排序方式: 共有8条查询结果,搜索用时 15 毫秒
1
1.
2.
A wet chemical deposition method for preparing transparent conductive thin films on the base of Al-doped ZnO (AZO) nanoparticles
has been demonstrated. AZO nanoparticles with a size of 7 nm have been synthesised by a simple precipitation method in refluxed
conditions in ethanol using zinc acetate and Al-isopropylate. The presence of Al in ZnO was revealed by the EDX elemental
analysis (1.8 at.%) and UV–Vis spectroscopy (a blue shift due to Burstein–Moss effect). The obtained colloid solution with
the AZO nanoparticles was used for preparing by spin-coating thin films on glass substrates. The film demonstrated excellent
homogeneity and transparency (T > 90%) in the visible spectrum after heating at 400 °C. Its resistivity turned to be excessively high (ρ = 2.6 Ω cm) that
we ascribe to a poor charge percolation due to a high film porosity revealed by SEM observations. To improve the percolation
via reducing the porosity, a sol–gel solution was deposited “layer-by-layer” in alternation with layers derived from the AZO
colloid followed by heating. As it was shown by optical spectroscopy measurements, the density of thus prepared film was increased
more than twice leading to a significant decrease in resistivity to 1.3 × 10−2 Ω cm. 相似文献
3.
Samuel Jorice Raccurt Olivier Poncelet Olivier Auger Aurélien Ling Wai-Li Cherns Peter Grunwald Didier Tillement Olivier 《Journal of nanoparticle research》2010,12(6):2255-2265
Journal of Nanoparticle Research - Fluorescent silica nanoparticles are widely used for various applications from mechanical reinforcement to biology. In many cases, their surface has to be... 相似文献
4.
Vincent?Maurice Ilaria?Rivolta Julien?Vincent Olivier?Raccurt Jean-Noel?Rouzaud Giuseppe?Miserrochi Eric?Doris Cécile?Reynaud Nathalie?Herlin-BoimeEmail author 《Journal of nanoparticle research》2012,14(2):697
This article presents a process for surface coating and functionalization of luminescent silicon nanoparticles. The particles
were coated with silica using a microemulsion process that was adapted to the fragile silicon nanoparticles. The as-produced
core–shell particles have a mean diameter of 35 nm and exhibit the intrinsic photoluminescence of the silicon core. The silica
layer protects the core from aqueous oxidation for several days, thus allowing the use of the nanoparticles for biological
applications. The nanoparticles were further coated with amines and functionalized with polyethylene glycol chains and the
toxicity of the particles has been evaluated at the different stages of the process. The core–shell nanoparticles exhibit
no acute toxicity towards lung cells, which is promising for further development. 相似文献
5.
Jorice Samuel Olivier Raccurt Cedric Mancini Christophe Dujardin David Amans Gilles Ledoux Olivier Poncelet Olivier Tillement 《Journal of nanoparticle research》2011,13(6):2417-2428
Gadolinium oxide nanoparticles are more and more used. They can notably provide interesting fluorescence properties. Herein they are incorporated into a non-aqueous-based polymer, the poly(methyl methacrylate). Their dispersion within the polymer matrix is the key to improve the composite properties. As-received gadolinium oxide nanopowders cannot be homogeneously dispersed in such a polymer matrix. Two surface treatments are, therefore, detailed and compared to achieve a good stability of the nanoparticles in a non-aqueous solvent such as the 2-butanone. Then, once the liquid suspensions have been stabilized, they are used to prepare nanocomposites with homogeneous particles dispersion. The two approaches proposed are an hybrid approach based on the growth of a silica shell around the gadolinium oxide nanoparticles, and followed by a suitable silane functionalization; and a non-hybrid approach based on the use of surfactants. The surface treatments and formulations involved in both methods are detailed, adjusted and compared. Thanks to optical methods and in particular to the use of a ??home made?? confocal microscope, the dispersion homogeneity within the polymer can be assessed. Both methods provide promising and conclusive results. 相似文献
6.
Nicolas Wartenberg Dr. Olivier Raccurt Prof. Elodie Bourgeat‐Lami Dr. Daniel Imbert Dr. Marinella Mazzanti 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(10):3477-3482
The bis‐tetrazolate‐pyridine ligand H2pytz sensitises efficiently the visible and/or near‐IR luminescence emission of ten lanthanide cations (Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb). The LnIII complexes present sizeable quantum yields in both domains with a single excitation source. The wide range of possible colour combinations in water, organic solvents and the solid state makes the complexes very attractive for labelling and encoding. 相似文献
7.
J. Vincent V. Maurice X. Paquez O. Sublemontier Y. Leconte O. Guillois C. Reynaud N. Herlin-Boime O. Raccurt F. Tardif 《Journal of nanoparticle research》2010,12(1):39-46
This article presents the evolution of the photo-luminescence (PL) of silicon quantum dots (QDs) with an average diameter
of 5–6 nm dispersed in alcohol under different conditions. Two samples were considered after alcohol dispersion: freshly synthesized
(kept in air for 2 days) QDs which do not exhibit luminescence and air-aged (kept in air for 2 years) QDs exhibiting red-IR
luminescence. Experiments performed with addition of a small volume of water, followed by heating for different times showed
that the oxidation occurs gradually until transforming totally the initial material in SiO2. The oxidation process does not enable the appearance of PL from the Si core for dispersed non-aged powders, while it results
in a blue shift of the PL maximum intensity for the aged ones. The results obtained after UV illumination clearly indicate
an effect of the UV irradiation on the luminescence of QDs dispersed in aqueous environment, and the treatments with acidic
water lead to the conclusion of a possible enhancement of the PL by hydrogen passivation of the non-radiative defects. This
result should be taken into account for post-production treatments and applications, more particularly, considering a controlled
and safe use of luminescent Si QDs. 相似文献
8.
Cottin-Bizonne C Steinberger A Cross B Raccurt O Charlaix E 《Langmuir : the ACS journal of surfaces and colloids》2008,24(4):1165-1172
A dynamic surface force apparatus is used to determine the intrinsic flow boundary condition of two simple liquids, water and dodecane, on various smooth surfaces. We demonstrate the impact of experimental errors and data analysis on the accuracy of slip length determination. In all systems investigated, the dissipation is described by a well-defined boundary condition accounting for a whole range of separation, film thickness, and shear rate. A no-slip boundary condition is found in all wetting situations. On strongly hydrophobic surfaces, water undergoes finite slippage that increases with hydrophobicity. We also compare the relative influence of hydrophobicity and liquid viscosity on boundary flow by using water-glycerol mixtures with similar wetting properties. 相似文献
1