Fission probabilities of Cu,Nb, Ag,Ho, Au and Bi nuclei excited by stopped antiprotons

The A dependence of nuclear fission induced by stopped antiprotons has been measured. An unambiguous identification of the binary fission decay mode was provided by a coordinate measurement of complementary fission fragments in coincidence using a large-acceptance fission detector based on low pressure multiwire proportional chambers. A deep fissility minimum was observed nearA=100, in agreement with the general behaviour predicted by the liquid-drop model. An unexpectedly low and high fission probability was found for the Ag and Cu nuclei, respectively.     

One-pot RAFT/"click" chemistry via isocyanates: efficient synthesis of α-end-functionalized polymers

A new methodology has been developed for preparing α-functional polymers in a one-pot simultaneous polymerization/isocyanate "click" reaction. Our original synthetic strategy is based on the preparation of a carbonyl-azide chain transfer agent (CTA) precursor that undergoes the Curtius rearrangement in situ during reversible addition-fragmentation chain transfer (RAFT) polymerization yielding well-controlled α-isocyanate modified polymers. This strategy overcomes numerous difficulties associated with the synthesis of a polymerization mediator bearing an isocyanate at the R group and with the handling of such a reactive functionality. This new carbonyl-azide CTA can control the polymerization of a wide range of monomers, including (meth)acrylates, acrylamides, and styrenes (M(n) = 2-30 kDa; ? = 1.16-1.38). We also show that this carbonyl-azide CTA can be used as a universal platform for the synthesis of α-end-functionalized polymers in a one-pot RAFT polymerization/isocyanate "click" procedure.     

Calculation of multiple-excitation cross sections using angle-dependent phase shifts

Multiple-excitation cross sections for the scattering of 70.4 MeV ¹²C ions on the even neodymium isotopes are calculated by the method of angle-dependent phase shifts. The results are compared with the data.     

The heavy-ion reaction channels of the system 16O + 16O

The reaction channels of the system ¹⁶O + ¹⁶O with outgoing heavy particles from lithium to magnesium have been measured using a ΔE-E telescope. Excitation functions from 49 to 65 MeV at θ_Lab = 30° and angular distributions from θ_Lab = 10° (20°) to 50° at E_Lab = 51.5 MeV are presented for the strong transitions. The excitation function of the ¹²C-²⁰Ne (4.25 MeV) channel shows a pronounced regular cross structure with peaks at 52 and 60 MeV. A selective excitation of certain states in the inelastic scattering and the ¹²C-²⁰Ne channel is observed; the yields of the other heavy-ion channels being weaker by at least one order of magnitude. An explanation of this phenomenon is given by considering the angular momentum matching between entrance and exit channels. Furthermore it is shown that no strong dependence of the cross sections on the transferred angular momentum or on the nuclear structure of the final states is observed. Possible implications of these results on the reaction mechanism are discussed.     

On the interpretation of heavy-ion sub-barrier fusion data

We study the well-known deviation of measured fusion cross-sections below the barrier from predictions of one-dimensional tunnelling models. A simple parametrisation of measured excitation functions is discussed which allows to identify a smooth general trend depending only on gross nuclear properties. The parametrisation is substantiated by quantum mechanically exact calculations in a two-dimensional tunnelling model. Various possibilities for the geometrical interpretation of the second degree of freedom are discussed. Neck formation is identified as the most probable degree of freedom effecting the overall behavior of sub-barrier fusion.     

Statistical significance of phase-shift analyses for heavy-ion elastic-scattering data

Zeitschrift für Physik A Hadrons and nuclei - It is shown that the phase-shift analysis of elastic-scattering data leads to a set of illposed, non-linear, stochastic equations. An algorithm is...     

Staged Surface Patterning and Self‐Assembly of Nanoparticles Functionalized with End‐Grafted Block Copolymer Ligands

Using two orthogonal external stimuli, programmable staged surface patterning and self‐assembly of inorganic nanoparticles (NPs) was achieved. For gold NPs capped with end‐grafted poly(styrene‐block‐(4‐vinylbenzoic acid)), P(St‐block‐4VBA), block copolymer ligands, surface‐pinned micelles (patches) formed from NP‐adjacent PSt blocks under reduced solvency conditions (Stimulus 1); solvated NP‐remote P(4VBA) blocks stabilized the NPs against aggregation. Subsequent self‐assembly of patchy NPs was triggered by crosslinking the P(4VBA) blocks with copper(II) ions (Stimulus 2). Block copolymer ligand design has a strong effect on NP self‐assembly. Small, well‐defined clusters assembled from NPs functionalized with ligands with a short P(4VBA) block, while NPs tethered with ligands with a long P(4VBA) block formed large irregularly shaped assemblies. This approach is promising for high‐yield fabrication of colloidal molecules and their assemblies with structural and functional complexity.