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A series of metal-organic frameworks, namely [Ni(PDB)(H2O)]n (1), [Pb(PDB)(H2O)] · (H2O) (2), [Co2(PDB)2(bpy)2(H2O)4] · 4H2O (3) and [Co2(PDB)2(phen)2]n (4) (H2PDB = pyridine-3,5-dicarboxylic acid, bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline), have been synthesized based on pyridine-3,5-dicarboxylate acid and two neutral chelate ligands, with different metal ions such as NiII, CoII and PbII, under hydrothermal conditions. The framework structures of these polymeric complexes have been determined by the X-ray single crystal diffraction technique. In the four complexes, the pyridine-3,5-dicarboxylate acid ligand exhibits diverse coordination modes, which play an important role in the construction of metal-organic frameworks. The thermal analyses of these four complexes have been measured and discussed. In addition, complex 2 shows strong phosphorescent emission at room temperature and the magnetic measurement of the polymer of 4 reveals a typical antiferromagnetic exchange.  相似文献   
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Gao  Jie  Zhai  JiYuan  Pan  WeiMin  Li  ShaoPeng  Sun  Yi  Dai  JianPing  Chi  YunLong  Li  ZhongQuan  Zhao  TongXian  Huang  TongMing  Ma  Qiang  Ge  Rui  Li  ChunHua  Guo  HaiSheng  Wang  GuangWei  Qiu  Feng  Lin  HaiYing  Hou  Mi  Wang  QunYao 《中国科学:物理学 力学 天文学(英文版)》2011,54(2):154-159
The 1.3 GHz superconducting radio-frequency (SRF) technology is one of the key technologies for the ILC and future XFEL and ERL projects in China. With the aim to develop 1.3 GHz SRF technology, IHEP has started a program to build an SRF Accelerating Unit. This unit contains a 9-cell 1.3 GHz superconducting cavity, a short cryomodule, a high power input coupler, a tuner and a low level RF system. This program also includes the SRF laboratory upgrade, which will permit the unit to be built and tested at IHEP. The unit will be used for the 1.3 GHz SRF system integration study, high power horizontal test and possible beam test in the future. In this paper, we report the recent R&D status of this program. The first large grain low-loss shape 9-cell superconducting RF cavity made by IHEP reached 20 MV/m in the first vertical test in July, 2010. The prototype tuner and low level RF (LLRF) system are under test. The high power input coupler and cryomodule are under fabrication. Several key SRF facilities for 9-cell cavity surface treatment and pre-tuning were successfully commissioned and are in operation.  相似文献   
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Liu  YaPing  Wang  GuangWei  Pan  WeiMin  Li  JiZhen  Liu  DeGui  Sun  Yi  Li  ZhongQuan  Dai  JianPing  Li  ShaoPeng  He  Kun  Wang  GuoPing  Zhao  GuangYuan  Ma  Qiang  Lin  HaiYing  Sha  Peng  Wang  QunYao  Qiu  Feng  Meng  FanBo  Li  Han 《中国科学:物理学 力学 天文学(英文版)》2011,54(2):178-181
Beijing Electron-Positron Collider Upgrade (BEPCII) adopts two 500 MHz superconducting cavities (SCCs) in each ring for higher accelerated gradient, higher Q and lower impedance (Wang et al. The proceedings of SRF’07). There’s no spare cavity due to the limited time and funding during BEPCII construction. If any serious trouble happened on either one of the two cavities and could not be recovered in a short time, the operation of BEPCII facility will be affected. Therefore, since 2009 three spare cavities have been fabricated in China to ensure reliable operation, and two of them have been successfully vertically tested in January and July 2011. This paper will briefly present the manufacture, post-process and vertical test performance of the 500 MHz spare cavities.  相似文献   
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By comparing the data of lattice parameters of more than 50 new FeAs-based high temperature superconductors in two syetems, the effect of bondlength on superconducting transition temperature (T C ) was found that, for both FeAs superconductor systems with similar ionic radii of cation A, the bond length L As-A between Arsenic atom and its nearest neighbor cation at the A site is in an inverse proportion to T C , i.e. the larger the bond length L As-A , the lower the T C . In addition, we also found a notice...  相似文献   
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The fluorescence spectra of three different dyes adsorbed on the tabular and cubic AgBr microcrystals are obtained by the picosecond time-resolved streak camera technique. The dependence of the ultrafast electron transferring from dye-aggregates to the conduction band of AgBr and the efficiency of spectral sensitization on different kinds of dyes with different concentrations is analyzed. Further more, the microcosmic mechanism of the sensitization process is discussed. It is found that the fluorescence decay curves are fitted very well by the double exponential function, consisting of a slow component and a fast one with large amplitude. We consider this fast one mainly attributable to the electron transfer from dye J-aggregates to the conduction band of AgBr. Supported by the National Natural Science Foundation of China (Grant No. 60478033), the Doctoral Foundation of Hebei Province of China (Grant No. B2003119), and the Science and Technology Project of Hebei Province of China (Grant No. 05215102)  相似文献   
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