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Sabina Ronneteg Rolf Berger Gilles André 《Journal of magnetism and magnetic materials》2010,322(6):681-685
The magnetic layer structure of TlCo2Se2−xSx has been thoroughly re-investigated with neutron powder diffraction. The cobalt magnetic moments are ferromagnetically arranged within the layers, but the interlayer coupling differs profoundly with varying composition (x): the spins in TlCo2Se2 form a helix along the c-axis with a turning-angle of ∼119° at 1.4 K. This kind of helical structure prevails for 0≤x≤1.5 with a gradual decrease of the angle with increasing sulphur content, down to 34°, showing an almost linear relationship with the interlayer distance of Co-Co. For x≥1.75 the interlayer coupling changes to ferromagnetic. Unexpectedly, two helices were found to coexist at x=0.5 and x=1.0. The interaction between adjacent cobalt layers is there characterized by an incommensurate angle (106°, resp., 73°) together with a commensurate angle of 90°. The magnetic structures have been refined as two magnetic phases, each having a characteristic wave vector. A tentative model where the symmetry of the structure and the interlayer distance compete is considered for explaining the simultaneous occurrence of the two kinds of diffraction profile satellites. 相似文献
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Kamali Saeed Häggström Lennart Ronneteg Sabina Berger Rolf 《Hyperfine Interactions》2004,156(1-4):315-319
Hyperfine Interactions - The quasi two-dimensional antiferromagnetic compound TlCo2Se2 has been studied by 57Fe Mössbauer spectroscopy. Small single crystals have been made with 2% Fe doping.... 相似文献
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Sabina Ronneteg Marck-Willem Lumey Richard Dronskowski Rolf Berger 《Journal of magnetism and magnetic materials》2006
Various solid solutions TlCo2−xMexSe2 (Me=Fe, Ni and Cu) have been investigated by neutron powder diffraction, supplemented by magnetometry. The incommensurate spin-helix running along the c-axis in tetragonal TlCo2Se2 prevails for low concentrations of copper and iron but changes pitch. In the copper case, only cobalt carries a magnetic moment. On nickel substitution, however, collinear antiferromagnetic coupling between the ferromagnetic layers occurs. The magnetic moment distribution between the two transition metals in the solid solution TlCo2−xNixSe2 was tentatively probed with first principle calculations on fictive ordered TlCoNiSe2, modelled by two types of superstructures. Also the ternary mother compounds, Pauli paramagnetic TlNi2Se2 and antiferromagnetic TlCo2Se2, were investigated with the same LMTO method. 相似文献
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Sabina Ronneteg Marck-Willem Lumey Ulrik Gelius Solveig Felton 《Journal of solid state chemistry》2004,177(9):2977-2984
An extensive investigation of the ferromagnetic compound TlCo2S2 has resulted in new information on the electronic and magnetic structure. Electronic structure calculations showed that magnetic ordering is energetically favorable with a clear driving force for ferromagnetic coupling within the cobalt layers. TlCo2S2 is metallic and the conductivity is due to holes in the valence band. XPS single crystal measurements did not show evidence of mixed oxidation states of cobalt. Neutron powder diffraction resulted in a ferromagnetic structure with the magnetic moment in the ab-plane. The derived magnetic moment of the cobalt atom is at 10 K and is in very good agreement with the value, at 10 K, inferred from the magnetic hysteresis curve. 相似文献
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