Feasibility Exploration of Laser‐based Techniques for Characterization of a Flashing Jet

Two‐phase flows hold an interest in many areas of science and engineering. In the safety field, one such topic is the accidental release of flammable and toxic pressure‐liquefied gases. In case of such a release, a flashing vapor explosion takes place resulting in a very dense two‐phase cloud. If the released substance is flammable, this cloud can be combustible and can lead to deflagration or detonation. For understanding the source processes of flashing and risk assessment, data related to cloud characteristics (i.e. droplet size, velocity etc.) is needed especially in the near region of the release. Due to the non‐equilibrium nature of the near field regions accurate data measurement is not possible with intrusive techniques. Therefore, laser‐based optical techniques (like Particle Image Velocimetry (PIV), Particle Tracking Velocimetry and Sizing (PTVS), Phase Doppler Anemometry (PDA) etc.) present the only possibility to obtain information for particle diameter and velocity evolution in this harsh environment.     

Extended glare point velocimetry and sizing for bubbly flows

A novel measuring technique for bubbly flows, named glare point velocimetry and sizing (GPVS), was developed in order to measure both bubble size and velocity with high accuracy in a 2D plane. This is accomplished by observing glare points in-focus under an observation angle of 96°. When a second laser-sheet is added, even higher accuracies are obtained and the relative refractive index of the bubble can be measured. It also allows non-spherical bubbles to be rejected and arbitrary angles to be used (e.g. 90°). The accuracy of the size and refractive index measurements was found to be within 1.3%.     

Contribution of individual flavonoids in Lysimachia species to the antioxidant capacity based on HPLC-DPPH assay

Quantitative phytochemical characterisation of the chief flavonoid aglycones in the hydrolysed Lysimachia extracts revealed the dominance of kaempferol, quercetin and myricetin in L. vulgaris, L. nummularia, L. punctata, L. christinae, L. ciliata and L. clethroides, respectively. Due to the significant radical scavenging capacity of the samples, the contribution of the individual aglycones to the total antioxidant activity became of interest. Therefore, a HPLC method coupled to pre-column DPPH scavenging assay was developed. Differences in the six Lysimachia species’ phenolic composition regarding their participation to the antioxidant activity were revealed. The participation of the three investigated flavonoids to the radical quenching activity was the highest (91.2%) in the L. vulgaris sample, the lowest in L. christinae sample with 29.6%. In L. vulgaris sample, the 76.3% contribution of quercetin to the scavenger capacity was the highest peak area decrement ratio among the investigated samples.     

Copper and iron interactions with angiotensin-converting enzyme inhibitors. A study by fast-atom bombardment tandem mass spectrometry

Fast atom bombardment, combined with high-energy collision-induced tandem mass spectrometry, has been used to investigate gas-phase metal-ion interactions with captopril, enalaprilat and lisinopril, all angiotensin-converting enzyme inhibitors.Suggestions for the location of metal-binding sites are presented. For captopril, metal binding occurs most likely at both the sulphur and the nitrogen atom. For enalaprilat and lisinopril, binding preferably occurs at the amine nitrogen. Copyright 1999 John Wiley & Sons, Ltd.     

ESI‐MS/MS of expanded porphyrins: a look into their structure and aromaticity

Electrospray mass spectrometry/mass spectrometry was used to investigate the gas‐phase properties of protonated expanded porphyrins, in order to correlate those with their structure and conformation. We have selected five expanded meso‐pentafluorophenyl porphyrins, respectively, a pair of oxidized/reduced fused pentaphyrins (22 and 24 π electrons), a pair of oxidized/reduced regular hexaphyrins (26 and 28 π electrons) and a regular doubly N‐fused hexaphyrin (28 π electrons). The gas‐phase behavior of the protonated species of oxidized and reduced expanded porphyrins is different. The oxidized species (aromatic Hückel systems) fragment more extensively, mainly by the loss of two HF molecules. The reduced species (Möbius aromatic or Möbius‐like aromatic systems) fragment less than their oxidized counterparts because of their increased flexibility. The protonated regular doubly fused hexaphyrin (non‐aromatic Hückel system) shows the least fragmentation even at higher collision energies. In general, cyclization through losses of HF molecules decreases from the aromatic Hückel systems to Möbius aromatic or Möbius‐like aromatic systems to non‐aromatic Hückel systems and is related to an increase in conformational distortion. Copyright © 2016 John Wiley & Sons, Ltd.     

On improvement of PIV image interrogation near stationary interfaces

In this paper the problem posed by interfaces when present in PIV measurements is addressed. Different image pre-processing, processing and post-processing methodologies with the intention to minimize the interface effects are discussed and assessed using Monte Carlo simulations. Image treatment prior to the correlation process is shown to be incapable of fully removing the effects of the intensity pedestal across the object edge. The inherent assumption of periodicity in the signal causes the FFT-based correlation technique to perform the worst when the correlation window contains a signal truncation. Instead, an extended version of the masking technique introduced by Ronneberger et al. (Proceedings of the 9th international symposium on applications of laser techniques to fluid mechanics, Lisbon, 1998) is able to minimize the interface-correlation, resolving only the particle displacement peak. Once the displacement vector is obtained, the geometric center of the interrogation area is not the correct placement. Instead, the centre of mass position allows an unbiased representation of the wall flow (Usera et al. in Proceedings of the 12th international symposium on applications of laser techniques to fluid mechanics, Lisbon, 2004). The aforementioned concepts have been implemented in an adaptive interrogation methodology (Theunissen et al. in Meas Sci Technol 18:275–287, 2007) where additionally non-isotropic resolution and re-orientation of the correlation windows is applied near the interface, maximizing the wall-normal spatial resolution. The increase in resolution and robustness are demonstrated by application to a set of experimental images of a flat-plate, subsonic, turbulent boundary layer and a hypersonic flow over a double compression ramp.     

Rainbow Interferometry with Wire Diffraction for Simultaneous Measurement of Droplet Temperature,Size and Velocity

A rainbow measurement technique is presented which measures simultaneously the size, temperature and velocity of individual droplets in a spray. The technique is based on rainbow interferometry in combination with diffraction by a wire placed in the spatial filter of the scattered-light detector. A photomultiplier detects the wire diffraction pattern superimposed on the rainbow interference pattern created by a droplet scattering laser light. The velocity is determined from the equivalent geometric wire shadow. The necessary sphericity validation is performed by comparing the Airy and the ripple droplet diameters, resulting from the respective interference structures. The temperature is recovered from the position of the wire diffraction pattern relative to the main rainbow maximum. The technique was applied to a water spray at ambient temperature. The results showed the importance of nonsphericity detection.     

Investigating the vortex melting phenomenon in BSCCO crystals using magneto-optical imaging technique

Using a novel differential magneto-optical imaging technique we investigate the phenomenon of vortex lattice melting in crystals of Bi₂Sr₂CaCu₂O₈ (BSCCO). The images of melting reveal complex patterns in the formation and evolution of the vortex solid-liquid interface with varying field (H)/temperature (T). We believe that the complex melting patterns are due to a random distribution of material disorder/inhomogeneities across the sample, which create fluctuations in the local melting temperature or field value. To study the fluctuations in the local melting temperature/field, we have constructed maps of the melting landscape T _m(H, r), viz., the melting temperature (T _m) at a given location (r) in the sample at a given field (H). A study of these melting landscapes reveals an unexpected feature: the melting landscape is not fixed, but changes rather dramatically with varying field and temperature along the melting line. It is concluded that the changes in both the scale and shape of the landscape result from the competing contributions of different types of quenched disorder which have opposite effects on the local melting transition.