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1.
The influence of different referencing methods on the accuracy of δ13C value measurement of ethanol fuel by gas chromatography/combustion/isotope ratio mass spectrometry
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João Marcos G. Barbosa Milenna K. Fernandes Rodrigues Lurian C. David Taynara C. e Silva Danielly A. Fortuna Lima Naiara Z. Pereira Emmanuel B. D'Alessandro Anselmo E. de Oliveira Paulo H. Jorge da Cunha Maria Clorinda S. Fioravanti Nelson R. Antoniosi Filho 《Biomedical chromatography : BMC》2020,34(11):e4935
An innovative volatolomic approach employs the detection of biomarkers present in cerumen (earwax) to identify cattle intoxication by Stryphnodendron rotundifolium Mart., Fabaceae (popularly known as barbatimão). S. rotundifolium is a poisonous plant with the toxic compound undefined and widely distributed throughout the Brazilian territory. Cerumen samples from cattle of two local Brazilian breeds (‘Curraleiro Pé-Duro’ and ‘Pantaneiro’) were collected during an experimental intoxication protocol and analyzed using headspace (HS)/GC–MS followed by multivariate analysis (genetic algorithm for a partial least squares, cluster analysis, and classification and regression trees). A total of 106 volatile organic metabolites were identified in the cerumen samples of bovines. The intoxication by S. rotundifolium influenced the cerumen volatolomic profile of the bovines throughout the intoxication protocol. In this way, it was possible to detect biomarkers for cattle intoxication. Among the biomarkers, 2-octyldecanol and 9-tetradecen-1-ol were able to discriminate all samples between intoxicated and nonintoxicated bovines. The cattle intoxication diagnosis by S. rotundifolium was accomplished by applying the cerumen analysis using HS/GC–MS, in an easy, accurate, and noninvasive way. Thus, the proposed bioanalytical chromatography protocol is a useful tool in veterinary applications to determine this kind of intoxication. 相似文献
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Dr. Felipe L. Coelho Eduarda S. Gil Dr. Paulo F. B. Gonçalves Dr. Leandra F. Campo Dr. Paulo H. Schneider 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(34):8157-8162
In this work, a series of 2-chalcogenylindoles was synthesized by an efficient methodology, starting from chalcogenoalkynes, including a previously unreported tellurium indole derivative. For the first time, these 2-substituted chalcogenylindoles were obtained in the absence of metal catalyst or base, under thermal conditions only. In addition, the results described herein represent a methodology with inverse regioselectivity for the chalcogen functionalization of indoles. 相似文献
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J. C. Fabris S. V. B. Gonçalves P. E. de Souza 《General Relativity and Gravitation》2002,34(12):2111-2126
The mass power spectrum for a Universe dominated by the Chaplygin gas is evaluated numerically from scales of the order of the Hubble horizon to 100 Mpc. The results are compared with a pure baryonic Universe and a cosmological constant model. In all three cases, the spectrum increases with k, the wavenumber of the perturbations. The slope of the spectrum is higher for the baryonic model and smaller for the cosmological constant model, the Chaplygin gas interpolating these two models. The results are analyzed in terms of the sound velocity of the Chaplygin gas and the moment the Universe begins to accelerate. 相似文献
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D. C. Oliveira Y. Messaddeq K. Dahmouche S. J. L. Ribeiro R. R. Gonçalves A. Vesperini D. Gindre J.-M. Nunzi 《Journal of Sol-Gel Science and Technology》2006,40(2-3):359-363
Organic-inorganic hybrid materials were prepared from an ureasil precursor (ureapropyltriethoxysilane designated as UPTES)
and acrylic acid modified zirconium (IV) n-propoxide. Thin films containing rhodamine 6G (Rh6G) were prepared by spin-coating on glass substrates with different Zr:Si molar ratios (Zr:Si = 75:25, 50:50 and 25:75). Refractive
index, thickness, number of propagating modes and attenuation coefficient were measured at 543.5, 632.8 and 1550 nm wavelengths
by the prism coupling technique. Distributed feedback (DFB) laser effect was observed and studied as a function of films thickness
and refractive index. 相似文献
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Paulo D. Cordaro 《Advances in Mathematics》2004,184(1):89-118
Taking as a start point the recent article of Meziani [7], we present several results concerning the normalization of a class of complex vector fields in the plane which degenerate along a real curve. We mainly deal with operators with finite regularity and analyze both the local situation as well as the case of normalization near a circle. Some related questions (e.g., on semi-global solvability and on the normalization of a class of generalized Mizohata operators) are also discussed. 相似文献
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Given a map f: X→Y and a Nielsen root class, there is a number associated to this root class, which is the minimal number of points among all
root classes which are H-related to the given one for all homotopies H of the map f. We show that for maps between closed surfaces it is possible to deform f such that all the Nielsen root classes have cardinality equal to the minimal number if and only if either N R[f]≤1, or N R[f]>1 and f satisfies the Wecken property. Here N R[f] denotes the Nielsen root number. The condition “f satisfies the Wecken property is known to be equivalent to |deg(f)|≤N R[f]/(1−χ(M
2)−χ(M
10/(1−χ(M
2)) for maps between closed orientable surfaces. In the case of nonorientable surfaces the condition is A(f)≤N R[f]/(1−χ(M
2)−χ(M
2)/(1−χ(M
2)). Also we construct, for each integer n≥3, an example of a map f: K
n
→N from an n-dimensionally connected complex of dimension n to an n-dimensional manifold such that we cannot deform f in a way that all the Nielsen root classes reach the minimal number of points at the same time. 相似文献
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