Electron Transfer Reactions of Photochemically Generated Ruthenium(III)–Polypyridyl Complexes with Methionines

The oxidation of methionine (Met) plays an important role during biological conditions of oxidative stress as well as for protein stability. Ruthenium(III)–polypyridyl complexes, [Ru(NN)₃]³⁺, generated from the photochemical oxidation of the corresponding Ru(II) complexes with molecular oxygen, undergo a facile electron transfer reaction with Met to form methionine sulfoxide (MetO) as the final product. Interaction of [Ru(NN)₃]³⁺ with methionine leads to the formation of >S^+● and (>S∴S<)⁺ species as intermediates during the course of the reaction. The interesting spectral, kinetic, and mechanistic study of the electron transfer reaction of four substituted methionines with six [Ru(NN)₃]³⁺ ions carried out in aqueous CH₃CN (1:1, v/v) by a spectrophotometric technique shows that the reaction rate is susceptible to the nature of the ligand in [Ru(NN)₃]³⁺ and the structure of methionine. The rate constants calculated by the application of Marcus semiclassical theory to these redox reactions are in close agreement with the experimental values.     

Versatile laser microfabrication techniques for lab-on-chip devices in general and uranium analysis in particular

In a plethora of microfabrication processes available now-a-days, one needs to choose the best possible option suitable for the job on-hand. This paper discusses three versatile approaches to fabricate microchips for lab-on-chip (LOC) applications in general and uranium analysis in water samples as a specific case. Laser-direct patterning succeeded by soft lithography, laser micropatterning followed by HF etching and micromilling have been demonstrated which not only suit the objective of uranium detection but also for most of the LOC applications. The different techniques elaborated enable development of LOCs in polymers as well as glass with a depth ranging from few microns to 100 μm or higher while squeezing the reaction lengths of ～10 cm on a 20 mm × 32 mm chip. This development equips one to design and develop more complicated LOC devices to take advantage of their hastened reaction cycle with minimal waste in terms of capital and maintenance cost.     

Main injector particle production experiment at Fermilab

The main injector particle production (MIPP) experiment at Fermilab uses particle beams of charged pions, kaons, proton and antiproton with beam momenta of 5?C90 GeV/c to measure particle production cross-sections of various nuclei including liquid hydrogen, MINOS target and thin targets of beryllium, carbon, bismuth and uranium. The physics motivation to perform such cross-section measurements is described here. Recent results on the analysis of NuMI target and forward neutron cross-sections are presented here. Preliminary cross-section measurements for 58 GeV/c proton on liquid hydrogen target are also presented. A new method is described to correct for low multiplicity inefficiencies in the trigger using KNO scaling.     

On dominator colorings in graphs

A dominator coloring of a graph G is a proper coloring of G in which every vertex dominates every vertex of at least one color class. The minimum number of colors required for a dominator coloring of G is called the dominator chromatic number of G and is denoted by ?? _d (G). In this paper we present several results on graphs with ?? _d (G)?=???(G) and ?? _d (G)?=???(G) where ??(G) and ??(G) denote respectively the chromatic number and the domination number of a graph G. We also prove that if ??(G) is the Mycielskian of G, then ?? _d (G)?+?1?????? _d (??(G))?????? _d (G)?+?2.     

Soliton-induced supercontinuum generation in liquid-filled photonic crystal fibre

We aim to study the nonlinear optical phenomena with ultra-broadband radiation in photonic crystal fibre (PCF). While PCFs with cores made from different glasses are well studied in previous works, in this paper, it is planned to investigate the dynamics of nonlinear processes of supercontinuum generation (SCG) in liquid-filled PCF (LCPCF) to understand the physical phenomena of femtosecond pulse propagation, particularly, the temporal and spectral changes of the pulse propagating through specific PCFs. Since the CS₂-filled LCPCF has complex nonlinear phenomena, we intend to analyse the role of saturable nonlinear response and slow nonlinear response on SCG in detail. For the physical explanation, soliton fission and modulational instability techniques will be implemented to investigate the impact of slow nonlinear response and saturable nonlinear response respectively, in SCG process.     

Kopsia Singapurensis提取物对酸性介质中低碳钢的缓蚀效应(英文)

The influence of the alkaloid extract of Kopsia singapurensis on the corrosion behavior of mild steel (MS) in 1 mol·L-1 HCl and 1 mol·L-1 H2SO4 was studied using electrochemical techniques, viz., potentiodynamic polarization and AC impedance. The experimental results clearly show that the plant extract effectively inhibits corrosion in both acid media and the inhibition efficiency obtained from the electrochemical techniques is in good agreement. Furthermore, the polarization technique indicates that the extract acts as an anodic type inhibitor in HCl and as a mixed type in H2SO4. Scanning electron microscopy (SEM) was carried out to examine the surface morphological changes of metal specimens in both the inhibited and uninhibited solutions. SEM images show the formation of an adsorbed layer over the metal surface by the inhibitor molecule. The presence of alkaloidal constituents in the plant extract was confirmed by Fourier transform infrared (FTIR) spectroscopy and chemical analysis.     

Impact of higher-order dispersion in the modulational instability spectrum of a relaxing coupled saturable media

A theoretical analysis of modulational instability (MI) of optical pulses propagating near the zero dispersion wavelength of a lossless fibre with the effect of delayed saturable nonlinear response is presented. We calculate the exact dispersion relation with the effect of higher dispersion for the harmonic perturbation. We analysed the impact of fourth-order dispersion effects in the MI spectrum. We examine the possibility of MI in both dispersion regimes, regardless of the sign of the group velocity dispersion.     

Volumetric, Ultrasonic and Transport Properties of Binary Liquid Mixtures Containing Dimethyl Formamide at 303.15 K

Excess volumes （v^E）, ultrasonic velocities （u）, isentropic compressibility （△Ks） and viscosities （η） for the binary mixtures of dimethyl formamide （DMF） with 1,2-dichlorobenzene, 1,3-dichlorobenzene, 1,2,4-trichlorobenzene, o-chlorotoluene, m-chlorotoluene, p-chlorotoluene, o-nitrotoluene and m-nitrotoluene at 303.15 K were studied. Excess volume data exhibit an inversion in sign for the mixtures of dimethyl formamide with 1,2- and 1,3-dichlorobenzenes and the property is completely positive over the entire composition range for the mixtures of dimethyl formamide with 1,2,4-trichlorobenzene, o-nitrotoluene and m-nitrotoluene. On the other hand, the quantity is negative for the mixtures of dimethyl formamide with chlorotoluenes. Isentropic compressibility （Ks） has been computed for the same systems from precise sound velocity and density data. Further, deviation of isentropic com- pressibility （△Ks） from ideal behavior was also calculated. AKs values are negative over the entire volume fraction range in all the binary mixtures. The experimental sound velocity data were analysed in terms of Free Length Theory （FLT） and Collision Factor Theory （CFT）. The viscosity data were analysed on the basis of corresponding state approach. The measured data were discussed on the basis of intermolecular interactions between unlike molecules.     

On the number of generators of a projective module

In this article we give a bound on the number of generators of a finitely generated projective module of constant rank over a commutative Noetherian ring in terms of the rank of the module and the dimension of the ring. Under certain conditions we provide an improvement to the Forster–Swan bound in case of finitely generated projective modules of rank n over an affine algebra over a finite field or an algebraically closed field.