自由曲面光学虚拟制造与检测系统的探讨

自由曲面光学产品设计、制造与检测的工艺流程，通常采取试凑法逐次逼近。由于加工 检测 再加工，循环往复，既费时，成本又高，产生了瓶颈问题。为了解决此弊端，本文运用虚拟制造技术，提出光学虚拟制造的基本构想，即虚拟制造系统结构模型，给出光学系统虚拟原型的构成和光学系统成像质量虚拟检测系统的构成，讨论光学成像质量的仿真检测以及敏度分析方法。研究结果表明：运用虚拟制造与检测技术，可缩短研发周期，降低成本，优化工艺并提高产品质量。     

Excimer and Exciplex Formation in Gold(I) Complexes Preconditioned by Aurophilic Interactions

Excimers and exciplexes are defined as assemblies of atoms or molecules A / A ′ where interatomic/intermolecular bonding appears only in excited states such as [ A ₂]* (for excimers) and [ AA ′]* (for exciplexes). Their formation has become widely known because of their role in gas‐phase laser technologies, but their significance in general chemistry terms has been given little attention. Recent investigations in gold chemistry have opened up a new field of excimer and exciplex chemistry that relies largely on the preorganization of gold(I) compounds (electronic configuration Au^I(5d¹⁰)) through aurophilic contacts. In the corresponding excimers, a new type of Au???Au bonding arises, with bond energies and lengths approaching those of ground‐state Au?Au bonds between metal atoms in the Au⁰(5d¹⁰6s¹) and Au^II(5d⁹) configurations. Excimer formation gives rise to a broad range of photophysical effects, for which some of the relaxation dynamics have recently been clarified. Excimers have also been shown to play an important role in photoredox binuclear gold catalysis.     

Extremely low vertical-emittance beam in the accelerator test facility at KEK

Electron beams with the lowest, normalized transverse emittance recorded so far were produced and confirmed in single-bunch-mode operation of the Accelerator Test Facility at KEK. We established a tuning method of the damping ring which achieves a small vertical dispersion and small x-y orbit coupling. The vertical emittance was less than 1% of the horizontal emittance. At the zero-intensity limit, the vertical normalized emittance was less than 2.8 x 10(-8) rad m at beam energy 1.3 GeV. At high intensity, strong effects of intrabeam scattering were observed, which had been expected in view of the extremely high particle density due to the small transverse emittance.     

Preparation and characterisation of palladium, platinum and manganese di(organo)carbene complexes from quinolinone and quinolinium precursors

A series of palladium, platinum and manganese di(organo)carbene complexes have been prepared from 4-chloro-N-methylquinolinone by processes that involve alkylation before or after attachment to the metal unit; the nucleophilic heteroatoms are separated from the C-donor atom by three bonds.     

Cones in Banach algebras

We develop spectral theory for elements in an ordered Banach algebra.     

On quasinilpotent equivalence of finite rank elements in Banach algebras

We characterize elements in a semisimple Banach algebra which are quasinilpotent equivalent to maximal finite rank elements.     

The index for Fredholm elements in a Banach algebra via a trace II

We show that the index defined via a trace for Fredholm elements in a Banach algebra has the property that an index zero Fredholm element can be decomposed as the sum of an invertible element and an element in the socle. We identify the set of index zero Fredholm elements as an upper semiregularity with the Jacobson property. The Weyl spectrum is then characterized in terms of the index.     

Preparing alpha,beta-unsaturated Fischer-type carbene complexes via an unforeseen route

Four 4-(NH-amino)-1-metalla-1,3-diene carbene complexes, two of which contain novel 4-membered heterometallacycles, formed regioselectively from the reaction of a mixture of [(CH(3))(2)(CH(3)S)S][BF(4)], the acetonitrilium electrophile, CH(3)CNCH(3)(+), and the deprotonated alkoxycarbene complexes, (CO)(5)M=C(OCH(3))CH(2)Li (M = Cr, W). The preferred Z-configurations of the alkoxy and amino groups are determined by strong H-bonding in the products. The metal-carbene bonds in the chelates are shorter by 0.08 A than those in the acyclic compounds.