Xuan Zhou 《Foundations of Computational Mathematics》2004,4(3):315-343
We describe a model for the evolution of the languages used by the agents of a
society. Our main result proves convergence of these languages to a common
one under certain conditions. A few special cases are elaborated in more
depth. 相似文献