排序方式: 共有29条查询结果,搜索用时 15 毫秒
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Pinto RD Sartorelli JC 《Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics》2000,61(1):342-347
A sequence of attractors, reconstructed from interdrops time series data of a leaky faucet experiment, is analyzed as a function of the mean dripping rate. We established the presence of a saddle point and its manifolds in the attractors and we explained the dynamical changes in the system using the evolution of the manifolds of the saddle point, as suggested by the orbits traced in first return maps. The sequence starts at a fixed point and evolves to an invariant torus of increasing diameter (a Hopf bifurcation) that pushes the unstable manifold towards the stable one. The torus breaks up and the system shows a chaotic attractor bounded by the unstable manifold of the saddle. With the attractor expansion the unstable manifold becomes tangential to the stable one, giving rise to the sudden disappearance of the chaotic attractor, which is an experimental observation of a so called chaotic blue sky catastrophe. 相似文献
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Aprile E Arisaka K Arneodo F Askin A Baudis L Behrens A Bokeloh K Brown E Bruch T Bruno G Cardoso JM Chen WT Choi B Cline D Duchovni E Fattori S Ferella AD Gao F Giboni KL Gross E Kish A Lam CW Lamblin J Lang RF Levy C Lim KE Lin Q Lindemann S Lindner M Lopes JA Lung K Undagoitia TM Mei Y Fernandez AJ Ni K Oberlack U Orrigo SE Pantic E Persiani R Plante G Ribeiro AC Santorelli R dos Santos JM Sartorelli G Schumann M Selvi M Shagin P Simgen H Teymourian A Thers D Vitells O Wang H Weber M 《Physical review letters》2011,107(13):131302
We present results from the direct search for dark matter with the XENON100 detector, installed underground at the Laboratori Nazionali del Gran Sasso of INFN, Italy. XENON100 is a two-phase time-projection chamber with a 62 kg liquid xenon target. Interaction vertex reconstruction in three dimensions with millimeter precision allows the selection of only the innermost 48 kg as the ultralow background fiducial target. In 100.9 live days of data, acquired between January and June 2010, no evidence for dark matter is found. Three candidate events were observed in the signal region with an expected background of (1.8 ± 0.6) events. This leads to the most stringent limit on dark matter interactions today, excluding spin-independent elastic weakly interacting massive particle (WIMP) nucleon scattering cross sections above 7.0 × 10(-45) cm(2) for a WIMP mass of 50 GeV/c(2) at 90% confidence level. 相似文献
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Giuseppe Giordano Krishnamurthy Shyam Alan C. Sartorelli Walter J. McMurray 《Journal of mass spectrometry : JMS》1992,27(5):633-635
Several 1,2,2-tris(sulfonyl)hydrazines, conceived as prodrugs of 1,2-bis(sulfonyl)hydrazines and synthesized as potential antineoplastic and trypanocidal drugs, were analyzed by mass Spectrometry as part of the confirmation of the structure of these compounds. Since these compounds showed activity against several transplanted animal tumors, an understanding of the mass spectral behavior of these agents is important to gain information should clinical trials and metabolic studies be undertaken. In all spectra, protonated molecular ions were observed. Collision activation resulted in considerable fragmentation in the fast atom bombardment spectra. Rearrangement ions formed by elimination of substituted diimides from the middle of the molecule were observed. Other rearrangements involving the alkyl substituent and sulfonyl oxygen also occurred. 相似文献
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Bioactivity-guided fractionation of n-hexane phase from MeOH extract of the seeds of Cassia fistula L. (Leguminosae) yielded two bioactive substances against Cladosporium cladosporioides and C. sphaerospermum. After spectroscopic analysis, these compounds were characterised as the known benzyl 2-hydroxy-3,6-dimethoxybenzoate and its dimer dibenzyl 2,2'-dihydroxy-3,6,3″,6″-tetramethoxy-biphenyl-1,1'-dicarboxylate, which showed a new structural arrangement. 相似文献
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Brian T. Heaton Luciano Longhetti D. Michael P. Mingos Clive E. Briant Peter C. Minshall Brian R.C. Theobald Luigi Garlaschelli Ugo Sartorelli 《Journal of organometallic chemistry》1981,213(1):333-350
The crystal structures of Rh4(CO)10(PPh3)2 and Rh4(CO)9P(OPh)33 are reported. 31P-1H NMR studies on Rh4(CO)12-x {P(OPh)3}x(X 1, 2 and 3) show that each derivative exists as only one isomer in solution whereas the analogous triphenylphosphine derivatives can exist as different isomers. A quantitative redistribution of triphenylphosphites occurs on mixing Rh4-(CO)12-xLx with Rh4(CO)12-yLy (L P(OPh)3; x 0, 1, 2, y x + 2; x 0, y x + 4) to give Rh4(CO)12-zLz[z (x + y)]; a related rapid intermolecular randomisation of carbonyls occurs on mixing Rh4(12CO)12 with Rh4(13CO)12. 相似文献
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N.Yu. Agafonova M. Aglietta P. Antonioli G. Bari A. Bonardi V.V. Boyarkin G. Bruno W. Fulgione P. Galeotti M. Garbini P.L. Ghia P. Giusti E. Kemp V.V. Kuznetsov V.A. Kuznetsov A.S. Malguin H. Menghetti R. Persiani A. Pesci I.A. Pless A. Porta V.G. Ryasny O.G. Ryazhskaya O. Saavedra G. Sartorelli M. Selvi C. Vigorito L. Votano V.F. Yakushev G.T. Zatsepin A. Zichichi 《The European Physical Journal C - Particles and Fields》2007,52(4):849-855
The CERN Neutrino to Gran Sasso (CNGS) project aims to produce a high energy, wide band νμ beam at CERN and send it toward the INFN Gran Sasso National Laboratory (LNGS), 732 km away. Its main goal is the observation
of the ντ appearance, through neutrino flavour oscillation. The beam started its operation in August 2006 for about 12 days: a total
amount of 7.6×1017 protons were delivered to the target. The LVD detector, installed in hall A of the LNGS and mainly dedicated to the study
of supernova neutrinos, was fully operating during the whole CNGS running time. A total number of 569 events were detected
in coincidence with the beam spill time. This is in good agreement with the expected number of events from Monte Carlo simulations.
PACS 14.60.Pq; 29.27.Fh; 29.40.Mc; 95.55.Vj 相似文献
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T. Pereira M.S. Baptista M.B. Reyes I.L. Caldas J.C. Sartorelli J. Kurths 《Chaos, solitons, and fractals》2009,39(5):2198-2210
We show a scenario of a two-frequency torus breakdown, in which a global bifurcation occurs due to the collision of a quasi-periodic torus T2 with saddle points, creating a heteroclinic saddle connection. We analyze the geometry of this torus-saddle collision by showing the local dynamics and the invariant manifolds (global dynamics) of the saddle points. Moreover, we present detailed evidences of a heteroclinic saddle-focus orbit responsible for the type-II intermittency induced by this global bifurcation. We also characterize this transition to chaos by measuring the Lyapunov exponents and the scaling laws. 相似文献
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Ivanildo A. Brito Fernanda Thevenard Thais A. Costa-Silva Samuel S. Oliveira Rodrigo L. O. R. Cunha Emerson A. de Oliveira Patricia Sartorelli Rafael C. Guadagnin Maiara M. Romanelli Andre G. Tempone Joo Henrique G. Lago 《Molecules (Basel, Switzerland)》2022,27(3)
As part of our continuous studies involving the prospection of natural products from Brazilian flora aiming at the discovery of prototypes for the development of new antiparasitic drugs, the present study describes the isolation of two natural acetylene acetogenins, (2S,3R,4R)-3-hydroxy-4-methyl-2-(n-eicos-11′-yn-19′-enyl)butanolide (1) and (2S,3R,4R)-3-hydroxy-4-methyl-2-(n-eicos-11′-ynyl)butanolide (2), from the seeds of Porcelia macrocarpa (Warm.) R.E. Fries (Annonaceae). Using an ex-vivo assay, compound 1 showed an IC50 value of 29.9 μM against the intracellular amastigote forms of Leishmania (L.) infantum, whereas compound 2 was inactive. These results suggested that the terminal double bond plays an important role in the activity. This effect was also observed for the semisynthetic acetylated (1a and 2a) and eliminated (1b and 2b) derivatives, since only compounds containing a double bond at C-19 displayed activity, resulting in IC50 values of 43.3 μM (1a) and 23.1 μM (1b). In order to evaluate the effect of the triple bond in the antileishmanial potential, the mixture of compounds 1 + 2 was subjected to catalytic hydrogenation to afford a compound 3 containing a saturated side chain. The antiparasitic assays performed with compound 3, acetylated (3a), and eliminated (3b) derivatives confirmed the lack of activity. Furthermore, an in-silico study using the SwissADME online platform was performed to bioactive compounds 1, 1a, and 1b in order to investigate their physicochemical parameters, pharmacokinetics, and drug-likeness. Despite the reduced effect against amastigote forms of the parasite to the purified compounds, different mixtures of compounds 1 + 2, 1a + 2a, and 1b + 2b were prepared and exhibited IC50 values ranging from 7.9 to 38.4 μM, with no toxicity for NCTC mammalian cells (CC50 > 200 μM). Selectivity indexes to these mixtures ranged from >5.2 to >25.3. The obtained results indicate that seeds of Porcelia macrocarpa are a promising source of interesting prototypes for further modifications aiming at the discovery of new antileishmanial drugs. 相似文献
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B.T. Heaton L. Longhetti L. Garleschelli U. Sartorelli 《Journal of organometallic chemistry》1980,192(3):431-435
Variable temperature 13C-{31P, 1H} NMR studies on Rh4(CO)8 {P(OPh)3}4 show that the solid state structure is maintained in solution at low temperature; at higher temperatures carbonyl migration occurs around the metal polyhedron with the lowest energy migration occurring via a Cotton type mechanism which also involves a rocking motion about the unique rhodium in the basal plane. At +82°C, the fast exchange limiting 13C-{31P, 1H} and 31P spectra exhibit a quintet and doublet of quartets, respectively. 相似文献