用区域分解算法结合蒙特卡罗法求坦克温度场和红外辐射出射度

本文将区域分解算法和蒙特卡罗法相结合，求坦克温度场和红外辐射出射度．采用蒙特卡罗法计算辐射传递系数，可以考虑界面的复杂辐射特性，如：镜反射、各向异性发射、各向异性反射等；可直接考虑界面的复杂几何特性，如:相互遮挡、太阳入射方向上的投影面积等．引入辐射传递系数，分离了计算的难点，使得在时间域（计算步骤）上能把整个问题分解为若干个子问题并行处理、在空间域（计算区域）上将坦克分解为若干个子区域，缩小计算规模，并可使用多个处理器并行计算；同时减轻了蒙特卡罗法编程的难度，缩短了计算时间．     

Physical gelation and macromolecular mobility of sustainable polylactide during isothermal crystallization

The mobility of free macromolecular chains is of importance to the growth of crystallites in a crystallizing sustainable polylactide (PLA), which was scarcely explored by rheology. In this study, the time‐resolved rheological properties for PLA during isothermal crystallization were investigated first, showing that the storage and loss modulus experience 2–3 decades of increase. The Avrami analysis reveals that the crystallization kinetics in rheological measurement protocol follows the homogeneous nucleation and three‐dimensional growth mechanism. The linear viscoelastic properties in the vicinity of physical gelation point were then studied at the inverse quenching temperature of 165 °C. The results show that physical gelation occurs when the critical absolute crystallinity reaches 13% as determined by the rheological method. Relaxation time spectra reveal that the interfacial relaxation is greatly retarded but the presence of growing spherulites possesses little constraint on the mobility of free chains in matrix especially before physical gelation point. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1235–1244     

非稳态油膜力作用下偏角不对中碰摩转子系统振动特性分析

建立了非稳态油膜力、碰摩力作用下,偏角不对中轴系的横向振动模型,将Jeffcott转子模型推广至约束条件下的轴系振动模型,通过引入转子间的位移约束,由Lagrange方程导出了不对中轴系系统的振动方程.仿真研究表明:由于不对中的存在,轴系横向振动是强非线性、非定常、同时含有自激励、参数激励和外激励的三自由度振动系统;由于从动轴与主动轴的不对中,导致了转轴间的运动约束,使轴系横向振动系统比Jeffcott转子动力学模型所描述的振动系统少了一个自由度.随着偏角不对中量、转轴质量比的变化,系统出现周期、概周期、混沌运动特征.不对中轴系处于概周期运动时,呈现出自激振动特征.其结果可为旋转机械故障诊断、轴系对中及设备的安全运行提供更为准确的理论参考.     

Multiplesite structure and photoluminescence properties of Eu3+ doped MgO nanocrystals

MgO:Eu³⁺ nanocrystals with average diameter around 15 nm were prepared via a facile combustion method under a weak reductive atmosphere at temperature as low as 300°C. The photoluminescence spectra showed that the MgO:Eu³⁺ nanocrystals emit white light, the hypersensitive transition (⁵ D ₀→⁷ F _j of Eu³⁺) emission was prominent in the emission spectra resulting from the noinversion symmetry local site at which Eu³⁺ ions were located. Two kinds of luminescence sites of Eu³⁺ are identified by means of the fluorescence decay and site-selective spectroscopy. The excitation and absorption spectra indicated that the absorption of surface state decreased with the increase of Eu³⁺ concentration, meaning that the surface defect decreased through Eu³⁺ doping for some of them located at the disordered sites near the surface or absorbed at the surface of MgO host. Meanwhile, absorptivity and CIE chromaticity coordinates of all samples were measured; the results were in accordance with the excitation and absorption spectra and photoluminescence spectra, respectively.     

Lewis acid catalyzed cyclization of glycals/2-deoxy-D-ribose with arylamines: additional findings on product structure and reaction diastereoselectivity

The cyclization reactions of arylamines with 2-deoxy-D-ribose or glycals were reinvestigated in the current report. In the montmorillonite KSF- or InCl(3)-initiated reactions of 2-deoxy-D-ribose with arylamines, a pair of diastereomeric tetrahydro-2H-pyran-fused tetrahydroquinolines was obtained in a nearly 1:1 ratio where the structure of one diastereomer was incorrectly assigned in the literature. Meanwhile, the diastereoselectivity in InBr(3)-catalyzed cyclization of glycals with arylamines was also incorrectly reported previously. It was found that high diastereomeric selectivity was achieved only when a C5-substituted glycal was used; otherwise, a pair of diastereomers was obtained in moderate yield with 1:1 diastereomeric ratio. Furthermore, tetrahydrofuran-fused tetrahydroquinolines 5b and 5b' were also prepared successfully by using TBDPS-protected ribose as the glycal precursor and montmorillonite KSF as the activator.     

半透明介质中辐射传递方程的反演计算及数值模拟

本文介绍了一侧为半透明、另一侧为非透明界面时一维半透明介质的辐射强度计算式。采用辐射与导热复合换热模型计算半透明介质内温度场。利用已知的温度场求半透明介质的辐射强度一正问题计算。将此辐射强度代入辐射反问题计算模型，引入测量误差，采用Ｃｈａｈｉｎｅ方法及演半透明介质内温度场一反问题计算。数值模拟表明，本文所采用的辐射反演法具有较高的精度及稳定性。     

四元数的复数形式及其在6R机器人反解中的应用

把四元数应用于平面旋转的特殊情况,并把旋转角度的正弦、余弦改写为复指数形式,导出平面四元数的两个复数形式的基.利用这两个基可以把表示三维变换的四元数和对偶四元数改造为复数形式,得到复数形式四元数的4个基和复数形式对偶四元数的8个基,以及它们之间乘法运算的运算法则.通过把它们应用到空间$6R$机器人的位移反解问题,证明了Dixon结式展开后的次数为16次,而不是形式上的24次,并且得到单变量的16次方程.     

块状及粒子煤灰复折射率的研究

1引言燃煤锅炉内的粒子（如焦碳、碳黑、飞灰粒子）及块状的燃烧产物（如积灰、结渣等）参与炉内辐射换热。这些固态物质的辐射特性，是炉内辐射换热计算的重要参数，而复折射率（。一n－7幼是确定这些参数的基本物性数据。复折射率不能直接测量，需要通过测量其它量，用反问题计算方法才能得到。目前；国际上求煤灰粒子复折射率的计算方法主要有两类：（1）直接利用煤灰粒子做实验［‘头（2）利用块状煤灰实验求其复折射率，认为它等于煤灰粒子的复折射率［’－‘］。D．R．Huffman问在理论上证明，二者的复折射率将会有所不同。本文分别…