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S. V. Ivanov V. V. Trachevskii O. S. Titova L. A. Zozulya 《Russian Journal of Applied Chemistry》2006,79(10):1712-1714
Experimental data demonstrate that a study of accelerated aging can enable prognostication of the working capacity and storage life of polymeric formulations used in aircraft components on the basis of changes in thermogravimetric constants of these polymeric formulations. 相似文献
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S. Yu. Ketkov H. L. Selzle E. W. Schlag S. N. Titova L. V. Kalakutskaya 《Optics and Spectroscopy》2004,97(4):567-571
Two-color photoionization of nickelocene molecules cooled in a supersonic jet is performed using a tunable nanosecond pulsed laser. The first stage of the multiphoton excitation is the transition from the highest occupied molecular orbital of nickelocene to the lowest Rydberg level. Conditions are found under which molecular ions (η 5-C5H5)2Ni+ are the only product of the multiphoton ionization in the one-color experiment. Irradiation of an excited molecule by an intense pulse of another laser increases significantly the yield of molecular ions. The dependence of the yield of (η5-C5H5)2Ni+ ions on the frequency of the second laser makes it possible to determine the adiabatic ionization potential of nickelocene as 6.138±0.012eV. 相似文献
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V. F. Balakirev S. Kh. Estemirova A. M. Yankin S. G. Titova 《Doklady Physical Chemistry》2007,416(1):240-242
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A. N. Titov O. N. Suvorova S. Yu. Ketkov S. G. Titova A. I. Merentsov 《Physics of the Solid State》2006,48(8):1466-1471
Single crystals and polycrystals of titanium diselenide TiSe2 intercalated with ferrocene Fe(η5-C5H5)2 and cobaltocene Co(η5-C5H5)2 are synthesized. The magnetic susceptibility and electrical resistivity of the intercalation compounds are measured. The results obtained demonstrate that the intercalation brings about the formation of an impurity band with a temperature-dependent width. 相似文献
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Titova K. V. Nikol'skaya V. P. Buyanov V. V. Suprun I. P. Pudova O. B. 《Russian Journal of Applied Chemistry》2004,77(3):402-406
The solubility and stability of the peroxo solvates KF·nH2O2 (n 1) and disinfectants based on them was studied in organic and aqueous-organic solvents. Polyhydric alcohols (glycerol and ethylene glycol) and Tosol (commercial antifreeze) were used as solvents. 相似文献
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Density functional theory calculations using the hybrid functional B3LYP have been performed to study the methyl transfer step in glycine N-methyltransferase (GNMT). This enzyme catalyzes the S-adenosyl-L-methionine (SAM)-dependent methylation of glycine to form sarcosine. The starting point for the calculations is the recent X-ray crystal structure of GNMT complexed with SAM and acetate. Several quantum chemical models with different sizes, employing up to 98 atoms, were used. The calculations demonstrate that the suggested mechanism, where the methyl group is transferred in a single S(N)2 step, is thermodynamically plausible. By adding or eliminating various groups at the active site, it was furthermore demonstrated that hydrogen bonds to the amino group of the glycine substrate lower the reaction barrier, while hydrogen bonds to the carboxylate group raise the barrier. 相似文献