Optical, X-ray absorption and photoelectron spectroscopy investigation of the Co site configuration in Zn1−xCoxO films prepared by pulsed laser deposition

In this paper, we investigate the Co site configuration in Zn_1−xCo_xO thin films by means of different spectroscopic techniques. Thin films were prepared by pulsed laser deposition with Co proportion from 1% to 30%. The Co 2p doublet observed in the X-ray photoelectron spectra exhibits the spin–orbit splitting and shake-up satellites typical of Co⁺² ionization states. X-ray absorption spectra at the Co K-edge, taken in fluorescence mode, unambiguously show that Co atoms are in tetrahedral configuration substituting for Zn over the whole composition range. Optical absorption spectra provide further evidence of the tetrahedral coordination of Co cations, both through the internal transitions in the Co 3d shell and through the shift to higher energies of the band-to-band absorption edge with the increase of the Co proportion.     

Pd(0) supported onto monolithic polymers containing IL-like moieties. Continuous flow catalysis for the Heck reaction in near-critical EtOH

Long-term stable Pd(0) catalysts can be easily supported onto polymeric monoliths containing methyl-imidazole moieties and the corresponding reactors based on these materials can be applied for the continuous Heck reaction in near-critical EtOH.     

X‐ray excited optical luminescence from crystalline silicon

Synchrotron based X‐ray excited optical luminescence (XEOL) has been measured with many direct bandgap semiconductors. We present XEOL measurements on crystalline silicon (Si), obtained despite of its indirect bandgap and the consequently low luminescence efficiency. Spectra of monocrystalline and multicrystalline (mc) Si at room temperature are compared to theoretical spectra. A possible application in the synchrotron‐based research on mc‐Si is exemplified by combining XEOL, X‐ray fluorescence (XRF) spectroscopy, photoluminescence (PL) spectroscopy, and microscope images of grain boundaries. This approach can be utilized to investigate the recombination activity of metal precipitates, to analyze areas of different lifetimes on mc‐Si samples and to correlate additional material parameters to XRF measurements. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Thermal radiative properties of carbon materials under high temperature and vacuum ultra-violet (VUV) radiation for the heat shield of the Solar Probe Plus mission

The Solar Probe Plus (SP+) mission will approach the Sun as close as 9.5 solar radii in order to understand the origin of the solar corona heating and the acceleration of the solar wind. Submitted to such extreme environmental conditions, a thermal protection system is considered to protect the payload of the SP+ spacecraft. Carbon-based materials are good candidate to fulfill this role and critical point remains the equilibrium temperature reached at perihelion by the heat shield. In this paper, experimental results obtained for the solar absorptivity α, the total hemispherical emissivity ? and its ratio α/?, conditioning the equilibrium temperature of the thermal protection system, are presented for different kinds of carbon materials heated at high temperatures with or without vacuum-UV (100 < λ < 200 nm) radiation. The synergistic effect of ion bombardment is also presented for one kind of material.     

Emissivity measurements on carbon-carbon composites at high temperature under high vacuum

Carbon-carbon composites are candidate materials for the conception of the thermal shield of the “Solar Probe” space mission. To understand their behavior under solar aggressions and know the possible interactions with the shipped-in instruments, these materials were tested in a facility that allows to partially simulate the solar environment and to carry out in situ measurements. In this paper, we present the experimental results obtained for the α/? ratio, i.e. the ratio of the solar absorptivity α to the total hemisherical emissivity ? that controls the thermal equilibrium of the thermal shield. The objective is to find the lower ratio α/? in order to have the lowest temperature on the shield at 4 solar radii.     

An algorithm for network dimensioning under reliability considerations

In this paper we introduce a new methodology to adjust link capacities in circuit switched networks taking into account the costing policy and reliability considerations. This methodology, which is an extension of previous work on reliability evaluation using routing models, is based on a cyclic decomposition algorithm which alternates between a routing subproblem and a link capacity adjustment subproblem. The proposed procedure, which is shown to converge to a global optimum for the dimensioning/routing problem, has been tested on a 14 undirected arc problem for various levels of link failure probability. The numerical results are extremely satisfactory and they demonstrate the usefulness of the proposed method for proper network dimensioning.     

Total cross sections,elastic scattering observables and direct reconstruction of scattering matrix in np Interactions between 0.8 and 1.1 GeV at SATURNE II

Neutron-proton total cross section differences with the beam and target polarizations orientated either transversally or longitudinally with respect to the beam direction, as well as 11 spin dependent elastic scattering observables measured at SATURNE II as a function of energy and angle are presented. A major part of results was measured using the quasimonoenergetic polarized neutron beam and/or the polarized proton target. A small part of data was obtained using a polarized deuteron beam considered as a beam of quasifree neutrons and protons. The present paper represents a review of measured observables. Several sets of present data are compared with results obtained in other laboratories below 0.8 GeV. Imaginary parts of spin dependent forward amplitudes for np scattering and for the isospin stateI=0 were determined. First direct reconstruction of the np scattering matrix at 0.84 GeV is shown.We acknowledge support for this work from J. Arvieux, R. Beurtey, P. Borgeaud, P. A. Chamouard, A. Fleury, E. Heer, J. M. Laget, L. Musílek, L. Price, N. A. Russakovich, J. Saudinos, and J. Tolar. Discussions with J. Franz, J. M. Lagniel, C. Lechanoine-Leluc, G. Milleret, I. Strakovsky, and Y. Terrien have solved several problems. The exploitation of the polarized target owes a lot to G. Guillier, Ph. Marlet and J. Mommejat. We thank T. Lambert, E. Perrin, J. Poupard and J. P. Richeux for their efficient help in preparation of the experiment and the SATURNE II crew for unusual accelerator operations. Finally, we express our gratitude to Françoise Haroutel, who efficiently helped overcome all administrative requirements concerning a large international colaboration. This work was partly supported by the Swiss National Science Foundation and by the US Department of Energy Contract No. W-31-109-ENG-38.     

Molecular Dynamics Simulation of Aqueous Solutions Using Interaction Energy Components: Application to the Solvation Gibbs Energy

Molecular dynamics simulations of aqueous solutions of the solutes acetamide (AcNH₂), acetic acid (AcOH), and acetaldehyde (AcH) were made using Lennard–Jones 12-6-1 potentials to describe the solute–solvent interactions. The Morokuma decomposition scheme and the ESIE solute atomic charges were used to reproduce the exchange, polarization, and electrostatic components of the solute–water interaction energy. A nonlinear perturbation was incorporated into the “slow-growth” technique in order to improve the results for the solvation Gibbs energy that were found to be in agreement with the available experimental and theoretical values.