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1.
V. A. Astapenko A. S. Kubankin N. N. Nasonov V. V. Polyanskiĭ G. P. Pokhil V. I. Sergienko V. A. Khablo 《JETP Letters》2006,84(6):281-284
The spectra of the collimated polarization bremsstrahlung of 7-MeV electrons intersecting Al, Cu, and Ni polycrystalline films have been measured. Detailed quantitative comparison of the experimental data with theoretical predictions has been performed. It has been shown that the model of a polycrystal as an ensemble of randomly oriented single crystals adequately describes the experimental results. This makes it possible to expect the development of a new method of diagnostics of the atomic structure of partially ordered solids. 相似文献
2.
3.
E. V. Sennikova A. S. Antsyshkina G. G. Sadikov A. V. Bicherov O. Yu. Korshunov G. S. Borodkin M. S. Korobov V. S. Sergienko N. N. Kharabaev A. D. Garnovskii 《Russian Journal of Coordination Chemistry》2008,34(5):315-321
The chelate and molecular complexes of 2-(2-benzazolyl, perimidyl)-indandiones-1,3 were synthesized for the first time. The structures of the ligands (tautomeric forms) and complex compounds were determined from the X-ray diffraction, 1H, 13C NMR, and IR data and the quantum-chemical calculations (RHF SCF in 6-31 G** basis). 相似文献
4.
V. N. Korneev P. M. Sergienko V. A. Shlektarev V. M. Aul’chenko M. A. Bukin V. M. Titov B. P. Tolochko M. R. Sharafutdinov A. V. Zabelin E. I. Litvinov A. M. Matyushin V. G. Stankevich M. A. Sheromov O. V. Naida A. A. Vazina 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2007,1(1):99-104
To modernize the DICSI station, new hardware and software have been created according to the conditions of the operating storage ring “Sibir’-2” beam channel. The recording system has been successfully tested on the operating channel of the storage ring VEPP-3 (Budker Institute of Nuclear Physics Siberian Branch, Russian Academy of Sciences, Novosibirsk) using the time-resolved “diffraction cinema” technique in studying real biological objects in the static and dynamic modes of data accumulation. At the DICSI station, structural changes in medical and biological objects are permanently investigated. The specific structure dimensions of these objects are in the nanometric range. 相似文献
5.
L. V. Baikalova V. I. Sokol I. A. Zyryanova I. V. Fedyanin V. N. Khrustalev E. A. Zel’bst O. A. Tarasova V. S. Sergienko B. A. Trofimov 《Russian Journal of General Chemistry》2006,76(5):791-797
The crystal and molecular structures of bis(1-isopropenylimidazole)dichlorocobalt (C12H16Cl2·N4Co) [R 0.036 (R W 0.089) for 3229 unique reflections with I > 2σ(I)] and tetra(1-vinylimidazole)dichlorocobalt (C20H24Cl2N8Co) [R 0.031 (R W 0.072) for 1863 unique reflections with I > 2σ(I)] were determined. In these molecular complexes, the monodentate terminal 1-alkenylimidazole ligands coordinate to the metal via a “pyridine” nitrogen atom. In C12H16Cl2N4Co, the Co atom has a distorted tetrahedral 2N,2Cl coordination. The coordination polyhedron of cobalt in C20H24Cl2N8Co is a strongly elongated 4N,2Cl octahedron. The Co-N and Co-Cl bonds [Co-N 2.015(2) and 2.032(4) Å; Co-Cl 2.229(2) Å] in the tetrahedral complex C12H16Cl2N4Co are shorter than those in the octahedral complex C20H24Cl2N8Co [Co-N 2.134(2) and 2.157(2) Å; Co-Cl 2.518(1) Å]. In the structures of both complexes there are short contacts involving the Cl atoms. 相似文献
6.
Davydov V. V. Al-Salekh O. A. Mercur'eva N. Yu. Ryabov M. A. Sokol V. I. Sergienko V. S. Shklyaev Yu. V. 《Russian Journal of Coordination Chemistry》2003,29(1):16-21
Twenty new complexes were synthesized by reacting Co(II), Cu(II), Zn, Cr(III), Fe(III), Cd and Ag salts with 3,3-dimethyl-1-(3-methylpyrazole-5-onilidene-4)-1,2,3,4-tetrahydroisoquinoline (L1), spiro{cyclohexane-1,3"-[1-(1-phenyl-3-methylpyrazole-5-onilidene-4)-1,2,3,4-tetrahydroisoquinoline]} (L2), and 3,3-dimethyl-1-(1-phenyl-3-methylpyrazole-5-onilidene-4)-1,2,3,4-tetrahydroisoquinoline (L3). These compounds were studied by IR and electronic absorption spectroscopy. The type of coordination of their ligands was discussed on the basis of the results obtained and X-ray diffraction data for L3 and [CuL2
2 Cl2] · 2L2 obtained previously. 相似文献
7.
A. é. Mistryukov I. D. Sadekov V. S. Sergienko G. M. Abakarov M. A. Porai-Koshits A. A. Shneider A. D. Garnovskii 《Chemistry of Heterocyclic Compounds》1989,25(12):1407-1409
The crystal and molecular structure of 2-phenylbenzotellurazole is determined by x-ray methods. The heterocyclic fragment of the molecule is planar. The dihedral angle between planes of the heterocycle and the 2-phenyl substituent is 31.2. Somewhat shortened Te-N intermolecular ocntacts (3.43 å) are seen in the crystal. These do not substantially affect the physical properties of the compound.For Communication 3, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1690–1692, December, 1989. 相似文献
8.
L. A. Zemnukhova S. V. Tomshich V. A. Mamontova N. A. Komandrova G. A. Fedorishcheva V. I. Sergienko 《Russian Journal of Applied Chemistry》2004,77(11):1883-1887
The composition and content of polysaccharides obtained from different samples of rice husk by successive treatment with water, ammonium oxalate (or oxalic acid), and alkali were studied. The chemical composition of the rice husk residues after the extraction was examined, and the possibility of their use for preparing amorphous silica or cellulose-containing products, depending on the hydrolysis conditions, was assessed.Translated from Zhurnal Prikladnoi Khimii, Vol. 77, No. 11, 2004, pp. 1901–1904.Original Russian Text Copyright © 2004 by Zemnukhova, Tomshich, Mamontova, Komandrova, Fedorishcheva, Sergienko. 相似文献
9.
Kavun V. Ya. Uvarov N. F. Sergienko V. I. Zemnukhova L. A. 《Russian Journal of Coordination Chemistry》2004,30(7):505-510
The internal mobility of fluoride ions and electrophysical characteristics of alkali metal tetrafluoroantimonates(III) (M = Na, K, Rb, and Cs) are studied by 19F NMR and impedance spectroscopies. The types of ion motions in the anionic sublattice of these compounds are determined in the 180-510 K temperature range. The superionic conductivity of the MSbF4 compounds is established above 480 K ( 2.9 × 10-2 to 1.3 × 10-4 S/cm). 相似文献
10.