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1.
Emily S. Tepe Ellen S. Deutsch MD Quiana Sampson Stephen Lawless James S. Reilly Robert Thayer Sataloff 《Journal of voice》2002,16(2):244-250
The objective of this study was to determine the incidence of vocal problems in young choir singers and to correlate vocal problems with demographic and behavioral information. A questionnaire addressing vocal habits and hygiene was offered to 571 young choir singers, up to 25 years of age, who sing at least weekly; 129 (22.6%) responded. More than one-half of the respondents had experienced vocal difficulty, particularly older adolescents. Detrimental behaviors and circumstances surveyed were not reflective of the incidence of vocal difficulty, except for morning hoarseness, chronic fatigue, insomnia, and female gender after puberty. Voice care professionals should be aware that self-reported voice difficulties are common among young choral singers, especially postpubescent girls, and children with symptoms consistent with reflux (morning hoarseness) and emotional stress (insomnia). Laryngologists should communicate with choral conductors and singing teachers to enhance early identification and treatment of children with voice complaints, and to develop choral educational strategies that help decrease their incidence. 相似文献
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H.J. Rossell 《Journal of solid state chemistry》1979,27(3):287-292
The orthorhombic fluorite-related superstructure phase Y3TaO7 is non-stoichiometric; the Y2O3 content may be varied from 75.0 to about 72.5 mole% without incurring structural changes. For overall Y2O3 contents from 72.0 to 70.5 mole%, the crystal symmetry changes from C2221 to Cmmm, and the c axis becomes halved. The structure of the low-Y2O3 material has been determined from powder X-ray diffraction intensities supplemented by single crystal electron-optical data. The relationship of this structure to that of stoichiometric Y3TaO7 is discussed. 相似文献
4.
Mottram HR Woodbury SE Rossell JB Evershed RP 《Rapid communications in mass spectrometry : RCM》2003,17(7):706-712
Maize oil commands a premium price and is thus a target for adulteration with cheaper vegetable oils. Detection of this activity presents a particular challenge to the analyst because of the natural variability in the fatty acid composition of maize oils and because of their high sterol and tocopherol contents. This paper describes a method that allows detection of adulteration at concentrations of just 5% (m/m), based on the Mahalanobis distances of the principal component scores of the delta(13)C values of major and minor vegetable oil components. The method makes use of a database consisting of delta(13)C values and relative abundances of the major fatty acyl components of over 150 vegetable oils. The sterols and tocopherols of 16 maize oils and 6 potential adulterant oils were found to be depleted in (13)C by a constant amount relative to the bulk oil. Moreover, since maize oil contains particularly high levels of sterols and tocopherols, their delta(13)C values were not significantly altered when groundnut oil was added up to 20% (m/m) and it is possible to use the values for the minor components to predict the values that would be expected in a pure oil; therefore, comparison of the predicted values with those obtained experimentally allows adulteration to be detected. A refinement involved performing a discriminant analysis on the delta(13)C values of the bulk oil and the major fatty acids (16:0, 18:1 and 18:2) and using the Mahalanobis distances to determine the percentage of adulterant oil present. This approach may be refined further by including the delta(13)C values of the minor components in the discriminant analysis thereby increasing the sensitivity of the approach to concentrations at which adulteration would not be attractive economically. 相似文献
5.
Montserrat Ferrer Anna Juli Roser Reina Oriol Rossell Miquel Seco Dominique de Montauzon 《Journal of organometallic chemistry》1998,560(1-2)
Treatment of [(ClAu)2(diphosphine)] {diphosphine=bis(diphenylphosphino)methane (dppm), bis(diphenylphosphino)isopropane (dppip), 1,2-bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp)} with two equivalents of the anion [Fe2(μ-CO)(CO)6(μ-PPh2)]− in the presence of TlBF4 gives the new heterometallic diclusters [{Fe2(μ-CO)(CO)6(μ-PPh2)Au}2(diphosphine)] that have been isolated and characterized. Their 31P-NMR spectra show different patterns as a function of the diphosphine ligand. The electrochemical behavior of these compounds has been investigated and compared with that of the mono- [Fe2(μ-CO)(CO)6(μ-PPh2)(μ-AuPPh3)] and tricluster [{Fe2(μ-CO)(CO)6(μ-PPh2)Au}3(triphos)] derivatives. 相似文献
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Chloroacetaldehyde reacts with viral M13mp18 single and double stranded DNA to form the highly fluorescent adducts, etheno-AMP and etheno-CMP. Absorbance and fluorescence spectroscopy can be used to monitor and characterize these reactions. Both single and double stranded DNA showed increases in the absorbance following reaction with the aldehyde. The fluorescence also increased in these two groups and continued to rise with increasing time of incubation until a point of saturation was reached. The fluorescence of the double stranded moiety was considerably enhanced following reaction with the aldehyde while that of the single stranded population was not, making this method appropriate for the separation of small quantities of the two populations of DNA. 相似文献
8.
Reza MD. Sultanur Taniguchi Rihito Kaneko Jyunya Oura Yasuji 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(6):2609-2619
Journal of Radioanalytical and Nuclear Chemistry - Instrumental photon activation analysis (IPAA) is nondestructive and multi-elemental analysis method like instrumental neutron activation... 相似文献
9.
Dr. Rebecca Walker Dr. Magdalena Majewska Dr. Damian Pociecha Dr. Anna Makal Prof. John MD Storey Prof. Ewa Gorecka Prof. Corrie T. Imrie 《Chemphyschem》2021,22(5):461-470
A selection of pyrene-based liquid crystal dimers have been prepared, containing either methylene-ether or diether linked spacers of varying length and parity. All the diether linked materials, CBOnO.Py (n=5, 6, 11, 12), exhibit conventional nematic and smectic A phases, with the exception of CBO11O.Py which is exclusively nematic. The methylene-ether linked dimer, CBnO.Py, with an even-membered spacer (n=5) was solely nematogenic, but odd-members (n=6, 8, 10) exhibited both nematic and twist-bend nematic phases. Replacement of the cyanobiphenyl fragment by cyanoterphenyl giving CT6O.Py, gave elevated melting and nematic-isotropic transition temperatures, and SmA and SmCA phases were observed on cooling the nematic phase. Intermolecular face-to-face associations of the pyrene moieties drive glass formation, and all these materials have a glass transition temperature at or above room temperature. The stability of the glassy twist-bend nematic phase allowed for its study using AFM, and the helical pitch length, PTB, was measured as 6.3 and 6.7 nm for CB6O.Py and CB8O.Py, respectively. These values are comparable to the shortest pitch of a twist-bend nematic phase measured to date. 相似文献
10.
Kinetico‐Mechanistic Insights on the Assembling Dynamics of Allyl‐Cornered Metallacycles: The PtNpy Bond is the Keystone
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Dr. Inmaculada Angurell Dr. Montserrat Ferrer Dr. Albert Gutiérrez Prof. Manuel Martínez Dr. Mercè Rocamora Dr. Laura Rodríguez Prof. Oriol Rossell Dipl.‐Chem. Yvonne Lorenz Dr. Marianne Engeser 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(44):14473-14487
The square‐like homo‐ and heterometallamacrocycles [{Pd(η3‐2‐Me‐C3H4)( L n )2}2{M(dppp)}2](CF3SO3)6 (dppp=1,3‐bis(diphenylphosphino)propane) and [{Pd(η3‐2‐Me‐C3H4)( L1 )2}2{M(PPh3)2}2](CF3SO3)6 [py=pyridine, M=Pd, Pt, L n =4‐PPh2py ( L1 ), 4‐C6F4PPh2py ( L2 )] containing allyl corners were synthesised by antisymbiotic self‐assembly of the different palladium and platinum metallic corners and the ambidentate N,P ligands. All the synthesised assemblies displayed a complex dynamic behaviour in solution, the rate of which is found to be dependent on the electronic and/or steric nature of the different building blocks. A kinetico‐mechanistic study by NMR line shape analysis of the dynamics of some of these assemblies was undertaken in order to determine the corresponding thermal activation parameters. Both an enhanced thermodynamic stability and slower dynamics were observed for platinum‐pyridine‐containing species when compared with their palladium analogues. Time‐dependent NMR spectroscopy in combination with ESI mass spectrometry was used to study the exchange between the assemblies and their building blocks, as well as that occurring between different metallamacrocycles. Preliminary studies were carried out on the activity of some of the metallamacrocyclic compounds as catalytic precursors in the allylic substitution reaction, and the results compared with that of the monometallic allylic corner [Pd(η3‐2‐Me‐C3H4)( L1 )2]+. 相似文献