全文获取类型
收费全文 | 321篇 |
免费 | 12篇 |
专业分类
化学 | 179篇 |
晶体学 | 1篇 |
力学 | 4篇 |
数学 | 40篇 |
物理学 | 109篇 |
出版年
2023年 | 5篇 |
2022年 | 5篇 |
2021年 | 6篇 |
2020年 | 9篇 |
2019年 | 8篇 |
2018年 | 9篇 |
2017年 | 4篇 |
2016年 | 7篇 |
2015年 | 6篇 |
2014年 | 11篇 |
2013年 | 37篇 |
2012年 | 18篇 |
2011年 | 22篇 |
2010年 | 10篇 |
2009年 | 10篇 |
2008年 | 16篇 |
2007年 | 20篇 |
2006年 | 16篇 |
2005年 | 10篇 |
2004年 | 5篇 |
2003年 | 5篇 |
2002年 | 12篇 |
2001年 | 6篇 |
2000年 | 6篇 |
1999年 | 10篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1991年 | 2篇 |
1989年 | 3篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1975年 | 2篇 |
1965年 | 1篇 |
1963年 | 1篇 |
1962年 | 1篇 |
1960年 | 1篇 |
1959年 | 1篇 |
1954年 | 1篇 |
排序方式: 共有333条查询结果,搜索用时 0 毫秒
1.
The dependence of the beam propagation factor (M
2 parameter) with the absorbed pump power in the case of monolithic microchip laser under face-cooled configuration is extensively
studied. Our investigations show that the M
2 parameter is related to the absorbed pump power through two parameters (α and β) whose values depend on the laser material properties and laser configuration. We have shown that one parameter arises due
to the oscillation of higher order modes in the microchip cavity and the other parameter accounts for the spherical aberration
associated with the thermal lens induced by the pump beam. Such dependency of M
2 parameter with the absorbed pump power is experimentally verified for a face-cooled monolithic microchip laser based on Nd3+ -doped GdVO4 crystal and the values of α and β parameters were estimated from the experimentally measured data points. 相似文献
2.
René Meziat Diego Patiño Pablo Pedregal 《Computational Optimization and Applications》2007,38(1):147-171
We propose an alternative method for computing effectively the solution of non-linear, fixed-terminal-time, optimal control
problems when they are given in Lagrange, Bolza or Mayer forms. This method works well when the nonlinearities in the control
variable can be expressed as polynomials. The essential of this proposal is the transformation of a non-linear, non-convex
optimal control problem into an equivalent optimal control problem with linear and convex structure. The method is based on
global optimization of polynomials by the method of moments. With this method we can determine either the existence or lacking
of minimizers. In addition, we can calculate generalized solutions when the original problem lacks of minimizers. We also
present the numerical schemes to solve several examples arising in science and technology. 相似文献
3.
Heavy ion irradiation in the electronic stopping power region induces macroscopic dimensional change in metallic glasses and introduces magnetic anisotropy in some magnetic materials. The present work is on the irradiation study of ferromagnetic metallic glasses, where both dimensional change and modification of magnetic anisotropy are expected. Magnetic anisotropy was measured using Mössbauer spectroscopy of virgin and irradiated Fe40Ni40B20 and Fe40Ni38Mo4B18 metallic glass ribbons. 90 MeV 127I beam was used for the irradiations. Irradiation doses were 5×1013 and 7.5×1013 ions/cm2. The relative intensity ratios D 23 of the second and third lines of the Mössbauer spectra were measured to determine the magnetic anisotropy. The virgin samples of both the materials display in-plane magnetic anisotropy, i.e., the spins are oriented parallel to the ribbon plane. Irradiation is found to cause reduction in magnetic anisotropy. Near-complete randomization of magnetic moments is observed at high irradiation doses. Correlation is found between the residual stresses introduced by ion irradiation and the change in magnetic anisotropy. 相似文献
4.
5.
6.
E. I. Basaldella J. C. Tara G. Aguilar Armenta M. E. Patiño-Iglesias E. Rodríguez Castellón 《Journal of Sol-Gel Science and Technology》2006,37(2):141-146
Samples of mesoporous silica, SBA-15, were prepared under hydrothermal conditions and Cu cations were incorporated into the
framework by two different impregnation techniques. The corresponding adsorption/desorption isotherms of propylene, propane,
and N2 were measured to evaluate the material's effectiveness in the separation of propane/propylene mixtures.
Adsorption uptake of propylene increased and that of propane decreased in Cu containing samples as compared to the uptakes
observed in undoped SBA-15 samples. It was demonstrated that the presence of Cu atoms in the adsorbent lattice led to a greater
selectivity towards propylene. Furthermore, the highest level of Cu(I) were obtained in samples prepared by equilibrium impregnation,
which in turn improved the olefin/paraffin uptake ratio. Under some working conditions, the amount of propylene adsorbed in
selected samples is totally reversible while propane uptake was negligible. 相似文献
7.
Nb-oxides and in the presence of acetic anhydride led to products , or with participation of the indole nucleus during the fragmentation reaction. 相似文献
8.
9.
Nrusingha C. Pati Subasini Lenka Padma L. Nayak Trijama R. Mohanty 《Journal of polymer science. Part A, Polymer chemistry》1978,16(2):343-351
The aqueous polymerization of acrylonitrile initiated by an acidified bromate–thiourea redox system has been studied under nitrogen atmosphere. The rate of polymerization is independent of thiourea concentration over the range 2–9 × 10?3M and reaches maximum at 9 × 10?3M. The rate varies linearly with [monomer]. The initial rate of polymerization as well as the maximum conversion increases within the range of 4–22.5 × 10?3M KBrO3, but beyond 22.5 × 10?3M the rate of polymerization decreases. The initial rate and the limiting conversion increases with increasing polymerization temperature in the range 30–45°C; and beyond 45°C they decrease. The effect of certain neutral salts, water-soluble solvents, and micelles of cationic, anionic, and nonionic surfactants on the rate of polymerization has been investigated. 相似文献
10.
The results of some investigations into the synthesis and characterization of a new class of oligomers and polymers, the polyselenoacetals, are described. 相似文献