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1.
Hans‐Ruedi Mürner Rosario Scopelliti Jean‐Claude G. Bünzli 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(8):m434-m435
In the title compound, [TbCl(C27H35N3)2(H2O)](ClO4)2·2C2H6O, the TbIII ion has a coordination number of eight, composed of two tridentate substituted‐terpyridine ligands, a water molecule and a bound Cl? anion. The first coordination shell can be described as a distorted bicapped trigonal prism. The dihedral angles between pyridine rings belonging to the same tpy ligand range from 5.2 (5) to 16.8 (5)°. 相似文献
2.
Ruedi Eggli 《Analytica chimica acta》1977,91(2):129-138
Primary coulometric versions of d.c. anodic stripping voltammetry, performed in a microcell at a mercury-plated rotating glassy carbon electrode, are applied to the determination of cadmium and lead. With exhaustive preelectrolysis of the sample solution, 5–100 ng of the metal can be determined from the charge contained in the stripping signal; precision and accuracy are in the 5% range. An extrapolation procedure that requires only partial metal deposition is evaluated. 相似文献
3.
Ott T Kern A Schuffenhauer A Popov M Acklin P Jacoby E Stoop R 《Journal of chemical information and computer sciences》2004,44(4):1358-1364
For the clustering of chemical structures that are described by the Similog, ISIS count, and ISIS binary fingerprints, we propose a sequential superparamagnetic clustering approach. To appropriately handle nonbinary feature keys, we introduce an extension of the binary Tanimoto similarity measure. In our applications, data sets composed of structures from seven chemically distinct compound classes are evaluated and correctly clustered. The comparison, with results from leading methods, indicates the superiority of our sequential superparamagnetic clustering approach. 相似文献
4.
V. König W. Grüebler R.A. Hardekopf B. Jenny R. Risler H.R. Bürgi 《Physics letters. [Part B]》1978,72(4):436-438
High-precision measurements of the vector and the three tensor analyzing powers of the mirror reactions 2H(d, p)3H and 2H(d, p)3He are compared between 2.5 and 11.5 MeV incident deuteron energy. Large and complex differences are observed over the whole energy range. Although at the present time proper Coulomb corrections cannot be made, possible charge symmetry violation has to be considered. 相似文献
5.
Yorick Hardy Willi-Hans Steeb Ruedi Stoop 《International Journal of Theoretical Physics》2003,42(12):2847-2853
Entangled quantum states are an important component of quantum computing techniques such as quantum error-correction, dense coding, and quantum teleportation. We describe how to generate fully entangled states in the Hilbert space C
N
C
N
starting from a unitary matrix and show that they form an orthonormal basis in this space. 相似文献
6.
Jean-Jacques Risler 《Inventiones Mathematicae》1987,89(1):119-137
Sans résumé 相似文献
7.
Scaling functions of the support and of the measure have been used to characterize the scaling behavior of a dynamical system. While scaling functions for the scaling of the measure, ƒ(), have been calculated for a number of experimental systems, examples of scaling functions φ(λ) for the scaling of the support are difficult to obtain. In this contribution, we report on a phase-transition-like effect of an experimental p-doped germanium semiconductor sample. It is found that the results obtained from the dynamical scaling function agree with those obtained by Horita et al. from model maps, indicating that scaling functions for the scaling of the support are a powerful method of characterizing experimental dynamical systems. 相似文献
8.
9.
Ruedi Gygax Jakob Wirz Joseph T. Sprague Norman L. Allinger 《Helvetica chimica acta》1977,60(8):2522-2529
The isodynamical interconversion between the quasiplanar equilibrium conformers 1b and 1c of 1,5-bisdehydro[12]annulene requires a free energy of activation ΔG# = 4.5 ± 0.2 kcal/mol (120 K) which was determined by line shape analysis of its temperature-dependent NMR. spectrum. Force field calculations indicate that this barrier reflects the energy needed to disrupt the cyclic π-conjugation in going to the nonplanar transition state 1a . 相似文献
10.