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1.
I. M. Batyaev S. M. Begel'dieva E. B. Kleshchinov S. M. Shilov 《Russian Journal of Applied Chemistry》2003,76(10):1694-1695
Synthesis and some chemical properties of the Al2O-SiO2-P2O5 system activated with MnO were studied. 相似文献
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V. P. Shilov 《Journal of Experimental and Theoretical Physics》2003,96(4):719-729
The supercritical Marangoni convection has been studied in a plane-parallel liquid layer, bounded by a free deformable gas-liquid interface from above and by a low-heat-conductivity wall from below, occurring under conditions of inhomogeneous heating in the horizontal plane. In a longwave approximation with a small inhomogeneity of heat flux, the process is described by a system of two-dimensional nonlinear equations for the temperature perturbations, vorticity, and free surface deformation. The concept of quasiequilibrium, implying stability of long-range flows, is introduced, which allows the inhomogeneous heat flux to be modeled by a step function. The linear stability is analyzed in the cases of planar and axisymmetric heat fluxes. The boundaries of stability of the convection regimes are determined on the plane of parameters characterizing the degree of supercriticity inside a heated spot and the depth of damping outside the spot. For an axisymmetric spot, the domains of stability with respect to perturbations for various azimuthal numbers are established. 相似文献
4.
S. G. Barsov A. L. Getalov S. L. Ginsburg V. P. Koptev S. P. Kruglov L. A. Kuzmin S. V. Maleyev E. I. Maltsev S. M. Mikirtychyants N. A. Tarasov G. V. Shcherbakov V. G. Grebinnik V. N. Duginov A. B. Lazarev V. G. Olshevski S. N. Shilov V. A. Zhukov I. I. Gurevich B. F. Kirillov A. I. Klimov B. A. Nikolski A. V. Pirogov A. N. Ponomarev V. A. Suetin 《Hyperfine Interactions》1991,64(1-4):415-419
The zero field μSR-method has been used to study the magnetism in the disordered magnetic alloy Fe82−xNixCr18 near the three-critical, pointx=25. The dynamic and static local field distributions are analyzed. The difference between spin-glass states obtained either
from the paramagnetic or after the double transition is discussed. 相似文献
5.
A new theoretical model describing the emission and absorption dynamics in an ensemble of molecules under intense coherent pulsed pumping is developed on the basis of the concepts of cooperative light-induced luminescence (CLIL). The CLIL development is described within the framework of formalism of the system density matrix in the space of photon wave functions. It is shown that the fast growth of CLIL relates to the development of coherent states of the quantum field in the area of efficient cooperative interactions of molecules (coherence volume). A system of equations for the calculation of CLIL energy, population of excited states, and optical absorption of the system in dependence on the laser pump energy density is solved. The theoretical results obtained are in good agreement with the experimental data. 相似文献
6.
B. S. Fedorov M. A. Fadeev V. V. Arakcheeva G. V. Strukov N. I. Golovina R. F. Trofimova G. V. Shilov L. O. Atovmyan 《Russian Chemical Bulletin》1994,43(12):2087-2090
A novel heterocyclic compound, 4-acetoxy-5,6-dihydro-5,5-dinitro-2H-1,3-oxazineN-oxide, has been synthesized by the reaction of the dipotassium salt of 1,1,5,5-tetranitro-3-oxapentane with aqueous acetic acid. The synthesized compound has been studied by X-ray diffraction analysis.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2207–2210, December, 1994.We would like to thank G. V. Lagodzinskaya (Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences) for recording and interpreting1H NMR spectra, A. M. Korolev (Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences) for helpful discussion, and V. I. Fetisov (Institute of Physiologically Active Compounds, Russian Academy of Sciences) for performing quantum-chemical calculations by the AM1 SCF MO LCAO method. 相似文献
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O. S. Filipenko S. M. Aldoshin G. V. Shilov N. I. Makarova V. A. Kharlanov M. I. Knyazhanskii 《Russian Chemical Bulletin》1995,44(2):287-292
The molecular structures of the initial compounds and the products of photocyclization involving amino and azomethine groups in perchlorates ofN-amino (1) andN-azomethine (2) derivatives of 2,4,6-triphenylpyridinium cations were studied. Cations1 and2 have an essentially non-coplanar arrangement of the -Ph rings, and the product of photocyclization of2, cation3, is characterized by a flattened structure. It was found that the orientation of the lone electron pair of the N atom with respect to one of the planes of the -Ph rings in molecule1 is more favorable for monocyclization involving the amino group. The structure of molecule2 allows two routes of the photoreaction,viz., O N proton transfer and monocyclization with an -Ph ring. However, the structural features of molecule2 are more favorable for photocyclization.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 296–301, February, 1995. 相似文献
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Karasevich E. I. Karasevich Yu. K. Shestakov A. F. Shilov A. E. 《Kinetics and Catalysis》2003,44(1):112-120
Published data on the kinetic isotope effects of the hydroxylation of deuterium-substituted methane molecules (CHD3, CH2D2, and CH3D) by methane monooxygenase are examined in the framework of the two-step nonradical mechanism through the intermediate formation of a complex containing pentacoordinate carbon. The kinetic schemes with the first step involving one, two, and three hydrogen atoms of the oxidized substrate are considered. Contrary to the widely accepted oxygen rebound mechanism, the experimental results obtained for the oxidation of various substrates by methane monooxygenase and cytochrome P450 can be explained from the viewpoint of the dynamics of a general nonradical mechanism. 相似文献