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1.
Hamid R Zare Masoud Salavati-Niassary Farkhondeh Memarzadeh Mohammad Mazloum Navid Nasirizadeh 《Analytical sciences》2004,20(5):815-819
A novel membrane coated platinum-wire electrode (MCPWE) based on N,N'-bis(2-thienylmethylene)-1,2-diaminobenzene (BTMD) for highly selective determination of Ag+ ion has been developed. The influences of membrane composition and pH on the potentiometric responses of electrode were investigated. The potentiometric responses are independent of the pH of the test solution in the range of 5.0 - 9.0. The electrode shows a linear response for Ag+ ion over the concentration range of 1.0 x 10(-60 to 1.0 x 10(-1) M with a lower detection limit of 6.0 x 10(-7) M. The electrode possesses a Nernstian slope of 59.7 mV decade(-1) and a fast response time of < or = 17 s and can be used for at least 2 months without any observable deviation. The proposed electrode displayed very good selectivity for Ag+ ion with respect to NH4+ and alkali, alkaline earth and some common transition metal ions. The practical utility of the electrode has been demonstrated by its use as the indicator electrode in the potentiometric titration of an AgNO3 solution with a NaI solution and in determination of the silver content of a developed radiological film. 相似文献
2.
[reaction: see text] Conformationally constrained side chain-bridged cyclic peptides were prepared using bis-carboxylic acid ring spacers. These macrocyles were designed to inhibit protein-protein interactions mediated by the third PDZ domain (PDZ3) of a mammalian neuronal protein, PSD-95. Isothermal titration calorimetry (ITC) experiments measured dissociation constants in the low micromolar range. For each compound, the change in entropy (TdeltaS) of binding either is comparable in magnitude to the enthalpy change (deltaH) or is the predominant driving force for association. 相似文献
3.
A. N. Andreyev D. D. Bogdanov V. I. Chepigin A. P. Kabachenko O. N. Malyshev Yu. Ts. Oganessian R. N. Sagajdak G. M. Ter-Akopian A. V. Yeremin F. P. Hessberger S. Hofmann V. Ninov M. Florek S. Saro M. Veselsky 《Zeitschrift für Physik A Hadrons and Nuclei》1992,344(2):225-226
The neutron-deficient isotopes257,258105 were produced in the reaction27Al+236u in 6n and 5n evaporation channels, respectively. The evaporation residues emerging from the target were separated in-flight from the projectiles and from products of different nuclear reactions by the electrostatic separator VASSILISSA [1]. The isotopes were then implanted into position-sensitive silicon detectors and identified using the --correlation method. The measured production cross-section is (5n)=(0.45±0.20)nb atE
P
=154 MeV and (6n)=(0.075±0.055) nb atE
P
=163 MeV. These cross-sections are compared with data measured for the same isotopes in the more symmetrical reaction50Ti+209Bi. 相似文献
4.
A previously developed flame synthesis method was applied to the preparation of mesoporous titania films for application in dye sensitized solar cells (DSSC). The method combines the synthesis of narrowly sized, ultrafine metal oxide particles with controllable chemical and phase purity and the deposition of these particles into a uniform, porous thin film in a single step. The current work used a series of ethylene–oxygen–argon flames to produce DSSC anode films of wide ranging properties. The performance of the solar cells prepared with these anode films was studied at the fundamental level with respect to variations of the titania crystal phase purity and content resulting from changes primarily from flame stoichiometry changes. Based on the basic relationship established among flame synthesis condition-material property-cell performance, a highly efficient DSSC was designed, which shows photocurrent densities better than some of the best performing cells reported to date. Additional studies have focused on a demonstration of the suitability of the flame process in engineering TiO2 films structurally and chemically with the potential of further improved DSSC efficiency. 相似文献
5.
M. Sahrai R. Nasehi M. Memarzadeh H. Hamedi J. B. Poursamad 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2011,65(3):571-579
Absorptive and dispersive properties of a four-level Λ-type atomic
system with two fold lower levels are investigated. The effect of quantum interference
induced by incoherent pump and spontaneous emission upon the absorption, dispersion, and
group index is them discussed. In addition, the rate of an incoherent pump field and the
intensity of coupling field on light propagation is also presented. 相似文献
6.
Saro Memarzadeh Erik D. Tolmachoff Denis J. Phares Hai Wang 《Proceedings of the Combustion Institute》2011,33(2):1917-1924
The properties of TiO2 nanoparticles synthesized using the flame stabilized on a rotating surface method (FSRS) are investigated. The method uses a laminar, premixed, stagnation flame, combining particle synthesis and film deposition in a single step. The current study examines the effects of flame properties on particle characteristics. Synthesized particles were characterized using X-ray diffractometry, Transmission Electron Microscopy and UV–vis spectrometry in order to quantify the effects of equivalence ratio and precursor loading on particle size, crystallinity and optical band-gap. Results show that flame stoichiometry significantly affects crystal phase, but it has little to no effect on particle size and light absorption band edge. In addition, precursor loading impacts both the particle size and the crystal phase. The study demonstrates the potential of the FSRS method for producing tailored nanoscale TiO2 particles for a variety of applications. 相似文献
7.
Although one-dimensional nonlinear photonic crystal (1D-NPC) has been widely studied, there is no comprehensive analysis on decreasing the bistability threshold power.In this paper, conditions required to create bistability have been specified for two types of structures of alternative high and low refractive index layers and defect layers with Kerr nonlinearity effect, in the order of (HL)p(D)q(LH)p and (LH)p(D)q(HL)p, where L and H denote low and high refractive index layers, respectively, D stands for the defect layers, p is the number of LH or HL layers and q is the number of defect layers.One of the essentials for the bistability is appropriate shifts of frequency of the defect mode, so the effect of the order of layer's arrangement in (1D-NPC) structures have been studied. Different structures have been introduced and the best structure for the lowest bistability threshold power has been proposed. Nonlinear finite-difference time-domain (NFDTD) in C++ has been employed for simulation. 相似文献
8.
A.N. Andreyev D. Ackermann P. Cagarda J. Gerl F.P. Heßberger S. Hofmann M. Huyse A. Keenan H. Kettunen A. Kleinböhl A. Lavrentiev M. Leino B. Lommel M. Matos G. Münzenberg C.J. Moore C.D. O'Leary R.D. Page S. Reshitko S. Saro C. Schlegel H. Schaffner M.J. Taylor P. Van Duppen L. Weissman R. Wyss 《The European Physical Journal A - Hadrons and Nuclei》2001,10(2):129-133
The 137I nucleus, populated in the spontaneous fission of 248Cm has been studied by means of prompt γ-ray spectroscopy using the EUROGAM2 array. Medium-spin yrast excitations in 137I were observed for the first time. The experimental level scheme is compared to the shell model calculation with modified
Kuo-Herling interaction. The theoretical predictions differ significantly from the experimental results, indicating that the
excitation pattern in 137I deviates significantly from the shell model scheme.
Received: 6 June 2001 / Accepted: 4 October 2001 相似文献
9.
Measurement of evaporation residue cross-sections of the reaction 30Si + 238U at subbarrier energies
K. Nishio S. Hofmann F. P. Heßberger D. Ackermann S. Antalic V. F. Comas Z. Gan S. Heinz J. A. Heredia H. Ikezoe J. Khuyagbaatar B. Kindler I. Kojouharov P. Kuusiniemi B. Lommel R. Mann M. Mazzocco S. Mitsuoka Y. Nagame T. Ohtsuki A. G. Popeko S. Saro H. J. Schött B. Sulignano A. Svirikhin K. Tsukada K. Tsuruta A. V. Yeremin 《The European Physical Journal A - Hadrons and Nuclei》2006,29(3):281-287
The reaction 30Si + 238U → 268Sg* was studied at beam energies close to the Coulomb barrier. At a center-of-mass energy of E
c.m. = 144.0MeV for reactions at half thickness of the target we measured three decay chains of 263Sg produced by evaporation of five neutrons. The cross-section was ( 67+67
-37) pb. At E
c.m. = 133.0MeV we measured three spontaneously fissioning nuclei which we assigned to the isotope 264Sg. The production cross-section was ( 10+10
-6) pb and a half-life of ( 120+126
-44) ms was determined. This half-life is a factor of twenty shorter than theoretical predictions. At E
c.m. = 128.0MeV an upper cross-section limit of 15pb was measured. The cross-section data reveal a strong influence of the orientation
of the deformed target nucleus on the production yield. Compared to excitation functions measured for the lighter system 16O + 238U → 254Fm*, a reduction of the fusion probability was observed at low beam energies indicating increasing competition from quasifission
processes. 相似文献
10.
In this work, isobaric (vapour + liquid) equilibrium data have been determined at (53.3 and 91.3) kPa for the binary mixtures of (1-propanol + 1-butanol). The thermodynamic consistency of the experimental values was checked by means the traditional area test and the direct test methods. According to the criteria for the test methods, the (vapour + liquid) equilibrium results were found to be thermodynamically consistent. The experimental values obtained were correlated by using the van Laar, Margules, Wilson, NRTL, and UNIQUAC activity-coefficient models. The binary interaction parameters of the activity-coefficient models have been determined and reported. They have been compared with those calculated by the activity-coefficient models. The average absolute deviation in boiling point and vapour-phase composition were determined. The calculated maximum average absolute deviations were 0.86 K and 0.0151 for the boiling point and vapour-phase composition, respectively. Therefore, it was shown that the activity-coefficient models used satisfactorily correlate the (vapour + liquid) equilibrium results of the mixture studied. However, the performance of the UNIQUAC model was superior to all other models mentioned. 相似文献