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排序方式: 共有217条查询结果,搜索用时 15 毫秒
1.
Unexpected benzimidazole ring formation from a quinoneimide species in the presence of ammonium acetate as supporting electrolyte used in the coupling of electrochemistry with mass spectrometry
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2.
The structure, morphology, and isothermal and nonisothermal crystallization of isotactic polypropylene/low‐molecular‐mass hydrocarbon resin blends (iPP/HR) (up to 20% in weight of HR) have been studied, using optical and electron microscopy, wide‐ and small‐angle X‐ray and differential scanning calorimetry. New structures and morphologies can be activated, using appropriate preparation and crystallization conditions and blend composition. For every composition and crystallization condition, iPP crystallizes in α‐form, with a spherulitic morphology. The size of iPP spherulites increases with resin content, whereas the long period decreases. In the range of crystallization temperatures investigated, HR modifies the birefringence of iPP spherulites, favoring the formation of radial lamellae and changing the ratio between tangential and radial lamellae. Spherulitic radial growth rates, overall crystallization rates, and melting temperatures are strongly affected by resin, monotonically decreasing with resin content. This confirms miscibility in the melt between the two components of the blends. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3368–3379, 2004 相似文献
3.
Ge segregation during the growth of Si1 − xGex alloys (x = 5, 10, 20, and 40%) was studied using X-ray photoelectron spectroscopy. The alloys were grown in thicknesses up to 20.0 nm at 500°C to measure quantitatively the amount of segregated surface Ge. The length of alloy needed to reach steady-state growth edge was found to decrease with increasing alloy concentration (4.8, 2.8, 2.4, and 2.0 nm, respectively). It was found that each alloy had a complete monolayer of Ge on the surface and an increasing amount of segregated Ge in the second layer (20, 55, 80, and 95%, respectively) during steady-state growth. An increase in the temperature of alloy growth (400–750°C) resulted in an increase in the leading edge of alloy growth but did not change the amount of segregated Ge during steady-state growth. We propose that film stress is responsible for the amount of Ge segregation. 相似文献
4.
KL Britton HF Rogers Y Asano T Dairi Y Kato TJ Stillman DW Rice 《Acta crystallographica. Section D, Biological crystallography》1998,53(4):124-126
The novel NAD+-linked opine dehydrogenase from a soil isolate Arthrobacter sp. strain 1C belongs to an enzyme superfamily whose members exhibit quite diverse substrate specificites. Crystals of this opine dehydrogenase, obtained in the presence or absence of co-factor and substrates, have been shown to diffract to beyond 1.8 ? resolution. X-ray precession photographs have established that the crystals belong to space group P21212, with cell parameters a = 104.9, b = 80.0, c = 45.5 ? and a single subunit in the asymmetric unit. The elucidation of the three-dimensional structure of this enzyme will provide a structural framework for this novel class of dehydrogenases to enable a comparison to be made with other enzyme families and also as the basis for mutagenesis experiments directed towards the production of natural and synthetic opine-type compounds containing two chiral centres. 相似文献
5.
Nicol Vivona Vincenzo Frenna Silvestre Buscemi Michele Ruccia 《Journal of heterocyclic chemistry》1985,22(1):97-99
The behaviour of (E)- and (Z)-N,N-diphenylhydrazones and O-Methyloximes of 3-benzoyl-5-phenyl-1,2,4-oxadiazole has been studied. When refluxed in benzene, or in dioxane-water (1:1), the (Z)-N,N-diphenylhydrazone 8Z gave the indazole 11 or the substituted semicarbazide 12 , respectively. The O-methyloxime 14Z did not give any rearrangement. A criticism of the oximation reaction of 3-benzoyl-5-phenyl-1,2,4-oxadiazole is also reported. 相似文献
6.
Bismuth(III) salts are efficient catalysts for the selective allylic oxidation using tert-butyl hydroperoxide. BiCl3 is especially effective and can be easily recovered and reused as BiOCl. Using BiCl3/K-10 as catalyst, an increase in the reaction rate was observed. 相似文献
7.
Gérald S. Remaud Virginie Silvestre Serge Akoka 《Accreditation and quality assurance》2005,10(8):415-420
The choice of the reference, either as internal or external is not straightforward in quantitative NMR. In this context ERETIC™
methodology appears as an universal referencing technique. An electronic signal, generated by the NMR spectrometer during
the acquisition time, operates as a virtual working standard. The processes for ensuring a traceability to primary standards
is illustrated on the official method devoted to (D/H)i ratios measurement on ethanol, using quantitative 2H-NMR. The ERETIC approach is shown to be equivalent to its official homologue, in terms of accuracy and precision. Finally,
its performance could be beneficial to other analytes, matrices and nuclei. 相似文献
8.
Buscemi S Pace A Palumbo Piccionello A Macaluso G Vivona N Spinelli D Giorgi G 《The Journal of organic chemistry》2005,70(8):3288-3291
The reaction of 3-benzoyl-5-perfluoroalkyl-1,2,4-oxadiazoles with hydrazine has been investigated, evidencing the possibility of competitive reaction paths. Nucleophilic addition of the hydrazine to the electrophilic C(5) of the 1,2,4-oxadiazole ring, followed by ring opening and ring closure with enlargement, leads with high yield and in very mild experimental conditions to the formation of Z-oximes of 3-perfluoroalkyl-6-phenyl-2H-1,2,4-triazin-5-ones (11a-c) as major products of the reaction. In turn, the hydrazine can attack the electrophilic carbonyl carbon giving 4-perfluoroacylamino-5-phenyl-2H-1,2,3-triazoles (13a-c) through the well-known Boulton-Katritzky rearrangement of the intermediate hydrazones. 相似文献
9.
10.
In this paper we prove a quantitative form of Landis’ conjecture in the plane. Precisely, let W(z) be a measurable real vector-valued function and V(z) ≥0 be a real measurable scalar function, satisfying ‖W‖ L ∞(R 2) ≤ 1 and ‖V‖ L ∞(R 2) ≤ 1. Let u be a real solution of Δu ? ?(Wu) ? Vu = 0 in R 2. Assume that u(0) = 1 and |u(z)| ≤exp (C 0|z|). Then u satisfies inf |z 0| =R sup |z?z 0| <1|u(z)| ≥exp (?CRlog R), where C depends on C 0. In addition to the case of the whole plane, we also establish a quantitative form of Landis’ conjecture defined in an exterior domain. 相似文献