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1.
The kinetics of polymerization of acrylonitrile initiated by KHSO5 and catalyzed by Ag(I) have been investigated in an aqueous medium over the temperature range of 35–50°C. The rates of polymerization Rp have been calculated and studied with respect to monomer and initiator. The catalytic activity of various metal ions on the initiator has been determined from a comparison of Rp values. The effects of monomer, catalyst, neutral salts, various amines, and inhibitor (hydroquinone) on the initial rate as well as maximum conversion have been studied. From the kinetics results a suitable reaction scheme has been proposed.  相似文献   
2.
A simple liquid chromatographic method was developed for the separation and quantification of voriconazole and its enantiomer in drug substance. The separation was achieved on Chiral cel-OD (250 mm × 4.6 mm × 10 μm) using mobile phase consisting of n-hexane and ethanol in the ratio 9:1 (v/v) with a flow rate of 1.0 mL min−1, at 27 °C column temperature and detection at 254 nm with an injection volume of 20 μL. Ethanol was used as diluent. The method is capable of detecting the (2S, 3R) enantiomer down to 0.0075% and can quantify down to 0.021% with respect to sample concentration. The method is rapid and the resolution achieved was about 3.0. This method can be employed for the quantification of (2S, 3R) enantiomer in voriconazole drug substance.  相似文献   
3.
4.
Summary A method for separation of thorium from rare earths in monazite based on the difference of stability of EDTA complexes towards oxine is described.  相似文献   
5.
Vinyl polymerization of acrylonitrile initiated by the Ce(IV)/thioacetamide redox system has been investigated in aqueous sulfuric acid in the temperature range of 10–20°C. The rate of polymerization (Rp) and the rate of Ce(IV) disappearance (?RCe) were measured. The effect of certain water-soluble organic solvents, added electrolytes, and aromatic and heterocyclic organic nitrogen compounds on the rate of polymerization has been investigated. Depending on the experimental results, we have suggested a suitable reaction scheme for the system which involves the production of initiating radicals from the oxidation of thioacetamide (TAm) by ceric ion and the termination of the polymer chain by metal ions.  相似文献   
6.
Summary Let k and l be integers such that 2k l. Let Sk and S l lbe two subsets of positive integers with SkQk and Sl Ql, where Qk denotes the set of k-free integers. Further suppose that the characteristic functions of Sk and S l l are multiplicative. Let T(n) denote the number of representations of n in the form n=a+b, where a Sk and b S l l. In this paper we establish an asymptotic formula for T(n), when n is sufficiently large; and deduce several known asymptotic formulae as particular cases.  相似文献   
7.
LetL(x) denote the number of square-full integers not exceedingx. It is well-known that $$L\left( x \right) \sim \frac{{\zeta \left( {{3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-\nulldelimiterspace} 2}} \right)}}{{\zeta \left( 3 \right)}}x^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} + \frac{{\zeta \left( {{2 \mathord{\left/ {\vphantom {2 3}} \right. \kern-\nulldelimiterspace} 3}} \right)}}{{\zeta \left( 2 \right)}}x^{{1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}} ,$$ whereζ(s) denotes the Riemann Zeta function, LetΔ(x) denote the error function in the asymptotic formula forL(x). On the assumption of the Riemann hypothesis (R.H.), it is known that $$\Delta x = O\left( {x^{13/81 + 8} } \right)$$ for everyε > 0. In this paper, we prove on the assumption of R.H. that $$\frac{1}{x}\int\limits_x^1 {\left| {\Delta \left( t \right)} \right|dt = O\left( {x^{1/10 + ^8 } } \right)} .$$ In fact, we prove a more general result. We conjecture that $$\Delta x = O\left( {x^{1/10 + ^8 } } \right)$$ under the assumption of the R.H.  相似文献   
8.
An isocratic reversed-phase liquid chromatographic method has been developed for quantitative determination of candesartan cilexetil, used to treat hypertension, in the bulk drug and in pharmaceutical dosage forms. The method is also applicable to analysis of related substances. Chromatographic separation was achieved on a 250 mm × 4.6 mm, 5 μm particle, CN column with a 50:50 (v/v) mixture of phosphate buffer, pH 3.0, and acetonitrile as mobile phase. The flow rate was 1.0 mL min−1 and the detection wavelength was 210 nm. Resolution of candesartan cilexetil and six potential impurities was greater than 2.0 for all pairs of compounds. The drug was subjected to hydrolytic, oxidative, photolytic, and thermal stress and substantial degradation occurred in alkaline and acidic media and under oxidative and hydrolytic stress conditions. The major product obtained as a result of basic hydrolysis was different from that produced by acid hydrolysis and aqueous hydrolysis. The stress samples were assayed against a reference standard and the mass balance was found to be close to 99.6%. The method was validated for linearity, accuracy, precision, and robustness.  相似文献   
9.
Summary A method for the photometric estimation of molybdenum(V) by extraction of the complex formed with NaDDTC in 5 N HCl solution is discussed. The reduction of Mo(VI) to Mo(V) is achieved with hydrazine sulphate. The colour intensity of the chloroform extract of the complex is measured at 450 nm. Beer's law is obeyed up to 500 g/25 ml of molybdenum.
Zusammenfassung Zur photometrischen Molybdänbestimmung wird der Komplex mit Diäthyldithiocarbamidat verwendet, der in 5 N salzsaurer Lösung gebildet und mit Chloroform extrahiert wird. Mo(VI) wird mit Hydrazinsulfat zur fünfwertigen Stufe reduziert. Die Messung erfolgt bei 450 nm; das Beersche Gesetz ist bis zu 500 g Mo/25 ml erfüllt.
  相似文献   
10.
LetL(x) denote the number of square full integers ≤x. By a square-full integer, we mean a positive integer all of whose prime factors have multiplicity at least two. It is well known that $$\left. {L(x)} \right| \sim \frac{{\zeta ({3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-\nulldelimiterspace} 2})}}{{\zeta (3)}}x^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} + \frac{{\zeta ({2 \mathord{\left/ {\vphantom {2 3}} \right. \kern-\nulldelimiterspace} 3})}}{{\zeta (2)}}x^{{1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}} ,$$ where ζ(s) denotes the Riemann Zeta function. Let Δ(x) denote the error function in the asymptotic formula forL(x). On the basis of the Riemann hypothesis (R.H.), it is known that \(\Delta (x) = O(x^{\tfrac{{13}}{{81}} + \varepsilon } )\) for every ε>0. In this paper, we prove the following results on the assumption of R.H.: (1) $$\frac{1}{x}\int\limits_1^x {\Delta (t)dt} = O(x^{\tfrac{1}{{12}} + \varepsilon } ),$$ (2) $$\int\limits_1^x {\frac{{\Delta (t)}}{t}\log } ^{v - 1} \left( {\frac{x}{t}} \right) = O(x^{\tfrac{1}{{12}} + \varepsilon } )$$ for any integer ν≥1. In fact, we prove some general results and deduce the above from them. On the basis of (1) and (2) above, we conjecture that \(\Delta (x) = O(x^{{1 \mathord{\left/ {\vphantom {1 {12}}} \right. \kern-0em} {12}} + \varepsilon } )\) under the assumption of R.H.  相似文献   
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