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1.
Tae Seok Kwon Sadanori Kumazawa Shuji Kondo† Koji Takagi Hideo Kunisada Yasuo Yuki 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(12):1895-1913
Abstract 1,4-Bis(p-tert-butylphenylselenomethyl) benzene was synthesized, and used as a bifunctional photoiniferter for the polymerization of styrene. Both the polymer yields and the number average of molecular weights (n) of polymers increased with the polymerization. The polymerization of styrene by this iniferter permitted telechelic polystyrene containing arylseleno groups at both chain ends, and the degree of functionality was 1.9. The seleno groups of both chain ends of polystyrene were reduced quantitatively by tri-n-butyltin hydride. These seleno groups in polystyrene were also eliminated by treatment with hydrogen peroxide to give telechelic polystyrene with carbon-carbon double bond at both chain ends. Further, polystyrene with double bonds was converted to telechelic polystyrene carrying terminal functional groups as epoxy, hydroxy, and iodide group, respectively. 相似文献
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Sadanori Konishi 《Annals of the Institute of Statistical Mathematics》1985,37(1):87-94
Summary A concept of normalizing transformations of statistics is constructed on the basis of the rate of convergence to normality.
The concept is applied to derive a normalizing transformation of a maximum likelihood estimate of intraclass correlation coefficient
in ap-variate normal sample. Numerical comparisons are made to examine whether the proposed transformation is efficient to achieve
normality. The relationship between normalization and variance stabilization is also considered.
The Institute of Statistical Mathematics 相似文献
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Sadanori Konishi 《Journal of multivariate analysis》1979,9(2):259-266
This paper deals with asymptotic expansions for the non-null distributions of certain test statistics concerning a correlation matrix in a multivariate normal distribution. For this purpose an asymptotic expansion is given for the distribution of a function of the sample correlation matrix. As special cases of the resulting expansion, asymptotic expansions for the distributions of the sample correlation coefficient, Fisher's z-transformation and arcsine transformation are also given. 相似文献
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Simultaneous Induction of Axial and Planar Chirality in Arene–Chromium Complexes by Molybdenum‐Catalyzed Enantioselective Ring‐Closing Metathesis
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Prof.Dr. Ken Kamikawa Dr. Sachie Arae Dr. Wei‐Yi Wu Chihiro Nakamura Prof.Dr. Tamotsu Takahashi Prof.Dr. Masamichi Ogasawara 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(13):4954-4957
The molybdenum‐catalyzed asymmetric ring‐closing metathesis of the various Cs‐symmetric (π‐arene)chromium substrates provides the corresponding bridged planar‐chiral (π‐arene)chromium complexes in excellent yields with up to >99 % ee. With a bulky and unsymmetrical substituent, such as N‐indolyl or 1‐naphthyl, at the 2‐positions of the η6‐1,3‐diisopropenylbenzene ligands, both biaryl‐based axial chirality and π‐arene‐based planar chirality are simultaneously induced in the products. The axial chirality is retained even after the removal of the dicarbonylchromium fragment, and the chiral biaryl/heterobiaryl compounds are obtained with complete retention of the enantiopurity. 相似文献
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The elastic properties of alkali germanate glasses, xR2O?(100 ? x)GeO2 (R = Li, Na, K, Rb, Cs ; x = 14, 28), have been studied by Brillouin scattering in the wide temperature range up to 1200 °C. The remarkable aging effect of Brillouin shift ΔνL has been observed below a glass transition temperature Tg ≈ 500 °C. The temperature dependence of longitudinal sound velocity VL of well annealed glasses shows the gradual decrease below Tg, while on further heating the remarkable decrease is observed above Tg. The scaled temperature dependence of VL is nearly independent on alkali metals below the melting temperature Tm. While on further heating above Tm, the drastic decrease of VL and increase of αL show the remarkable alkali dependence. It may be attributed to the appearance of dynamic process related to ionic hopping of alkali metals released from glass network above Tm. 相似文献
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Sadanori Sekiya Kenichi Taniguchi Koichi Tanaka 《Rapid communications in mass spectrometry : RCM》2012,26(6):693-700
3‐Aminoquinoline/α‐cyano‐4‐hydroxycinnamic acid (3AQ/CHCA) is a liquid matrix (LM), which was reported by Kumar et al. in 1996 for matrix‐assisted laser desorption/ionization (MALDI) mass spectrometry. It is a viscous liquid and has some advantages of durability of ion generation by a self‐healing surface and quantitative performance. In this study, we found a novel aspect of 3AQ/CHCA as a MALDI matrix, which converges hydrophilic material into the center of the droplet of analyte‐3AQ/CHCA mixture on a MALDI sample target well during the process of evaporation of water derived from analyte solvent. This feature made it possible to separate not only the buffer components, but also the peptides and oligosaccharides from one another within 3AQ/CHCA. The MALDI imaging analyses of the analyte‐3AQ/CHCA droplet indicated that the oligosaccharides and the peptides were distributed in the center and in the whole area around the center of 3AQ/CHCA, respectively. This 'on‐target separation' effect was also applicable to glycoprotein digests such as ribonuclease B. These features of 3AQ/CHCA liquid matrix eliminate the requirement for pretreatment, and reduce sample handling losses thus resulting in the improvement of throughput and sensitivity. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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This paper is concerned with an algorithm for solving a large scale semi-definite logit model which cannot be solved by an outer approximation (cutting plane) algorithm proposed earlier by one of the authors. Outer approximation algorithm can solve a problem with up to 10 financial attributes and 7,800 companies which is less than satisfactory from the viewpoint of failure discriminant analysis. The new algorithm can generate an approximately optimal solution for problems with over 14 attributes and 8,000 companies, by which the quality of failure discriminant analysis would be substantially improved. 相似文献
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Mitsuo Takayama Sadanori Sekiya Ryunosuke Iimuro Shinichi Iwamoto Koichi Tanaka 《Journal of the American Society for Mass Spectrometry》2014,25(1):120-131
Selective and nonselective cleavages in ion trap low-energy collision-induced dissociation (CID) experiments of the fragments generated from in-source decay (ISD) with matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS) of intact proteins are described in both positive and negative ion modes. The MALDI-ISD spectra of the proteins demonstrate common, discontinuous, abundant c- and z′-ions originating from cleavage at the N–Cα bond of Xxx-Asp/Asn and Gly-Xxx residues in both positive- and negative-ion modes. The positive ion CID of the c- and z′-ions resulted in product ions originating from selective cleavage at Asp-Xxx, Glu-Xxx and Cys-Xxx residues. Nonselective cleavage product ions rationalized by the mechanism of a “mobile proton” are also observed in positive ion CID spectra. Negative ion CID of the ISD fragments results in complex product ions accompanied by the loss of neutrals from b-, c-, and y-ions. The most characteristic feature of negative ion CID is selective cleavage of the peptide bonds of acidic residues, Xxx-Asp/Glu/Cys. A definite influence of α-helix on the CID product ions was not obtained. However, the results from positive ion and negative ion CID of the MALDI-ISD fragments that may have long α-helical domains suggest that acidic residues in helix-free regions tend to degrade more than those in helical regions. Figure
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