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排序方式: 共有100条查询结果,搜索用时 15 毫秒
1.
Louis Dressler Hendrik Nicolai Senda Agrebi Florian Ries Amsini Sadiki 《Entropy (Basel, Switzerland)》2022,24(5)
This contribution presents a straightforward strategy to investigate the entropy production in stratified premixed flames. The modeling approach is grounded on a chemistry tabulation strategy, large eddy simulation, and the Eulerian stochastic field method. This enables a combination of a detailed representation of the chemistry with an advanced model for the turbulence chemistry interaction, which is crucial to compute the various sources of exergy losses in combustion systems. First, using detailed reaction kinetic reference simulations in a simplified laminar stratified premixed flame, it is demonstrated that the tabulated chemistry is a suitable approach to compute the various sources of irreversibilities. Thereafter, the effects of the operating conditions on the entropy production are investigated. For this purpose, two operating conditions of the Darmstadt stratified burner with varying levels of shear have been considered. The investigations reveal that the contribution to the entropy production through mixing emerging from the chemical reaction is much larger than the one caused by the stratification. Moreover, it is shown that a stronger shear, realized through a larger Reynolds number, yields higher entropy production through heat, mixing and viscous dissipation and reduces the share by chemical reaction to the total entropy generated. 相似文献
2.
Ko-Ki Kunimoto Kouji Kimura Takatomo Takai Hitoshi Senda Motoo Shiro Akio Kuwae 《光谱学快报》2013,46(4):509-522
Two polymorphic forms (I and II) of 4-fluorophenylpyruvic acid (F-PPA) were obtained by crystallization from different solvents, showing a melting point at 163.2 and 171.0 °C. Crystal structures of polymorphs I and II were determined by X-ray crystallography. IR and Raman spectra of the two polymorphs were measured and the spectral characteristics were compared with those of phenylpyruvic acid. the two polymorphs show similar molecular and crystal structures to each other, except for the molecular geometries of the enol and the carboxylic acid moieties. Distinct IR spectral differences which result from the crystal field splitting were observed between the two polymorphs. 相似文献
3.
4.
Kambale Mondo Senda Agrebi Fathi Hamdi Fatma Lakhal Amsini Sadiki Mouldi Chrigui 《Entropy (Basel, Switzerland)》2022,24(5)
Even though there is a pressing interest in clean energy sources, compression ignition (CI) engines, also called diesel engines, will remain of great importance for transportation sectors as well as for power generation in stationary applications in the foreseeable future. In order to promote applications dealing with complex diesel alternative fuels by facilitating their integration in numerical simulation, this paper targets three objectives. First, generate novel diesel fuel surrogates with more than one component. Here, five surrogates are generated using an advanced chemistry solver and are compared against three mechanisms from the literature. Second, validate the suggested reaction mechanisms (RMs) with experimental data. For this purpose, an engine configuration, which features a reacting spray flow evolving in a direct-injection (DI), single-cylinder, and four-stroke motor, is used. The RNG k-Epsilon coupled to power-law combustion models is applied to describe the complex in-cylinder turbulent reacting flow, while the hybrid Eulerian-Lagrangian Kelvin Helmholtz-Rayleigh Taylor (KH-RT) spray model is employed to capture the spray breakup. Third, highlight the impact of these surrogate fuels on the combustion properties along with the exergy of the engine. The results include distribution of temperature, pressure, heat release rate (HRR), vapor penetration length, and exergy efficiency. The effect of the surrogates on pollutant formation (, , ) is also highlighted. The fifth surrogate showed 47% exergy efficiency. The fourth surrogate agreed well with the maximum experimental pressure, which equaled 85 Mpa. The first, second, and third surrogates registered 400, 316, and 276 g/kg fuel, respectively, of the total CO mass fraction at the outlet. These quantities were relatively higher compared to the fourth and fifth RMs. 相似文献
5.
Substituted alkylcyclohexanones were hydrogenated over several transition metal catalysts. The hydrogenation with freshly prepared Raney Ni gave predominantly the axial alcohols but catalyst to which sodium hydroxide was added or aged catalyst increased the stereoselectivity. In contrast to the PtO2 hydrogenation in which the equatorial alcohols were favoured, more axial alcohols were obtained than the equatorial counterparts on Pt-black. On Pd catalyst the isomeric ratios of the cyclohexanols changed as the reaction progressed. This may be due to a decrease in the amount of hydrogen available caused by the strong adsorption of ketones on the catalyst. Rh catalyst gave more of the axial alcohols than any other catalyst used in the present study. 相似文献
6.
Reaction of 5-formyl-1,3-dimethyluracil with some active methylene compounds in the presence of base causes novel ring transformations to give the p-hydroxybenzoates and the nicotinate. 相似文献
7.
Hanai K Kuwae A Takai T Senda H Kunimoto KK 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2001,57(3):513-519
The IR and Raman spectra of the two polymorphic forms (58 degree- and 68 degree-forms) of cis-cinnamic acid were measured, and the spectral differences discussed on the basis of the crystal structures of the two forms. The IR bands related to the COOH group differ in the frequencies and band shape, reflecting differences in the hydrogen bonding between the two modifications. These spectra were compared with those of trans-cinnamic acid. The IR, Raman, and NMR spectra of the isotopic compounds, including the deuterated and 13C analogs of the cis and trans acids, were also recorded in the solid state and in solution to confirm the spectral assignments. 相似文献
8.
(2R,5S)-2-Methyl-5-hexanolide and its antipode were synthesized in highly optically pure state (?98–99% e.e.) starting from ethyl (S)-lactate and the enantiomers of methyl β-hydroxyisobutyrate. The specific rotations of our samples were [α]D±91.0-93.5° (CHCl3), while the reported values of the samples prepared by resolution or asymmetric synthesis were ±64.5–65.6°. 相似文献
9.
In a prototype of an adenine analyser, adenosine and adenine nucleotides were derivatized with a fluorescent reagent, bromoacetaldehyde, after separation on a Hitachi gel No. 3012-N column by high-performance liquid chromatography. The previous analyser was improved by using a shorter reaction coil and by introduction of a Hitachi gel No. 3013-N with 5-microns particles of porous polystyrene-divinylbenzene, and applied to estimate the freshness of porgy. Total amounts of ATP, ADP and AMP in an isolated muscle just after death gradually decreased to 60% of the original amount after 5 h, and the ATP content rapidly decreased to 20% after 1 h. A good correlation was found between the levels of total adenine compounds and the energy charge values obtained from nineteen porgies frozen at a prerigour state. On the other hand, there existed no relationship between total adenine levels and the K values, which were indices for estimating freshness of fish. The analyser will be useful to evaluate the freshness of tissues and cells based on the higher contents of total adenine compounds, especially ATP. 相似文献
10.
A theoretical analysis of the current-potential curves for facilitated ion transfer across an oil/water interface is presented for the case where two complex species having an ion-to-ligand ratio of 1:1 and 1:2 are allowed to exist in the oil phase. Cyclic voltammograms are calculated numerically by using a finite difference method assuming that the ion transfer is reversible and the complex formation equilibria are maintained throughout the oil phase. When the ligand concentration in the oil phase is much smaller than the ion concentration in the aqueous phase and the former limits the ion-transfer current, two well separated peaks may develop even under the assumption of equilibrium conditions for the complex formation. The shape of the voltammogram is determined primarily by the ratio of the two reduced stability constants: b1 = K1bcLO and b2 = K1K2(bcOL)2, where K1 and K2 are the stability constants for 1:1 and 1:2 complexes in the oil phase and bcOL the ligand concentration in the bulk of the oil phase. The degree of peak separation thus depends not only on K2/K1 but also on bcOL. A method for estimating the two stability constants from the voltammograms is proposed. 相似文献