全文获取类型
收费全文 | 177篇 |
免费 | 0篇 |
专业分类
化学 | 89篇 |
晶体学 | 7篇 |
力学 | 10篇 |
数学 | 20篇 |
物理学 | 51篇 |
出版年
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 2篇 |
2015年 | 2篇 |
2014年 | 3篇 |
2013年 | 3篇 |
2012年 | 4篇 |
2011年 | 7篇 |
2010年 | 8篇 |
2009年 | 5篇 |
2008年 | 6篇 |
2007年 | 4篇 |
2006年 | 6篇 |
2005年 | 2篇 |
2004年 | 8篇 |
2003年 | 8篇 |
2002年 | 5篇 |
2001年 | 8篇 |
1999年 | 10篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 7篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 4篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 3篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1966年 | 3篇 |
1965年 | 2篇 |
1964年 | 1篇 |
排序方式: 共有177条查询结果,搜索用时 0 毫秒
1.
D. K. Kuznetsov I. S. Baturin V. Ya. Shur N. Menou C. Muller T. Schneller A. Sternberg 《Physics of the Solid State》2006,48(6):1174-1176
The effect of irradiation with electrons and neutrons and of exposure to synchrotron radiation on cyclic switching of polarization in thin films of lead zirconate titanate Pb(Zr,Ti)O3 (PZT) was studied. It is shown that variations in the shape of switching currents are due to the generation of a spatially nonuniform bound internal field with account for an increase in the rate of bulk screening caused by irradiation. A correlation between structural variations and the evolution of the switching current measured during and after irradiation is established. 相似文献
2.
3.
V. S. Lenenko P. Kränke M. Wahren V. B. Shur M. E. Vol'pin 《Russian Chemical Bulletin》1995,44(7):1293-1299
The interaction of labeled dinitrogen complexescis-(Me2PhP)4Mo(15N2)2 andtrans-(dppe)2W(15N2)2 with non-labeled nitronium and nitrosonium fluoroborates,14NO2BF4 and14NOBF4, in sulfolane at room temperature in the presence of H2SO4 results in rapid formation of labeled nitrous and nitric oxides (15N14NO,15NO), as well as15N14N. The yield of the products depends on the reagent ratio and reaches 10–20 mol. % per mole of a complex under optimum conditions. The mechanism of the reactions found is proposed. It involves the step of protonation of the dinitrogen ligand to form the corresponding hydrazido(2–) derivatives, which are then attacked by nitronium or nitrosonium cations. In accordance with the mechanism proposed, it was established that the hydrazido(2–) complexes, (Me2PhP)3Mo(15N2H2)Cl2 and (dppe)2W(15N2H2)Cl2, are capable of forming15N14NO,15NO, and15N14N under the action of14NO2BF4 and14NOBF4 in the absence of an acid.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 13–13, July, 1995. 相似文献
4.
THz spectroscopic investigation of 2,4-dinitrotoluene 总被引:5,自引:0,他引:5
Yunqing Chen Haibo Liu Yanqing Deng Dunja Schauki Michael J. Fitch Robert Osiander Caroline Dodson James B. Spicer Michael Shur X.-C. Zhang 《Chemical physics letters》2004,400(4-6):357-361
We have investigated the terahertz (THz) spectrum of 2,4-DNT by using Fourier transform infrared spectroscopy in the 0.2–19.5 THz region. We also examined low-frequency intermolecular or phonon modes between 0.2 and 1.8 THz via THz time-domain spectroscopy. The extracted absorption coefficient and refractive index of an intermolecular band at 1.08 THz are 110 cm−1 and 1.67, respectively. Density functional theory (DFT) was applied to obtain structure and vibrational frequencies of 2,4-DNT. The calculated results are in agreement with the experimental data. Observed vibrational frequencies have been interpreted using DFT. Two intermolecular or phonon modes were identified at 1.08 and 2.52 THz. 相似文献
5.
Tikhonova I. A. Shubina E. S. Dolgushin F. M. Tugashov K. I. Teplitskaya L. N. Filin A. M. Sivaev I. B. Petrovskii P. V. Furin G. G. Bregadze V. I. Epstein L. M. Shur V. B. 《Russian Chemical Bulletin》2003,52(3):594-600
The reaction of cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3 (1) with the polyhedral [B12H11SCN]2– anion in THF at 20 °C affords the {[(o-C6F4Hg)3](B12H11SCN)}2– (4) and {[(o-C6F4Hg)3]2(B12H11SCN)}2– (5) complexes. Complex 5 was isolated as the tetrabutylammonium salt. X-ray diffraction analysis showed that this complex has a bent-sandwich structure in which the [B12H11SCN]2– anion is located between the planes of two molecules 1 and is coordinated to both these molecules through B—H—Hg bridges and S—Hg bonds. The stability constants of complexes 4 and 5 in THF (20 °C), which were determined from the IR spectroscopic data, are 16 L mol–1 and 992 L2 mol–2, respectively. 相似文献
6.
Demin A. M. Kandarakov O. F. Minin A. S. Kuznetsov D. K. Uimin M. A. Shur V. Ya. Belyavsky A. V. Krasnov V. P. 《Russian Chemical Bulletin》2021,70(6):1199-1208
Russian Chemical Bulletin - Peculiar features of the modification of Fe3O4 magnetic nanoparticles (MNPs) obtained by co-precipitation from solutions of FeII and FeIII salts (10-nm MNPs) and by the... 相似文献
7.
M. G. Berdichevskii V. V. Marusun S. M. Kazakov A. I. Korotkov N. A. Prilezhaeva A. M. Noskov V. L. Glagolev Yu. V. Pomazan V. N. Shamshev S. F. Manole N. A. Barba I. D. Korzha Ya. E. Guiu R. K. Shukla A. M. Shur M. I. Shenbor A. S. Azarov A. L. Furer V. L. Furer L. N. Maklakova G. V. Sheban B. E. Zaitsev O. A. Tambieva E. S. Lisitsyna K. M. Dyumaev 《Journal of Applied Spectroscopy》1978,29(1):882-885
8.
I. A. Tikhonova F. M. Dolgushin K. I. Tugashov P. V. Petrovskii M. Yu. Antipin V. B. Shur 《Russian Chemical Bulletin》2004,53(12):2871-2873
The first double-decker sandwich complex of a sandwich was synthesized and fully characterized. The complex was prepared by the reaction of cyclic trimeric perfluoro-o-phenylene-mercury (o-C6F4Hg)3 (1) with ferrocene in an ethereal solution at 20 °C and has the composition {[(o-C6F4Hg)3]2(Cp2Fe)} (2). The ferrocene sandwich in 2 is located between the planes of two mercury-containing macrocycles and is coordinated to each of them through donation of the -electrons of the 5-Cp ligands to vacant orbitals of the mercury atoms of the adjacent molecule 1. It was concluded that all carbon atoms of the 5-Cp rings in complex 2 are involved in the bonding to the macrocycles. Complexation with 1 leads to considerable shifts of the (C-H) and (C-H) bands of ferrocene in the IR spectrum to high frequencies. The structure of complex 2 was determined by X-ray diffraction.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2754–2756, December, 2004. 相似文献
9.
A. L. Chistyakov I. V. Stankevich N. P. Gambaryan I. A. Tikhonova V. B. Shur 《Russian Chemical Bulletin》1995,44(6):997-1004
Geometries and electronic structures of the complexes of halide anions with cyclic trimerico-phenylenemercury, (o-C6H4Hg)3, perfluoro-o-phenylenemercury, (o-C6F4Hg)3, vinylenemercury, (C2H2Hg)3, and perfluorovinylenemercury, (C2F2Hg)3, were modelled by the MNDO method. Calculations were performed for [L-X]– semisandwich complexes, [X-L-X]2– bipyramidal complexes, and [L-X-L]– sandwich complexes (where X=Hal,L is a mercury-containing macrocycle). Based on the results of calculations, we concluded that it was advantageous to describe the chemical bonding between halide anions and mercury-containing macrocycles in terms of generalized chemical bonds, which were successfully used for -complexes of transition metals. In the [L-X]– semisandwich complexes, the halide anion and the metallacycle are involved in the formation of three generalized chemical bonds: one headlight-shaped -bond and two two-lobe -bonds. In the [X-L-X]2– bipyramidal complexes, each halide anion forms three generalized chemical bonds with the macrocycle. It is possible because the macrocycleL has unoccupied molecular orbitals suitable for the formation of such bonds; these MOs consist mainly of the orbitals of mercury atoms directed toward both the upper and lower halogen atoms. In the [L-X-L]– sandwich complexes, the halide anion cannot be bonded to each ringvia three bonds, and, hence, an unsymmetrical structure is formed, in which the rings are located at different distances from the central atom: the [L-X]– semisandwich complex solvated by macrocycleL.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1035–1042, June, 1995.The authors are grateful to V. I. Faustov for valuable remarks.This work was supported by the Russian Foundation for Basic Research (Project No. 93-03-18342). 相似文献
10.
Arndt P Baumann W Spannenberg A Rosenthal U Burlakov VV Shur VB 《Angewandte Chemie (International ed. in English)》2003,42(12):1414-1418