排序方式: 共有22条查询结果,搜索用时 31 毫秒
1.
A. M. Safiulina O. A. Sinegribova A. G. Matveeva E. I. Goryunov M. S. Grigoriev E. E. Nifant’ev I. G. Tananaev 《Russian Journal of Inorganic Chemistry》2012,57(1):108-114
The extraction capacities and selectivities of 1,8-naphthyridine-based neutral organophosphorus reagents in extracting trivalent
lanthanides (Ln, Nd, Ho, Yb) from carbonate solutions were studied. The length and nature of the linker between the naphthyridine
and phosphoryl moieties were found to have considerable influence on the efficiency and selectivity of lanthanide extraction. 相似文献
2.
Complexation of uranium(VI) and europium(III) with new polydentate pincer ligands in aqueous systems
N. E. Borisova A. M. Safiulina V. A. Knizhnikov M. D. Reshetova A. V. Lizunov 《Russian Journal of Inorganic Chemistry》2017,62(2):244-248
Coordination of uranyl ion with new polydentate ligands derived from amino acids and extraction of uranium(VI) and europium(III) from aqueous salt solution into poly(ethylene glycol) phase with the use of new polydentate pincer ligands has been studied. 相似文献
3.
A. G. Matveeva A. M. Thu A. M. Safiulina G. V. Bodrin E. I. Goryunov I. B. Goryunova O. A. Sinegribova E. E. Nifant’ev 《Russian Chemical Bulletin》2013,62(6):1309-1316
The extraction ability and selectivity of a series of phosphoryl ketones Ph2P(O)CH2C(O)Me, and Ph2P(O)CRR’CH2C(O)Me (R = H, Me; R’ = H, Me, n-C5H11, Ph, 2-thienyl, 2-furyl) towards trivalent lanthanides (LaIII, NdIII, HoIII, YbIII) and actinides (UVI, ThIV) were studied. The efficiency and selectivity of the new ligands in the extraction of f-elements from nitric acid solutions into chloroform were compared to those of model phosphine oxide Ph2P(O)Bu and known extractants: tributyl phosphate (BuO)3P(O), trioctylphosphine oxide (C8H17)3P(O), and carbamoylmethyl phosphine oxide Ph2P(O)CH2C(O)NBu2. 相似文献
4.
E. I. Goryunov A. G. Matveeva A. M. Safiulina I. B. Goryunova G. V. Bodrin V. K. Brel 《Russian Journal of General Chemistry》2016,86(3):629-638
A simple and effective general method of synthesis of α- and β-diphenylphosphorylated secondary alkanols by the reduction of the corresponding phosphorylalkanones with NaBH4 was developed. The extraction properties of the resulting phosphorylalkanols Ph2P(O)(CR2)nCH2CH(OH)Me (n = 0, 1; R = H, Me) were studied in the recovery of f-elements (LaIII, NdIII, HoIII, YbIII, UVI, ThIV) from nitric acid solutions into chloroform and compared with those of both related phosphorylketones and known extractants (n-BuO)3PO, (n-C8H17)3PO, and Ph2P(O)CH2C(O)N(n-Bu)2. 相似文献
5.
A. M. Safiulina A. G. Matveeva T. K. Dvoryanchikova O. A. Sinegribova A. M. Tu D. A. Tatarinov A. A. Kostin V. F. Mironov I. G. Tananaev 《Russian Chemical Bulletin》2012,61(2):392-398
Extraction capability and selectivity of acetyl-containing phosphine oxides R2P(O)CMe2CH2C(O)Me (R = Pr, Bu, n-C5H11, n-C6H13, n-C8H17, Ph) toward actinides (UVI, ThIV) and trivalent lanthanides (LaIII, NdIII, HoIII, YbIII) were studied. The new ligands were shown to be more efficient and selective in the extraction of uranium, thorium, and heavy lanthanides from nitric acid solutions into chloroform as compared to the known extractants such as carbamoylphosphine oxide Ph2P(O)CH2C(O)NBu2, trioctylphosphine oxide (n-C8H17)3P(O), and tributyl phosphate (n-BuO)3P(O). 相似文献
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E. I. Matrosov I. B. Goryunova K. A. Lysenko M. S. Grigor’ev A. M. Safiulina E. I. Goryunov E. E. Nifant’ev 《Russian Journal of Inorganic Chemistry》2011,56(4):539-544
A new phosphoryl-containing ligand based on 4-aminoantipyrine-N-(1,5-dimethyl-3-oxo-2-phenyl-1,2-dihydropyrazol-4-yl)-P,P-diphenylamidophosphinate (L) was synthesized. In crystals, the L molecules were found to be combined in centrosymmetric dimers
through N-H…O=C hydrogen bonds. The complexes of L with neodymium(III), erbium(III), thorium(IV), and uranyl nitrates were
obtained, and their structures were determined. The bands of the C=O and P=O groups in the IR spectra of these complexes are
shifted toward low frequencies (by 50–65 and 40–70 cm−1, respectively), which is indicative of a bidentate coordination of the organophosphorus ligand. According to the X-ray crystallography
data, uranyl is bidentately coordinated by both the L molecule (through the C=O and P=O groups) and two nitrate anions. 相似文献
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10.
A. G. Matveeva M. S. Grigoriev T. K. Dvoryanchikova S. V. Matveev A. M. Safiulina O. A. Sinegribova M. P. Passechnik I. A. Godovikov D. A. Tatarinov V. F. Mironov I. G. Tananaev 《Russian Chemical Bulletin》2012,61(2):399-404
The reactions of (2-methyl-4-oxopent-2-yl)diphenylphosphine oxide (L) with uranyl and neodymium nitrates afforded complexes with compositions M: L = 1: 2 and 1: 3. These complexes were characterized by X-ray diffraction, IR spectroscopy, and elemental analysis. In the solid complexes, phosphine oxide L has a variable denticity. Studies by 1H and 31P NMR and IR spectroscopy showed that in chloroform, the mononuclear complexes [UO2(O-L)2-(O,O-NO3)2], [Nd(O-L)2(O,O-NO3)3] and [Nd(O-L)3(O,O-NO3)3] are neutral, and the ligand molecules are coordinated to the metal cation through the phosphoryl oxygen atom. 相似文献