Fractionation and composition of the carbohydrates of leaf vegetables

The qualitative and quantitative compositions of the carbohydrates of the leaf vegetables Lactuca sativa L., Spinacea oleracea L., and Rumex acetosa L. have been studied.M. V. Lomonosov Odessa Technological Institute of the Food Industry. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 349–351, May–June, 1993.     

The mutual influence of ligands in transition metal bis-chelates

Electronic structure quantum chemical calculations of the Fe(II), Ni(II) and Cu(II) bis-chelate series are reported. The nature of the ligand mutual influence effect on these compounds is elucidated. This effect manifests itself in polarization of metal—ligand bonds. The ligands which have highly covalent bonds with the metal form bonds of even greater covalent character in mixed complexes, whereas bonds for the other ligands become more ionic.     

252Cf plasma desorption mass spectrometric study of interactions of steroid glycosides with amino acids

252Cf Plasma desorption with time-of-flight mass spectrometry (TOF-PDMS) has been applied to comparative studies of the interactions of steroid glycosides (SGs) of the spirostan series with amino acids. SGs can interact with amino acids to form heteroclusters of the type [SG + aminoacid + H](+) and [SG + aminoacid + K](+). It is shown how the affinity of SGs for amino acids depends on the structures of both the SG carbohydrate chain and the SG aglycone, and on the nature of the amino acid side chain. Copyright 2000 John Wiley & Sons, Ltd.     

Synthesis and properties of a number of salts of N-succinylmethionine

A comparative study has been made of the radioprotector activity of cystamine and the synthesized cobalt and copper salts of N-succinylmethionine. Activity falls in the sequence cystamine-copper salt-cobalt salt.Khar'kov Scientific-Research Institute of Endocrinology and Hormone Chemistry. Khar'kov Medical Institute. Khar'kov Scientific-Research Institute of Medical Radiology. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 86–88, January–February, 1990.     

Strong solutions to stochastic equations with a Lévy noise and a non-constant diffusion coefficient

The goal of this study is to prove an existence and uniqueness theorem for the solution of a stochastic differential equation with Lévy noise in the case where the drift coefficient can be discontinuous. Additionally, the differentiability of the solution with respect to the initial condition is proved.     

Analysis of elastic and inelastic α + <Superscript>24</Superscript>Mg scattering within the <Emphasis Type="Italic">S</Emphasis> matrix model involving regge poles

A generalization of the phenomenological S-matrix model taking into account isolated Regge poles is proposed for simultaneously describing refractive effects in the cross sections for the elastic and inelastic scattering of light nuclei. The cross sections for elastic α + ²⁴Mg scattering are analyzed at energies of 50, 54, 65.7, 81, and 119 MeV. The analysis of the cross sections for elastic scattering is supplemented with an analysis of the inelastic scattering of alpha particles that is accompanied by the excitation of the first excited state (2⁺) of ²⁴Mg nuclei. It is shown that the proposed model makes it possible to describe satisfactorily all of the aforementioned cases of elastic and inelastic scattering, correctly reproducing the refraction Airy structures and anomalous large-angle scattering that are observed at large scattering angles.     

A diglyceride uronoside from streptomyces LA 7017

Chemistry of Natural Compounds - A new glycolipid, a 1-O-[4-O-(α-D-glucopyranosyl)-α-D-glucopyranuronosyl]-2,3-diglyceride has been isolated from the total cell lipids of Streptomyces LA...     

Eleuthesides and their analogs: IV. Synthesis of (1R,5R,6S)-6-(1,3-dithian-2-yl)-1-(2-hydroxyethyl)-5-methylcyclohex-3-ene and its O-tert-butyldimethylsilyl derivative

Two schemes for the preparation of chiral alcohols as key synthons for the synthesis of eleutheside analog at the A ring have been developed on the basis of the Diels-Alder adduct of levoglucosenone with piperylene.