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1.
Characterization of autocatalytic decomposition reactions is important
for the safe handling and storage of energetic materials. Isothermal differential
scanning calorimetry (DSC) has been widely used to detect autocatalytic decomposition
of energetic materials. However, isothermal DSC tests are time consuming and
the choice of experimental temperature is crucial. This paper shows that an
automatic pressure tracking calorimeter (APTAC) can be a reliable and efficient
screening tool for the identification of autocatalytic decomposition behavior
of energetic materials.
Hydroxylamine nitrate (HAN) is an important
member of the hydroxylamine family. High concentrations of HAN are used as
liquid propellants, and low concentrations of HAN are used primarily in the
nuclear industry for decontamination of equipment. Because of its instability
and autocatalytic decomposition behavior, HAN has been involved in several
incidents. 相似文献
2.
Paul W. Percival 《Hyperfine Interactions》1991,65(1-4):901-911
As “rapporteur” for the papers submitted to this conference in the general area of muonium chemistry, I briefly review the
major developments since μSR86, and attempt to show how the papers presented at μSR90 relate to each other and work published
in the intervening years. Some topics are discussed in more detail than others, reflecting my own interests and views on what
is of current importance. Nevertheless, I try to cover all current research in muonium chemistry. The major areas are: early
events following muon thermalization, including subsequent loss of muon polarization (the “missing fraction”); molecular structure
and dynamics, primarily of muonium-substituted free radicals: and reaction kinetics. 相似文献
3.
4.
We describe a method for searching for ideal symmetric solutions to the Prouhet-Tarry-Escott Problem. We report results of extensive searches for solutions of sizes up to 12. We found two solutions of size 10 that are smaller by two orders of magnitude than the solution found by A. Letac in the 1940s, which was the smallest size 10 solution known before our search.
5.
Muon irradiation of pure liquid 3‐chloropropene, CH2=CH-CH2Cl, yields a primary radical, \dot\mboxCH2-CHMu-CH2Cl, and a secondary radical, MuCH2-\rm\dot\mboxCH-CH2Cl. 2‐methyl‐3‐chloropropene yields only the tertiary radical, MuCH2-\rm\dot\mboxC(CH3)-CH2Cl. These three chloroalkyl radicals have been characterized by μSR and μLCR, and the hyperfine coupling constants (hfcs)
have been determined over a range of temperatures, either in the pure liquid precursor or in concentrated solution. The temperature
variation of the hfcs has been analyzed to obtain estimates of the barrier to internal rotation about the C_\alpha-C_\beta
axis for various alkyl groups, and also their minimum energy conformations, i.e. their orientations with respect to the axis
of the 2p_z orbital of the unpaired electron. The tertiary radical is particularly interesting because all three methyl‐like
groups, -CH3,-CH2Cl and -CH2Mu, are represented. The results can be compared to electron spin resonance data for analogous radicals, to provide information
on the effects of Mu substitution for H.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
6.
Ghandi K Addison-Jones B Brodovitch JC McCollum BM McKenzie I Percival PW 《Journal of the American Chemical Society》2003,125(32):9594-9595
Muoniated free radicals have been detected in muon-irradiated aqueous solutions of acetone at high temperatures and pressures. At temperatures below 250 degrees C, the radical product is consistent with muonium addition to the keto form of acetone. However, at higher temperatures, a different radical was detected, which is attributed to muonium addition to the enol form. Muon hyperfine coupling constants have been determined for both radicals over a wide range of temperatures, significantly extending the range of conditions under which these radicals and the keto-enol equilibrium have been studied. 相似文献
7.
8.
A computational study has been performed to examine the reactions of a model beta-diketiminatoaluminium (I) complex with the hydrogen atom and with the electron. It was found that the hydrogen atom adds to the metal centre exothermically (DeltaH(rxn)=-202 kJ mol(-1)), and the spin density in the resulting radical resides entirely on the beta-diketiminato ligand. The spin density of the corresponding radical anion is very similar to the H-adduct. 相似文献
9.
Feng Ji Paul W. Percival Jean-Claude Brodovitch Brenda Addison-Jones Stanislaw Wlodek 《Hyperfine Interactions》1994,87(1):853-858
Muonium adds to allyl chloride, CH2=CHCH2Cl, to form two radicals: MuCH2CHCH2Cl (main product) and CH2CHMuCH2Cl (minor product). Both radicals were fully characterized bySR andLCR. In the main product, the LCR lines due to the35Cl and37Cl nuclei were observed. Also, the temperature dependence of various hyperfine coupling constants (hfc) indicates that both Mu and Cl eclipse the unpaired electronp
2-orbital in the minimum energy conformation. For the fragment-CH2Cl, the presence of Mu in the-position is found to affect significantly the hfc of Cl in the-position; an internal rotational barrier of 12 kJ mol–1 was estimated using a simpleV
2 torsional potential. 相似文献
10.
Martina Schwager Emil Roduner Ivan D. Reid Paul W. Percival Jean-Claude Brodovitch Stanislaw Wlodek Robert F. Marzke 《Hyperfine Interactions》1994,87(1):859-864
SR spectra of the ethyl radical adsorbed on porous silica were observed in transverse and in longitudinal magnetic fields in the temperature range 190–298 K. The line widths reflect the dynamic partial averaging of the hyperfine anisotropy due to reorientation and surface diffusion. 相似文献