排序方式: 共有156条查询结果,搜索用时 78 毫秒
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A. Nozad Golikand S. M. Golabi M. Ghannadi Maragheh L. Irannejad M. Asgari 《Journal of the Iranian Chemical Society》2007,4(3):304-309
Electrocatalytic oxidation of methanol on a glassy carbon electrode coated with Ni(II)-(1,2-phenylendiamine)2 (GC/NiOPD), conditioned by the potential recycling in a potential range of 100–650 mV (vs. SCE) is studied by cyclic voltammetry in an alkaline medium (0.10 M NaOH). The results show that the NiOPD layer formed at the surface of the electrode behaves as an efficient electrocatalyst for the oxidation of methanol in the alkaline medium via the Ni(III) species with a cross exchange reaction occurring throughout the layer at a low concentration of methanol. The effects of various parameters such as potential scan rates, methanol concentration and NiOPD surface concentration on the electro-oxidation of methanol are also investigated. 相似文献
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We have designed and proposed the edge modes supported by graphene ribbons and the planar band-pass filter consisting of graphene ribbons coupled to a graphene ring resonator by using the finite-difference time-domain numerical method.Simulation results show that the edge modes improve the electromagnetic coupling between devices. This structure works as a novel, tunable mid-infrared band-pass filter. Our studies will benefit the fabrication of planar, ultra-compact nano-scale devices in the mid-infrared region. A power splitter consisting of two output ribbons that is useful in photonic integrated devices and circuits is also designed and simulated. These devices are useful for designing ultra-compact planar devices in photonic integrated circuits. 相似文献
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Optimization of synthesis procedure and structure characterization of manganese tungstate nanoplates
Mehdi Rahimi-Nasrabadi S. Mahdi Pourmortazavi Morteza Khalilian-Shalamzari S. Somayyeh Hajimirsadeghi M. Mahdi Zahedi 《Central European Journal of Chemistry》2013,11(8):1393-1401
A simple and fast chemical method was used for synthesis of manganese tungstate nanoplates in flower-like clusters; while Taguchi robust design was employed as statistical method for optimization of the experimental parameters for the procedure. Ultrafine manganese tungstate plates in flower-like clusters were synthesized via a direct precipitation method involving addition of manganese ion solution to the aqueous tungstate reagent. Effects of various reaction conditions such as manganese and tungstate concentrations, flow rate of reagent addition and reactor temperature on the thickness of the synthesized manganese tungstate plates were investigated experimentally. Analysis of variance (ANOVA) showed that manganese tungstate nanoplates could be effectively synthesized by tuning significant parameters of precipitation procedure. Meanwhile, optimum conditions for synthesis of MnWO4 nanoplates via this simple, fast, and cost effective method were proposed. The structure and composition of the prepared nanoplates under optimum conditions were characterized by EDX, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), FT-IR spectroscopy, and photoluminescence techniques. 相似文献
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A. Qaiumzadeh F. K. Joibari R. Asgari 《The European Physical Journal B - Condensed Matter and Complex Systems》2010,74(4):479-485
We present numerical calculations of the effect of gap opening on the quasiparticle properties of a doped graphene sheet within
G0W-RPA approximation. We present results of the renormalized Fermi velocity suppression and the renormalization constant over
a broad range of the energy gap values. We find that the renormalized velocity is density independent at large density values
which is in agreement with recent experimental observations. We also show that the inelastic
quasiparticle lifetime decreases by increasing the gap value. Finally, we show that the inelastic mean free path reduces by
increasing the gap values but in the range of the typical gap values it is large enough and transport remains in the semi-ballistic
regime. 相似文献
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Mohammad Ali Kamyabi Z. Asgari H. Hosseini Monfared 《Journal of Solid State Electrochemistry》2010,14(9):1547-1553
A carbon past electrode modified with [Mn(H2O)(N3)(NO3)(pyterpy)],
( \textpyterpy = 4¢- ( 4 - \textpyridyl ) - 2,2¢:\text6¢,\text2¢¢- \textterpyridine ) \left( {{\text{pyterpy}} = 4\prime - \left( {4 - {\text{pyridyl}}} \right) - 2,2\prime:{\text{6}}\prime,{\text{2}}\prime\prime - {\text{terpyridine}}} \right) complex have been applied to the electrocatalytic oxidation of nitrite which reduced the overpotential by about 120 mV with
obviously increasing the current response. Relative standard deviations for nitrite determination was less than 2.0%, and
nitrite can be determined in the ranges of 5.00 × 10−6 to 1.55 × 10−2 mol L−1, with a detection limit of 8 × 10−7 mol L−1. The treatment of the voltammetric data showed that it is a pure diffusion-controlled reaction, which involves one electron
in the rate-determining step. The rate constant k′, transfer coefficient α for the catalytic reaction, and diffusion coefficient of nitrite in the solution, D, were found to be 1.4 × 10−2, 0.56× 10−6, and 7.99 × 10−6 cm2 s−1, respectively. The mechanism for the interaction of nitrite with the Mn(II) complex modified carbon past electrode is proposed.
This work provides a simple and easy approach to detection of nitrite ion. The modified electrode indicated reproducible behavior,
anti-fouling properties, and stability during electrochemical experiments, making it particularly suitable for the analytical
purposes. 相似文献
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L. Mohammadzadeh A. Asgari S. Shojaei E. Ahmadi 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,84(2):249-253
In this paper the excitons of armchair graphene nanoribbons with layers of different width and thickness have been investigated.
In this investigation, the band structure and energy gap of armchair graphene nanoribbons have been calculated using a tight-binding
model including edge deformation effects (all edge atoms have been passivated with hydrogen atoms). Also, by calculating the
conductance in armchair graphene nanoribbons (A-GNRs) optical absorption of armchair graphene nanoribbon in the single-electron
approximation has been obtained. Finally, the binding energy of excitons in armchair graphene nanoribbons has been calculated
using the Wannier model, Hartree-Fock approximation and the Bethe-Salpeter equation. 相似文献
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The lifetime of electrostatically trapped indirect excitons in a field-effect structure based on coupled AlGaN/GaN quantum wells has been theoretically studied. Within the plane of a double quantum well, indirect excitons are trapped between the surfaces of the AlGaN/GaN heterostructures and a semitransparent metallic top gate. The trapping mechanism has been assumed to be a combination of the quantum confined Stark effect and local field enhancement. In order to study the trapped exciton lifetime, the binding energy of indirect excitons in coupled quantum wells is calculated by finite difference method in the presence of an electric field. Thus, the lifetime of trapped excitons is computed as a function of well width, AlGaN barrier width, the position of double quantum well in the device and applied voltage. 相似文献