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Ali Sarafraz-Yazdi Soroosh Sepehr Zarrin Es’haghi Hamed Piri Moghadam 《Chromatographia》2010,72(9-10):923-931
In this research, the sol–gel technology was applied for the preparation of solid-phase microextraction fibers for extracting of methyl tert-butyl ether (MTBE) from environmental water samples. For this purpose, two different polymers such as poly(ethylene glycol) (PEG) and combination of PEG and multiwall carbon nanotubes (MWCNTs) were prepared using sol–gel technology as coating procedure for the fibers. The pre-concentration process followed by GC–FID determination was used and the results evidenced that pre-concentration factor for PEG/CNTs fiber was approximately five times higher than PEG. Parameters affecting the extraction efficiency such as temperature, extraction time, stirring speed and salt effect for each fiber were investigated and optimized. On the optimal conditions, the linear range for MTBE with PEG and PEG/CNT fibers were 10–3,000 and 1–1,000 ng mL?1 and the detection limits (S/N = 3) were 1.0 and 0.3 ng mL?1, respectively. The sol–gel PEG/CNTs fiber has good performance and therefore relatively better figures of merit and experimental results such as thermal stability (up to 320 °C), average of life time (over 150 times) and repeatability (RSD < 4) in comparison to conventional PDMS/Carboxen fiber, which was already reported for determination of MTBE. 相似文献
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The convective instability of a horizontal liquid layer confined in an annular Hele–Shaw cell subject to a constant rotation and submitted to a centrifugal gradient of temperature is investigated. Using a linear stability analysis, we study the effects of both Coriolis forces and curvature aspect on the stationary convective threshold when the Prandtl number is of the order of unity or larger than unity. We show that the Coriolis forces have a stabilizing effect, and the wave number is independent of these forces. However, a multicellular regime in the radial direction is observed for small Ekman numbers. The results related to the influence of the curvature are also shown. To cite this article: S. Ramezani et al., C. R. Mecanique 330 (2002) 633–640. 相似文献
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Base‐Catalyzed Formation of Isoxazoles from Dialkyl Acetylenedicarboxylates and 2‐Nitroacetophenones 下载免费PDF全文
The reaction of dialkyl acetylenedicarboxylates with 1‐aryl‐2‐nitroethanones in the presence of pyridine leads to dialkyl 5‐aryloyl‐isoxazole‐3,4‐dicarboxylates through a novel mechanism, which involves a [2+2] cycloaddition/ring opening/cyclization sequence. 相似文献
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Niloofar Parizadeh Eskandar Alipour Sepehr Soleymani Rezvan Zabihollahi Mohammad Reza Aghasadeghi 《Phosphorus, sulfur, and silicon and the related elements》2018,193(4):225-231
Novel quinolone derivatives featuring an 1,3,4-oxadiazole ring as a metal-chelating component and a benzyl group base on HIV-1 integrase inhibitors pharmacophore were designed and synthesized. An antiviral assay revealed that most analogues inhibited HIV-1 replication in the cell culture. Our results showed that compounds bearing small alkyl groups as R group were inactive in anti-HIV-1 assay, whereas compounds possessing benzyl or substituted benzyl at the same position showed good anti-HIV activity with the range of 20–57% at 100 μM concentration. Among them, 3-(5-((2-fluorobenzyl)thio)-1,3,4-oxadiazol-2-yl)-8-phenylquinolin-4-(1H)-one (compound 13) showed reasonable cell-based antiviral activity (EC50 = 50 μM) with no considerable cytotoxicity (CC50 > 100 μM) in the cell viability assay, suggesting that it may be amenable to further development for identifying new anti-HIV-1 agents. Docking studies using the later crystallographic data available for PFV integrase corroborate favorable binding to the active site of HIV integrase, providing a basis for the design of more potent analogues. 相似文献
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A novel model of Cw diode pumped Yb:YAG thin disk laser has been presented to simulate absorption pump power distribution by Monte-Carlo ray tracing. Comparing obtained results with the common distribution function indicate the offered model is quite trustful. So these findings help to evaluate temperature distribution due to the 3D finite element analyses (FEA) based on heat conduction equation. To improve our simulation the temperature dependent of crystal property such as the absorption coefficient, thermal conductivity, stimulated emission cross section and Boltzman population factors are considered by a numerical iterative approach. 相似文献
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Zare Davijani Neda Kia-Kojoori Reza Abdolmohammadi Shahrzad Sadegh-Samiei Sepehr 《Molecular diversity》2022,26(4):2121-2134
Molecular Diversity - In this research, we synthesized the Fe3O4/CuO/ZnO@MWCNT magnetic nanocomposites using water extract of Petasites hybridus rhizome, and the high performance of synthesized... 相似文献
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To study the safety and potential health benefits of soy isoflavones, a rapid and simple method based on liquid chromatography combined with mass spectrometry (LC/MS) and photodiode array detector (PDA) was developed for the determination of isoflavones in rat plasma. The analytes included daidzein, genistein, glycitein, equol, 4-ethyl phenol, and biochanin A over a concentration range of 1.0-4320.0 nM using 75 microL of rat plasma. Rat plasma samples were hydrolyzed by adding an enzyme mixture from Helix pomatia containing glucuronidase and sulfatase to convert the isoflavone beta-glycosides daidzin, genistin, and glycitin to their active aglycone forms. A liquid-liquid extraction method using ethyl acetate as the extraction solvent was used to extract aglycones and the internal standards (phenolphthalein beta-D glucuronide, 4-methylumbelliferyl sulfate, and apigenin) from digested plasma samples. The extract was evaporated to dryness under a nitrogen stream, reconstituted with 0.1% formic acid in water-acetonitrile (85 + 15), and injected into a Zorbax SB-CN reversed-phase column (4.6 x 75 mm, 3.5 microm particle size). The Micromass ZQ detector was operated in the positive ion selected-ion monitoring mode. The flow rate for LC was 1.0 mL/min, with a split where 25% of the effluent was introduced into the electrospray ionization probe of the MS instrument and 75% into the PDA. The chromatographic run time was 16.0 min, with delay of 10 min/injection. The interday precision and accuracy of the standard samples were <2.6% relative standard deviation and <10% relative error, respectively. Recovery of the reported isoflavones with this method varied from 86 to 100%. 相似文献