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排序方式: 共有108条查询结果,搜索用时 15 毫秒
1.
New types of concerted domino acylation-cycloalkylation/alkylation-cycloacylation reactions have been described. These processes promoted by methanesulfonic acid-phosphorus pentoxide and concentrated H(2)SO(4), respectively, provide efficient, elegant, and expeditious routes for biologically active naturally occurring diterpenoids, namely (+/-)-ferruginol (1), (+/-)-nimbidiol (2), (+/-)-nimbiol (3), (+/-)-totarol (4), and ar-abietatriene (5). 相似文献
2.
A highly atom-efficient synthetic protocol for hydroarylation of terminal-aryl alkynes and styrene through the regioselective CC bond formation via the electrophilic addition of naphthols and substituted phenols has been developed using alumina-sulfuric acid as a heterogeneous supported solid acid catalyst. This methodology shows excellent regioselectivity and affords the desired product in good to excellent yield. The heterogeneous catalyst can also be recycled efficiently without much loss of activity. 相似文献
3.
Prasad RL Prasad R Bhar GC Thakur SN 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(14):3093-3102
IR spectra in the 'Finger Print' spectral range has great importance in qualitative and quantitative analysis of explosives like trinitrotoluene (TNT) and cyclotrimethyltrinitramine (RDX). Highly resolved IR bands of these compounds have been recorded in the 9.6 and 10.6 microm regions of CO2 laser. TNT and RDX are large molecules each having 21 atoms and it is very difficult to assign the modes of vibrations by comparison with those in other molecules making the vibrational assignments of observed bands a difficult task. The ab initio quantum chemical calculation is used for determining the molecular geometries and modes of vibration of these molecules with a view to assign their normal modes in the high resolution vibrational photoacoustic spectra. These assignments are very reliable in view of the good agreement between the observed and calculated frequencies of deuterated TNT. 相似文献
4.
Piyali Bagchi Khatua Ujjal Debnath 《International Journal of Theoretical Physics》2012,51(12):3701-3720
In this work, we have considered Cardassian Universe in Ho?ava-Lifshitz gravity. Four types of Cardassian Universe models i.e., polytropic/power law, modified polytropic, exponential and modified exponential models have been considered for accelerating models. The natures of statefinder parameters, deceleration parameter, Om diagnostic and EoS parameters have been investigated for all types of Cardassian models in Ho?ava-Lifshitz gravity. 相似文献
5.
We provide a new class of interior solution of a(2+1)-dimensional anisotropic star in Finch and Skea spacetime corresponding to the BTZ black hole. We develop the model by considering the MIT bag model EOS and a particular ansatz for the metric function grrproposed by Finch and Skea [M.R. Finch and J.E.F. Skea, Class. Quantum.Grav. 6(1989) 467]. Our model is free from central singularity and satisfies all the physical requirements for the acceptability of the model. 相似文献
6.
The aldol reaction of ketene silyl acetals with aldehydes proceeds efficiently on the solid surface of alumina impregnated with anhydrous zinc chloride under sonication providing aldol products in high yields and with good stereoselectivity. 相似文献
7.
A simple, convenient and efficient protocol for the construction of an array of glycospiro-pyrroloisoquinolines using isoquinolinium ylide and a carbohydrate-derived exocyclic olefin in the presence of Cu(OTf)2–Et3N catalytic system is described. Isoquinoline and alkylbromoacetates/2-bromoacetophenones were employed to generate the azomethine ylides in the presence of Et3N in refluxing toluene and subsequent exposure to the olefin led to the desired isoquinoline derivatives. 相似文献
8.
Farook Rahaman Piyali Bhar Ritabrata Biswas A. A. Usmani 《The European Physical Journal C - Particles and Fields》2014,74(4):1-7
An exact formulation of two-dimensional chiral hydrodynamics with diffeomorphism and conformal anomalies is provided. The constitutive relation involving the stress tensor is computed. It reveals a one parameter class of solutions which is a new result. For a particular value of this parameter, the results found in the gradient expansion scheme are reproduced. Moreover, the constitutive relation is analogous to the corresponding relation for an ideal fluid, appropriately modified to include the chirality property, which has also been derived here. 相似文献
9.
We have considered a model of two component mixture i.e., mixture of Chaplygin gas and barotropic fluid with tachyonic field.
In the case, when they have no interaction then both of them retain their own properties. Let us consider an energy flow between
barotropic and tachyonic fluids. In both the cases we find the exact solutions for the tachyonic field and the tachyonic potential
and show that the tachyonic potential follows the asymptotic behavior. We have considered an interaction between these two
fluids by introducing a coupling term. Finally, we have considered a model of three component mixture i.e., mixture of tachyonic
field, Chaplygin gas and barotropic fluid with or without interaction. The coupling functions decays with time indicating
a strong energy flow at the initial period and weak stable interaction at later stage. To keep the observational support of
recent acceleration we have considered two particular forms (i) Logamediate Scenario and (ii) Intermediate Scenario, of evolution
of the Universe. We have examined the natures of the recent developed statefinder parameters and slow-roll parameters in both
scenarios with and without interactions in whole evolution of the universe. 相似文献
10.
Suprio Bhar 《Potential Analysis》2017,46(2):261-277
In order to identify which of the strong solutions of Itô’s stochastic differential equations (SDEs) are Gaussian, we introduce a class of diffusions which ‘depend deterministically on the initial condition’ and then characterize the class. This characterization allows us to show, using the Monotonicity inequality, that the transpose of the flows generated by the SDEs, for an extended class of initial conditions, are the unique solutions of the class of stochastic partial differential equations introduced in Rajeev and Thangavelu (Potential Anal. 28(2), 139–162 2008), ‘Probabilistic Representations of Solutions of the Forward Equations’. 相似文献